Related papers: Microcanonical ensemble out of equilibrium
Particle number fluctuations are studied in the microcanonical ensemble. For the Boltzmann statistics we deduce exact analytical formulae for the microcanonical partition functions in the case of non-interacting massless neutral particles…
The postulates of thermodynamics were originally formulated for macroscopic systems. They lead to the definition of the entropy, which, for a homogeneous system, is a homogeneous function of order one in the extensive variables and is…
We develop the argument that the Gibbs-von Neumann entropy is the appropriate statistical mechanical generalisation of the thermodynamic entropy, for macroscopic and microscopic systems, whether in thermal equilibrium or not, as a…
The Renyi statistics in the canonical and microcanonical ensembles is examined in the general case and in particular for the ideal gas. In the microcanonical ensemble the Renyi statistics is equivalent with the Boltzmann-Gibbs statistics.…
Conventional thermo-statistics address infinite homogeneous systems within the canonical ensemble. However, some 170 years ago the original motivation of thermodynamics was the description of steam engines, i.e. boiling water. Its essential…
We prove that information-theoretic maximum entropy (MaxEnt) approach to canonical ensemble is mathematically equivalent to the classic approach of Boltzmann, Gibbs and Darwin-Fowler. The two approaches, however, "interpret" a same…
Microcanonical analysis is a powerful method for studying phase transitions of finite-size systems. This method has been used so far only for studying phase transitions of equilibrium systems, which can be described by microcanonical…
Breaking of ensemble equivalence between the microcanonical ensemble and the canonical ensemble may occur for random graphs whose size tends to infinity, and is signaled by a non-zero specific relative entropy of the two ensembles. In [3]…
Stochastic thermodynamics as reviewed here systematically provides a framework for extending the notions of classical thermodynamics like work, heat and entropy production to the level of individual trajectories of well-defined…
We have obtained an exact expression for the phase-space volume corresponding to a microcanonical ensemble of systems under center of mass, total linear and angular momenta conservation constraints, and arbitrary constraints on the…
In contrast to the canonical ensemble where thermodynamic functions are smooth for all finite system sizes, the microcanonical entropy can show nonanalytic points also for finite systems, even if the Hamiltonian is smooth. The relation…
We review here the microcanonical and canonical ensembles constructed on an underlying generalized quantum dynamics and the algebraic properties of the conserved quantities. We discuss the structure imposed on the microcanonical entropy by…
A simple, exactly solvable statistical model is presented for the description of baryonic matter in the thermodynamic conditions associated to the evolution of core-collapsing supernova. It is shown that the model presents a first order…
For a macroscopic, isolated quantum system in an unknown pure state, the expectation value of any given observable is shown to hardly deviate from the ensemble average with extremely high probability under generic equilibrium and…
We study a particle immersed in a heat bath, in the presence of an external force which decays at least as rapidly as $1/x$, for example a particle interacting with a surface through a Lennard-Jones or a logarithmic potential. As time…
Ensemble inequivalence has been observed in several systems. In particular it has been recently shown that negative specific heat can arise in the microcanonical ensemble in the thermodynamic limit for systems with long-range interactions.…
Translation of Ludwig Boltzmann's paper "\"Uber die Eigenschaften monozyklischer und anderer damit verwandter Systeme" Crelles Journal 98. S. 68-94. 1884 u. 1885 from German into English. In this foundational paper Boltzmann introduced two…
We show that entropy is globally concave with respect to energy for a rich class of mean field interactions, including regularizations of the the point-vortex model in the plane, plasmas and self-gravitating matter in 2D, as well as the…
Regardless of studies and debates over a century, the statistical origin of the second law of thermodynamics still remains illusive. One essential obstacle is the lack of a proper theoretical formalism for non-equilibrium entropy. Here I…
Filyokov and Karpov [Inzhenerno-Fizicheskii Zhurnal 13, 624 (1967)] have proposed a theory of non-equilibrium steady states in direct analogy with the theory of equilibrium states : the principle is to maximize the Shannon entropy…