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This tutorial presents an introduction to the interaction of light and matter on the attosecond timescale. Our aim is to detail the theoretical description of ultra-short time-delays, and to relate these to the phase of extreme ultraviolet…

Atomic Physics · Physics 2012-07-20 J. M. Dahlström , A. L'Huillier , A. Maquet

Time-delays in the photoionization of molecules are investigated. As compared to atomic ionization, the time-delays expected from molecular ionization present a much richer phenomenon, with a strong spatial dependence due to the anisotropic…

Atomic Physics · Physics 2017-02-14 P. Hockett , E. Frumker , D. M. Villeneuve , P. B. Corkum

We investigate theoretically the relative time delay of photoelectrons originating from the different subshells (2s and 2p) of neon. This quantity was measured via attosecond streaking and studied theoretically by Schultze et al. [Science…

Atomic Physics · Physics 2017-02-15 J. Wätzel , A. S. Moskalenko , Y. Pavlyukh , J. Berakdar

We present measurements of single-photon ionization time delays between valence electrons of argon and neon using a coincidence detection technique that allows for the simultaneous measurement of both species under identical conditions.…

Atomic Physics · Physics 2015-10-28 M. Sabbar , S. Heuser , R. Boge , M. Lucchini , T. Carette , E. Lindroth , L. Gallmann , C. Cirelli , U. Keller

Shape resonances in photoionization of atoms and molecules arise from a particular geometry of the ionic potential which traps the receding photoelectron in a quasi-bound state in a particular partial wave. This mechanism allows us to…

Atomic Physics · Physics 2026-03-03 Anatoli S. Kheifets , Stephen Catsamas

The narrowing of electron and ion wave packets in the process of photoionization is investigated, with the electron-ion recoil fully taken into account. Packet localization of this type is directly related to entanglement in the joint…

Quantum Physics · Physics 2009-11-10 M. V. Fedorov , M. A. Efremov , A. E. Kazakov , K. W. Chan , C. K. Law , J. H. Eberly

We study the role of electron-electron correlation in the ground-state of Ne, as well as in photoionization dynamics induced by an attosecond XUV pulse. For a selection of central photon energies around 100 eV, we find that while the…

Atomic Physics · Physics 2018-01-31 Juan J. Omiste , Lars Bojer Madsen

In time-resolved photoemission experiments, more than one electron can be emitted from the solid by a single ultra-short pulse. We theoretically demonstrate how correlations between the momenta of outgoing electrons relate to time-dependent…

Strongly Correlated Electrons · Physics 2019-06-26 Christopher Stahl , Martin Eckstein

Chiral light-matter interactions have been investigated for two centuries, leading to the discovery of many chiroptical processes used for discrimination of enantiomers. Whereas most chiroptical effects result from a response of bound…

Photoionisation is a process where absorption of one or several photons liberates an electron and creates a hole in a quantum system, such as an atom or a molecule. Is it faster to remove an electron using one or many photons, and how to…

Quantum Physics · Physics 2015-09-25 Jivesh Kaushal , Felipe Morales , Lisa Torlina , Misha Ivanov , Olga Smirnova

More than 100 years after its discovery and its explanation in the energy domain, the duration of the photoelectric effect is still heavily studied. The emission time of a photoelectron can be quantified by the Wigner time delay.…

We investigate attosecond time delays in the emission of photoelectrons using a hierarchy of models of the $CO_2$ molecule including the strong field approximation, Coulomb-scattering, short-range parts of the molecular potential, Hartree…

Atomic Physics · Physics 2021-03-30 Hakon Volkmann , Vinay P. Majety , Armin Scrinzi

We study laser-assisted photodetachment time delays by attosecond pulse trains from the closed-shell negative ions F- and Cl-. We investigate the separability of the delay into two contributions: (i) the Wigner-like delay associated with…

Atomic Physics · Physics 2017-09-13 Eva Lindroth , Jan Marcus Dahlström

In this paper we have tried to establish a theory for angular correlation between the photo- and Auger electrons in the two-step double photoionization of a rare gas atom. The basic finding of this paper is that a general theoretical…

Atomic Physics · Physics 2007-05-23 Chiranjib Sur , Dipankar Chattarji

We investigate electron correlation effects in internuclear-distance-dependent enhanced ionization of $\mathrm{H}_2$, $\mathrm{LiH}$, and $\mathrm{HF}$ molecules by intense near-infrared laser pulses using a 3D description of the systems…

Atomic Physics · Physics 2019-02-27 Siddhartha Chattopadhyay , Lars Bojer Madsen

In this paper we explain the photoelectric effect in a variant of the standard model of non relativistic quantum electrodynamics, which is in some aspects more closely related to the physical picture, than the one studied in [BKZ]: Now we…

Mathematical Physics · Physics 2008-11-26 Heribert Zenk

The development of attosecond technology has enabled the real-time observation of coherent electron motion in atoms, molecules and condensed phases. Experimentally, it is now possible to generate laser pulses of durations of only a few tens…

Chemical Physics · Physics 2017-05-18 David Ayuso

Characterizing time delays in molecular photoionization as a function of the ejected electron emission direction relative to the orientation of the molecule and the light polarization axis pro-vides unprecedented insights into the…

In the fluorescence light of a single atom, the probability for emission of a photon with certain polarization depends on the polarization of the photon emitted immediately before it. Here correlations of such kind are investigated with a…

Quantum Physics · Physics 2015-05-14 F. Rohde , J. Huwer , N. Piro , M. Almendros , C. Schuck , F. Dubin , J. Eschner

Recollision physics and attosecond pulse generation meld the precision of optics with collision physics. As a follow-up to our previous work, we reveal a new direction for the study of electronic structure and multielectron dynamics by…

Atomic Physics · Physics 2023-06-06 Chunmei Zhang , Graham G. Brown , Dong Hyuk Ko , Paul B. Corkum