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In condensed matter, scattering processes determine the transport of charge carriers. In case of heterostructures, interfaces determine many dynamic properties like charge transfer and transport and spin current dynamics. Here we discuss…

We propose a simple model of cytochrome c oxidase, including four redox centers and four protonable sites, to study the time evolution of electrostatically coupled electron and proton transfers initiated by the injection of a single…

Other Condensed Matter · Physics 2015-05-13 Anatoly Yu. Smirnov , Lev G. Mourokh , Franco Nori

Realizing remarkable tunability in optical properties without sacrificing speed is critical to obtain all optical ultrafast devices. In this work, we investigate the ultrafast temporal behavior of optically tunable epsilon-near-zero (ENZ)…

Molecular absorption and photo-electron spectra can be efficiently predicted with real-time time-dependent density-functional theory (TDDFT). We show here how these techniques can be easily extended to study time-resolved pump-probe…

Atomic and Molecular Clusters · Physics 2013-01-10 Umberto De Giovannini , Gustavo Brunetto , Alberto Castro , Jessica Walkenhorst , Angel Rubio

The temporal dynamics of double ionization of H2 has been investigated both experimentally and theoretically with few-cycle laser pulses. The main observables are the proton spectra associated to the H^+ + H^+ fragmentation channel. The…

Quantum Physics · Physics 2008-09-23 Sébastien Saugout , Eric Charron , Christian Cornaggia

Charge transfer is a fundamental phenomenon in biology and chemistry, and involves the movement of charge through a system driven by nuclear dynamics. Because of the involvement of nuclear motion, it is generally assumed that charge…

Chemical Physics · Physics 2024-08-27 Simon P. Neville , Martha Yaghoubi Jouybari , Michael S. Schuurman

Roaming reactions involving a neutral fragment of a molecule that transiently wanders around another fragment before forming a new bond are intriguing and peculiar pathways for molecular rearrangement. Such reactions can occur for example…

We propose an experimental technique to generate large amplitude coherent phonons with irradiation of THz-rate pump pulses and to study the dynamics of phase transition in GeTe ferroelectrics. When a single pump pulse irradiates the sample…

Materials Science · Physics 2011-02-01 Muneaki Hase , Masahiro Kitajima , Shin-ichi Nakashima , Kohji Mizoguchi

Highly intense, sub-picosecond terahertz (THz) pulses can be used to induce ultrafast temperature jumps (T-jumps) in liquid water. A supercritical state of gas-like water with liquid density is established, and the accompanying structural…

Chemical Physics · Physics 2019-01-24 Caroline Arnold , Ludger Inhester , Sergio Carbajo , Ralph Welsch , Robin Santra

A stochastic model for the dynamics of enzymatic catalysis in explicit, effective solvents under physiological conditions is presented. Analytically-computed first passage time densities of a diffusing particle in a spherical shell with…

Biomolecules · Quantitative Biology 2015-06-04 Jeremy Schofield , Paul Inder , Raymond Kapral

Hydrogen bonding interactions between biological chromophores and their surrounding protein and solvent environment significantly affect the photochemical pathways of the chromophore and its biological function. A common first step in the…

Chemical Physics · Physics 2017-12-18 D. A. Horke , H. M. Watts , A. D. Smith , E. Jager , E. Springate , O. Alexander , C. Cacho , R. T. Chapman , R. S. Minns

A novel polarization-modulation transient method has been developed for studying fast anisotropic relaxation in electronic excited states of polyatomic and biologically relevant molecules under excitation with femtosecond laser pulses. The…

Chemical Physics · Physics 2020-05-12 Ioanna Gorbunova , Nikolay Bezverkhnii , Maxim Sasin , Idris Gagzhiev , Oleg Vasyutinskii

We experimentally investigate various processes present in the photoassociative interaction of an ultracold atomic sample with shaped femtosecond laser pulses. We demonstrate the photoassociation of pairs of rubidium atoms into…

For several decades, the interest of the scientific community in aneutronic fusion reactions such as proton-Boron fusion has grown because of potential applications in different fields. Recently, many scientific teams in the world have…

Plasma Physics · Physics 2021-09-27 X. Ribeyre , R. Capdessus , E. d'Humières , J. Wheeler , G. Mourou

Understanding and controlling the electronic as well as ro-vibrational motion and, thus, the entire chemical dynamics in molecules is the ultimate goal of ultrafast laser and imaging science. In photochemistry, laser-induced dissociation…

We investigate the quantum dynamics of energy and charge transfer in a wheel-shaped artificial photosynthetic antenna-reaction center complex.This complex consists of six light-harvesting chromophores and an electron-acceptor fullerene. To…

Biological Physics · Physics 2015-05-28 Pulak Kumar Ghosh , Anatoly Yu. Smirnov , Franco Nori

Recent experimental techniques in multicolor waveform synthesis allow the temporal shaping of strong femtosecond laser pulses with applications in the control of quantum mechanical processes in atoms, molecules, and nanostructures.…

Atomic Physics · Physics 2017-10-11 Janne Solanpää , Marcelo F. Ciappina , Esa Räsänen

Photocatalysis induced by sunlight is one of the most promising approach to environmental protection, solar energy conversion and sustainable production of fuels. The computational modeling of photocatalysis is a rapidly expending field…

Materials Science · Physics 2020-04-14 Yvelin Giret , Pu Guo , Li-Feng Wang , Jun Cheng

A fundamental, Quantum Mechanical description of photoactivation of a generic photosensitizer and the ensuing transfer of energy to endogenous oxygen as part of the Type II pathway to photodamage during photodynamic therapy (PDT) is…

Medical Physics · Physics 2023-01-11 Vincent M. Rossi

Femtosecond optical pump-probe technique is used to study charge carrier dynamics in few-layer MoS2 samples fabricated by mechanical exfoliation. An ultrafast pump pulse excites carriers and differential reflection of a probe pulse tuned to…

Mesoscale and Nanoscale Physics · Physics 2011-11-01 Rui Wang , Brian A. Ruzicka , Nardeep Kumar , Matthew Z. Bellus , Hsin-Ying Chiu , Hui Zhao