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Organic semiconductor crystals stand out as an efficient, cheap and diverse platform for realising optoelectronic applications. The optical response of these crystals is governed by a rich tapestry of exciton physics. So far, little is…

Mesoscale and Nanoscale Physics · Physics 2022-09-13 Joshua J. P. Thompson , Dominik Muth , Sebastian Anhäuser , Daniel Bischof , Marina Gerhard , Gregor Witte , Ermin Malic

The broad use of organic semiconductors for optoelectronic applications relies on quantitative understanding and control of their spectroscopic properties. Of paramount importance are the transport gap - the difference between ionization…

Materials Science · Physics 2012-10-10 Sahar Sharifzadeh , Ariel Biller , Leeor Kronik , Jeffrey B. Neaton

The search for superconductivity with higher transition temperature ($T_C$) has long been a challenge in research efforts ever since its first discovery in 1911. The effort has led to the discovery of various kinds of superconductors and…

Superconductivity · Physics 2016-10-07 S. H. Rhim , Rolando Saniz , M. Weinert , A. J. Freeman

Actively tunable photonic devices are vital for next-generation optoelectronics requiring rapid switching and high bandwidth. Although organic optoelectronic devices have found wide application, their use as optical modulators has been…

The mechanism behind fast intersystem crossing in transition-metal complexes is shown to be a result of the dephasing of the photoexcited state to the phonon continuum of a different state with a significantly different transition…

Strongly Correlated Electrons · Physics 2010-02-11 Michel van Veenendaal , Jun Chang , A. J. Fedro

We study the collective photon decay of multiple quantum emitters embedded in a thin high-index dielectric layer such as hexagonal boron nitride (hBN), with and without a metal substrate. We first explore the significant role that guided…

This is a review of exciton dynamics in conjugated polymers. Exciton dynamics encompass multiple time and length scales. Ultrafast femtosecond processes are intrachain and involve a quantum mechanical correlation of the exciton and nuclear…

Chemical Physics · Physics 2021-02-15 William Barford

While optical technology provides the best solution for the transmission of information, optical logics still calls for qualitative new concepts to be explored. Exciton-polaritons are composite particles, resulting from the strong coupling…

Due to the Coulomb interaction exciton eignestates in monolayer transitional metal dichalcogenides are coherent superposition of two valleys. The exciton band which couples to the transverse electric mode of light has parabolic dispersion…

Mesoscale and Nanoscale Physics · Physics 2018-06-20 Areg Ghazaryan , Mohammad Hafezi , Pouyan Ghaemi

The concept of an exciton as a quasiparticle that represents collective excited states was originally adapted from solid-state physics and has been successfully applied to molecular aggregates by relying on the well-established limits of…

Chemical Physics · Physics 2026-01-01 Seogjoo J. Jang , Irene Burghardt , Chao-Ping Hsu , Christopher J. Bardeen

Light-matter interactions are known to lead to the formation of polariton states through what is called strong coupling, leading to the formation of two hybrid states usually tagged as Upper and Lower Polaritons. Here, we consider a similar…

In this work, we numerically study the Fizeau-Doppler shift of surface modes in a moving plasmonic metamaterial. At proper surface plasmon resonance conditions, a slow group velocity is resulted in the metamaterials, and our simulation…

Mesoscale and Nanoscale Physics · Physics 2009-07-13 Leilei Yin , Nicholas X. Fang

The plasmon-mediated manipulation of light-matter interaction in two-dimensional atomically transition-metal dichalcogenides (TMDs) critically depends on the design of plasmonic nanostructures to achieve the maximum optical field in TMDs.…

Optics · Physics 2021-12-07 Wei Li , Ming Xin , Wenze Lan , Qinghu Bai , Shuo Du , Gang Wang , Baoli Liu , Changzhi Gu

Monolayer (1L) transition metal dichalcogenides (TMDC) are of strong interest in nanophotonics due to their narrow-band intense excitonic transitions persisting up to room temperature. When brought into resonance with surface plasmon…

Effects of coupling between a molecular exciton and a surface plasmon (exciton-plasmon coupling) on the luminescence properties of the molecule and the surface plasmons are investigated using the nonequilibrium Green's function method.…

Materials Science · Physics 2013-06-12 Kuniyuki Miwa , Mamoru Sakaue , Hideaki Kasai

Surface plasmon polaritons (SPP or SP) are electromagnetic waves propagating along metal dielectric interfaces and existing over a wide range of frequencies. They have become popular because of their sub-wavelength confinement and the…

Optics · Physics 2012-11-08 Vasily V. Temnov

We present a computational study of the laser-driven quantum dynamics of positronium (Ps), PsH, and PsCl at the time-dependent Hartree-Fock level of theory. To eliminate finite-basis effects and to properly capture continuum dynamics, we…

Polaritons are quasi-particles describing the coupling between a photon and a material excitation, which can carry large momentum and confine electromagnetic fields to small dimensions, enabling strong light-matter interactions. In the…

Optics · Physics 2024-04-23 Yonatan Gershuni , Itai Epstein

Polaritons are compositional light-matter quasiparticles that arise as a result of strong coupling between a vacuum field of a resonant optical cavity and electronic excitations in quantum emitters. Reaching such a regime is often hard, as…

Organic semiconductors have the remarkable property that their optical excitation not only generates charge-neutral electron-hole pairs (excitons) but also charge-separated polaron pairs with high yield. The microscopic mechanisms…