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High-resolution spectroscopy (HRS) has grown into one of the main techniques to characterise the atmospheres of extrasolar planets. High spectral resolving power allows for the efficient removal of telluric and host-star contamination.…

The study of exoplanetary atmospheres is one of the most exciting and dynamic frontiers in astronomy. Over the past two decades ongoing surveys have revealed an astonishing diversity in the planetary masses, radii, temperatures, orbital…

Using forward models for representative exoplanet atmospheres and a radiometric instrument model, we have generated synthetic observational data to explore how well the major C- and O-bearing chemical species (CO, CO2, CH4, and H2O),…

The best-characterized exoplanets to date are planets on close-in transiting orbits around their host stars. The high level of irradiation and transiting geometry of these objects make them ideal targets for atmospheric investigations.…

Exoplanet observations promise one day to unveil the presence of extraterrestrial life. Atmospheric compounds in strong chemical disequilibrium would point to large-scale biological activity just as oxygen and methane do in the Earth's…

Exoplanetary science is on the verge of an unprecedented revolution. The thousands of exoplanets discovered over the past decade have most recently been supplemented by discoveries of potentially habitable planets around nearby low-mass…

With the advanced capabilities of ground- and space-based telescopes, exoplanet science is beginning to characterize the physics and chemistry of exoplanet atmospheres. However, interpreting exoplanet observations requires sophisticated…

With the rapid developments in the exoplanet field, more and more terrestrial exoplanets are being detected. Characterising their atmospheres using transit observations will become a key datum in the quest for detecting an Earth-like…

The spectrum of an exoplanet reveals the physical, chemical, and biological processes that have shaped its history and govern its future. However, observations of exoplanet spectra are complicated by the overwhelming glare of their host…

Exoplanets are now being discovered in profusion. However, to understand their character requires spectral models and data. These elements of remote sensing can yield temperatures, compositions, and even weather patterns, but only if…

Transiting exoplanets provide detailed access to their atmospheres, as the planet's signal can be effectively separated from that of its host star. For transiting exoplanets three fundamental atmospheric measurements are possible:…

More than a thousand exoplanets have been discovered over the last decade. Perhaps more excitingly, probing their atmospheres has become possible. With current data we have glimpsed the diversity of exoplanet atmospheres that will be…

It is possible to learn a great deal about exoplanet atmospheres even when we cannot spatially resolve the planets from their host stars. In this chapter, we overview the basic techniques used to characterize transiting exoplanets -…

Of the many recently discovered worlds orbiting distant stars, very little is yet known of their chemical composition. With the arrival of new transit spectroscopy and direct imaging facilities, the question of molecular detectability as a…

Atmospheric compositions for rocky exoplanets will depend strongly on the bulk planetary composition and the orbital position of the planet. Non-traditional gases may be present in the atmospheres of exceptionally hot planets. Atmospheres…

[Abridged] Recently, there have been a series of detections of molecules in the atmospheres of extrasolar planets using high spectral resolution (R~100,000) observations, mostly using the CRyogenic high-resolution InfraRed Echelle…

With the ever-growing number of exoplanets detected, the issue of characterization is becoming more and more relevant. Direct imaging is certainly the most efficient but the most challenging tool to probe the atmosphere of exoplanets and…

What makes the study of exoplanetary atmospheres so hard is the extraction of its tiny signal from observations, usually dominated by telluric absorption, stellar spectrum and instrumental noise. The High Resolution Spectroscopy has emerged…

With the increasing number of directly imaged giant exoplanets the current atmosphere models are often not capable of fully explaining the spectra and luminosity of the sources. A particularly challenging component of the atmosphere models…

Determining the atmospheric structure and chemical composition of an exoplanet remains a formidable goal. Fortunately, advancements in the study of exoplanets and their atmospheres have come in the form of direct imaging - spatially…