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We introduce an approach to improve single-reference coupled cluster theory in settings where the Aufbau determinant is absent from or plays only a small role in the true wave function. Using a de-excitation operator that can be efficiently…

Chemical Physics · Physics 2024-07-03 Harrison Tuckman , Eric Neuscamman

An implementation of coupled-cluster (CC) theory to treat atoms and molecules in finite magnetic fields is presented. The main challenges stem from the magnetic-field dependence in the Hamiltonian, or, more precisely, the appearance of the…

Chemical Physics · Physics 2015-09-02 Stella Stopkowicz , Jürgen Gauss , Kai K. Lange , Erik I. Tellgren , Trygve Helgaker

A novel reduced-scaling, general-order coupled-cluster approach is formulated by exploiting hierarchical representations of many-body tensors, combined with the recently suggested formalism of scale-adaptive tensor algebra. Inspired by the…

Chemical Physics · Physics 2018-03-14 Dmitry I. Lyakh

We establish the exponential clustering of correlation functions for the high-temperature Gibbs states of Bose-Hubbard type models. To overcome the technical difficulties arising from the unboundedness of bosonic operators, we develop the…

Statistical Mechanics · Physics 2026-03-31 Xin-Hai Tong , Tomotaka Kuwahara , Zongping Gong

We derive and implement a new way of solving coupled cluster equations with lower computational scaling. Our method is based on decomposition of both amplitudes and two electron integrals, using a combination of tensor hypercontraction and…

Chemical Physics · Physics 2020-05-14 Roman Schutski , Jinmo Zhao , Thomas M. Henderson , Gustavo E. Scuseria

We study emerging notions of quantum correlations in compound systems. Based on different definitions of quantumness in individual subsystems, we investigate how they extend to the joint description of a composite system. Especially, we…

Quantum Physics · Physics 2017-06-12 J. Sperling , E. Agudelo , I. A. Walmsley , W. Vogel

The objective of the present paper is to prove cluster multiplication theorem in the quantum cluster algebra of type $A_{2}^{(2)}$. As corollaries, we obtain bar-invariant $\mathbb{Z}[q^{\pm\frac{1}{2}}]$-bases established in [6], and…

Quantum Algebra · Mathematics 2018-04-17 Liqian Bai , Xueqing Chen , Ming Ding , Fan Xu

Clustering has received much attention in Statistics and Machine learning with the aim of developing statistical models and autonomous algorithms which are capable of acquiring information from raw data in order to perform exploratory…

Methodology · Statistics 2022-07-26 Victor Muthama Musau , Carlo Gaetan , Paolo Girardi

The theory of correlated electron systems is formulated in a form which allows to use as a reference point an ab initio band structure theory (AIBST). The theory is constructed in two steps. As a first step the total Hamiltonian is…

Strongly Correlated Electrons · Physics 2007-05-23 Igor Sandalov , Borje Johansson , Olle Eriksson

Cellular automata can show well known features of quantum mechanics, such as a linear updating rule that resembles a discretized form of the Schr\"odinger equation together with its conservation laws. Surprisingly, a whole class of…

Quantum Physics · Physics 2016-08-26 Hans-Thomas Elze

The unitary coupled cluster (UCC) approximation is one of the more promising wave-function ans\"atze for electronic structure calculations on quantum computers via the variational quantum eigensolver algorithm. However, for large systems…

Quantum Physics · Physics 2021-09-30 Jia Chen , Hai-Ping Cheng , James K. Freericks

A generalized version of the coupled coherent states method for coherent states of arbitrary Lie groups is developed. In contrast to the original formulation, which is restricted to frozen-Gaussian basis sets, the extended method is…

Quantum Physics · Physics 2016-03-09 Adriano Grigolo , Thiago F. Viscondi , Marcus A. M. de Aguiar

A self-energy-functional approach is applied to construct cluster approximations for correlated lattice models. It turns out that the cluster-perturbation theory (Senechal et al, PRL 84, 522 (2000)) and the cellular dynamical mean-field…

Strongly Correlated Electrons · Physics 2007-05-23 M. Potthoff , M. Aichhorn , C. Dahnken

We have studied electron correlations in the doped two-dimensional (2D) Hubbard model by using the coupled-cluster method (CCM) to investigate whether or not the method can be applied to correct the independent particle approximations…

Strongly Correlated Electrons · Physics 2009-10-31 Yoshihiro Asai , Hideki Katagiri

We discuss a coupled-cluster formalism for carrying out imaginary-time evolution from an arbitrary reference, and study the properties of the resulting evolution trajectories. The evolution converges to a solution of the standard…

Chemical Physics · Physics 2026-04-09 Yuhang Ai , Huanchen Zhai , Garnet Kin-Lic Chan

In this paper we utilize superoperator formalism to explore the entanglement evolution of four-qubit cluster states in a number of decohering environments. A four-qubit cluster state is a resource for the performance of an arbitrary single…

Quantum Physics · Physics 2015-05-20 Yaakov S. Weinstein , Jay Feldman , Jacob Robins , Jason Zukus , Gerald Gilbert

The cluster state model for quantum computation [Phys. Rev. Lett. 86, 5188] outlines a scheme that allows one to use measurement on a large set of entangled quantum systems in what is known as a cluster state to undertake quantum…

Quantum Physics · Physics 2007-05-23 William Hall

Quantum networks are natural scenarios for the communication of information among distributed parties, and the arena of promising schemes for distributed quantum computation. Measurement-based quantum computing is a prominent example of how…

Quantum Physics · Physics 2017-12-14 Mario Arnolfo Ciampini , Paolo Mataloni , Mauro Paternostro

Non-unitary theories are commonly seen in the classical simulations of quantum systems. Among these theories, the method of moments of coupled-cluster equations (MMCCs) and the ensuing classes of the renormalized coupled-cluster (CC)…

Quantum Physics · Physics 2022-12-13 Bo Peng , Karol Kowalski

We develop an operator-based framework to coarse-grain interacting particle systems that exhibit clustering dynamics. Starting from the particle-based transfer operator, we first construct a sequence of reduced representations: the operator…

Statistical Mechanics · Physics 2026-04-10 Nathalie Wehlitz , Grigorios A. Pavliotis , Christof Schütte , Stefanie Winkelmann