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Spontaneous orientation polarization (SOP) occurs when molecules with a finite permanent dipole moment are grown as thin films by physical vapor deposition and their alignment is such that a net non-zero polarization remains. We discuss how…

Materials Science · Physics 2025-11-12 Albin Cakaj , Markus Schmid , Alexander Hofmann , Wolfgang Brütting

The alignment of permanent dipole moments and the resulting spontaneous orientation polarization (SOP) is commonly observed in evaporated neat films of polar organic molecules and leads to a so-called giant surface potential. In case of…

Materials Science · Physics 2025-05-01 Alexander Hofmann , Albin Cakaj , Lea Kolb , Yutaka Noguchi , Wolfgang Brütting

Upon film growth by physical vapor deposition, the preferential orientation of polar organic molecules can result in a non-zero permanent dipole moment (PDM) alignment, causing a macroscopic film polarization. This effect, known as…

Materials Science · Physics 2024-10-23 Albin Cakaj , Markus Schmid , Alexander Hofmann , Wolfgang Brütting

We present a general electromagnetic description for dipoles confined to surfaces with oblique dipole moment orientations, extending the conventional in-plane (IP) and out-of-plane (OOP) treatments. This description is useful for describing…

So-called polar liquid crystals possess spontaneous long-range mutual orientation of their electric dipole moments, conferring bulk polarity to fluid phases of matter. The combination of polarity and fluidity leads to complex phase…

Soft Condensed Matter · Physics 2025-08-22 Jordan Hobbs , Calum J. Gibb , Richard J. Mandle

Molecular self-assembly has been extensively used for surface modification of metals and oxides for a variety of applications, including molecular and organic electronics. One of the goals of this research is to learn how the electronic…

Materials Science · Physics 2009-11-13 M. F. Calhoun , J. Sanchez , D. Olaya , M. E. Gershenson , V. Podzorov*

Vapour-deposited organic glasses are currently in use in many optoelectronic devices. Their operation temperature is limited by the glass transition temperature of the organic layers and thermal management strategies become increasingly…

The structural symmetry of solids plays an important role in defining their linear and nonlinear optical properties. The quest for versatile, cost-effective, large-scale, and defect-free approaches and materials platforms for tailoring…

A simple model was constructed to describe the polar ordering of non-centrosymmetric supramolecular aggregates formed by self assembling triblock rodcoil polymers. The aggregates are modeled as dipoles in a lattice with an Ising-like…

Soft Condensed Matter · Physics 2009-10-31 M. Sayar , F. J. Solis , M. Olvera de la Cruz , S. I. Stupp

The design of large-scale electronic circuits that are entirely spintronics-driven requires a current source that is highly spin-polarised at and beyond room temperature, cheap to build, efficient at the nanoscale and straightforward to…

We introduce electrically-poled small molecule assemblies that can serve as the active electro-optic material in nano-scale guided-wave circuits such as those of the silicon photonics platform. These monolithic organic materials can be…

Materials Science · Physics 2024-05-21 Lauren Dallachiesa , Ivan Biaggio

Highly oriented VO2 thin films were grown on sapphire substrates by the sol-gel method that includes a low pressure annealing in an oxygen atmosphere. This reduction process effectively promotes the formation of the VO2 phase over a…

Materials Science · Physics 2007-05-23 Byung-Gyu Chae , Hyun-Tak Kim , Sun-Jin Yun , Bong-Jun Kim , Yong-Wook Lee , Doo-Hyeb Youn , Kwang-Yong Kang

Materials with large second-order nonlinearities are crucial for next-generation integrated photonics. Spontaneously oriented organic thin films prepared by physical vapor deposition offer a promising poling-free and scalable approach. This…

We report on the theory and experimental generation of a class of diffraction-attenuation-resistant beams with state of polarization (SoP) and intensity that can be controlled on demand along the propagation direction. This is achieved by a…

The development of high-performance multifunctional polymer-based electronic circuits is a major step towards future flexible electronics. Here, we demonstrate a tunable approach to fabricate such devices based on rationally designed…

Very thin (1.2-2.5nm) self-assembled organic dielectric monolayers have been integrated into organic thin-film diode to achieve electrical characteristics. These dielectrics are fabricated by self-assembling deposition, resulting in smooth,…

Materials Science · Physics 2007-08-13 C. Trapes , V. Gadenne , L. Rouaï

We explore the possibility of forming a oriented polar molecule directly from a pair of colliding atoms. The process comprises the photoassociation and vibrational stabilization along with the molecular orientation. These processes are…

Quantum Physics · Physics 2026-01-14 Murilo D. Forlevesi , Edson Denis Leonel , Emanuel F. de Lima

We show that the electric dipole-dipole interaction between a pair of polar molecules undergoes an all-out transformation when superimposed by a far-off resonant optical field. The combined interaction potential becomes tunable by variation…

Atomic Physics · Physics 2015-05-30 Mikhail Lemeshko , Bretislav Friedrich

Organic semiconductors tend to self-assemble into highly ordered and oriented morphologies with anisotropic optical properties. Studying these optical anisotropies provides insight into processing-dependent structural properties and informs…

Materials Science · Physics 2016-11-03 Steven J. Brown , Ruth A. Schlitz , Michael L. Chabinyc , Jon A. Schuller

With an indirect band gap in the visible and a direct band gap at a much higher energy, boron phosphide (BP) holds promise as an unconventional p-type transparent conductor. Previous experimental reports deal almost exclusively with…

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