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We describe a setup to study ultrafast dynamics in gas-phase molecules using time-resolved photoelectron and photoion spectroscopy. The vacuum ultraviolet (VUV) probe pulses are generated via strong field high-order harmonic generation from…

Atomic and Molecular Clusters · Physics 2014-04-14 Markus Koch , Thomas J. A. Wolf , Jakob Grilj , Emily Sistrunk , Markus Gühr

A two-dimensional fluid model is used to investigate the electron heating dynamics and the production of neutral species in a capacitively coupled radio-frequency micro atmospheric pressure helium plasma jet -- specifically the COST jet --…

Non-adiabatic molecular dynamics simulations are used to analyze the role of different solvent degrees of freedom in the non-radiative relaxation of the first excited state of the hydrated electron. The relaxation occurs through a…

chem-ph · Physics 2008-02-03 Oleg V. Prezhdo , Peter J. Rossky

Visualizing ultrafast dynamics at the atomic scale requires time-resolved pump-probe characterization with femtosecond temporal resolution. For single-shot ultrafast electron diffraction (UED) with fully relativistic electron bunch probes,…

Conversion of solar energy with high quantum efficiencies is a key challenge in energy technologies. Excitation energy transfer (EET) mechanisms, such as F\"orster resonance energy transfer (FRET), play a crucial role in facilitating…

Radiationless deactivation channels of 2-thiocytosine in aqueous environment are revisited by means of quantum-chemical simulations of excited-state absorption spectra, and investigations of potential energy surfaces of the chromophore…

Chemical Physics · Physics 2018-08-22 Mikołaj J. Janicki , Rafał Szabla , Jiří Šponer , Robert W. Góra

Spin-crossover complexes exhibit two stable configurations with distinct spin states. The investigation of these molecules using low-temperature scanning tunneling microscopy has opened new perspectives for understanding the associated…

Mesoscale and Nanoscale Physics · Physics 2026-01-05 Jonas Fußangel , Björn Sothmann , Sven Johannsen , Sascha Ossinger , Felix Tuczek , Richard Berndt , Jürgen König , Manuel Gruber

We describe a method for simulating exciton dynamics in protein-pigment complexes, including effects from charge transfer as well as fluorescence. The method combines the hierarchical equations of motion, which are used to describe quantum…

Chemical Physics · Physics 2022-11-23 Thomas P. Fay , David T. Limmer

Imidazole and 1,2,3-triazole are promising hydrogen-bonded heterocycles that conduct protons via a structural mechanism and whose derivatives are present in systems ranging from biological proton channels to proton exchange membrane fuel…

Chemical Physics · Physics 2021-10-28 Austin O. Atsango , Mark E. Tuckerman , Thomas E. Markland

Directly imaging structural dynamics involving hydrogen atoms by ultrafast diffraction methods is complicated by their low scattering cross-sections. Here we demonstrate that megaelectronvolt ultrafast electron diffraction is sufficiently…

The characteristics of atmospheric-pressure microdischarges excited by nanosecond high-voltage pulses are investigated in helium-nitrogen mixtures, as a function of the parameters of the excitation voltage pulses. In particular, cases of…

Plasma Physics · Physics 2019-09-04 Zoltan Donko , Satoshi Hamaguchi , Timo Gans

Interfaces between molecules and 2D materials exhibit energy-driven functionalities, wherein charge transfer directs molecular motion. Unlike equilibrium systems, where molecular assemblies settle into static configurations, continuous…

The advent of pump-probe spectroscopy techniques paved the way to the exploration of the ultrafast dynamics of electrons and phonons in crystalline solids. Following photo-absorption of a pump pulse and the initial electronic…

Materials Science · Physics 2023-07-14 Fabio Caruso , Dino Novko

The surprising discovery of ultrafast demagnetization -- where electric field of femtosecond laser pulse couples to electrons of a ferromagnetic (FM) layer causing its magnetization vector {\em to shrink while not rotating}, is also assumed…

Mesoscale and Nanoscale Physics · Physics 2024-08-28 Jalil Varela-Manjarres , Ali Kefayati , M. Benjamin Jungfleisch , John Q. Xiao , Branislav K. Nikolic

A mechanism of electron-mediated pumping of heat in the absence of net charge transfer is proposed. It may be realized in charge-neutral electron systems, such as graphene, coupled to an external electric potential. The flow of heat in this…

Mesoscale and Nanoscale Physics · Physics 2022-03-14 A. V. Andreev

We show that the complete photoemission dynamics in situations of electron-ion entanglement can be retrieved from photoelectron spectral measurements without information on the ion. To this end, we develop an energy-time analysis of the…

Ultrafast spectroscopy paved the way for probing transient states of matter produced through photoexcitation. Despite significant advances, the microscopic processes governing the formation of these states remain largely unknown. This study…

Materials Science · Physics 2024-08-23 Francesco Libbi , Anders Johansson , Boris Kozinsky , Lorenzo Monacelli

Various hydrodynamic models of the heliospheric interface have been presented meanwhile, numerically simulating the interaction of the solar wind plasma bubble with the counterstreaming partially ionized interstellar medium. In these model…

Astrophysics · Physics 2009-11-10 H. J. Fahr , M. Bzowski

We present the design and implementation of a highly compact femtosecond electron diffractometer working at electron energies up to 100 keV. We use a multi-body particle tracing code to simulate electron bunch propagation through the setup…

Instrumentation and Detectors · Physics 2015-11-30 Lutz Waldecker , Roman Bertoni , Ralph Ernstorfer

We examine a simple model of proton pumping through the inner membrane of mitochondria in the living cell. We demonstrate that the pumping process can be described using approaches of condensed matter physics. In the framework of this…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Anatoly Yu. Smirnov , Lev G. Mourokh , Franco Nori