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Using computer simulations, we study the dynamic arrest in a schematic model of colloid-polymer mixtures combining short-ranged attractions with long-ranged repulsions. The arrested gel is a dilute rigid network of colloidal particles…

Soft Condensed Matter · Physics 2018-08-17 David Richard , C. Patrick Royall , Thomas Speck

We study a microscopically realistic model of a physical gel and use computer simulations to investigate its static and dynamic properties at thermal equilibrium. The phase diagram comprises a sol phase, a coexistence region ending at a…

Soft Condensed Matter · Physics 2009-11-13 Pablo I. Hurtado , Pinaki Chaudhuri , Ludovic Berthier , Walter Kob

We develop and validate a simulation framework for colloidal gelation. We first reproduce the benchmark results of Santos, Campanella, and Carignano for spherical, gel-forming particles, then extend the methodology to more complex systems…

Soft Condensed Matter · Physics 2025-11-24 Johannes Krotz

A transition from solid-like to liquid-like behavior occurs when colloidal gels are subjected to a prolonged exposure to a steady shear. This phenomenon, which is characterized by a yielding point, is found to be strongly dependent on the…

Soft Condensed Matter · Physics 2019-02-08 José Ruiz-Franco , Nicoletta Gnan , Emanuela Zaccarelli

We use a combination of original light scattering techniques and particles with unique optical properties to investigate the behavior of suspensions of attractive colloids under gravitational stress, following over time the concentration…

Soft Condensed Matter · Physics 2015-05-27 Giovanni Brambilla , Stefano Buzzaccaro , R. Piazza , Ludovic Berthier , Luca Cipelletti

Thermosensitive microgels are widely studied hybrid systems combining properties of polymers and colloidal particles in a unique way. Due to their complex morphology their interactions and packing, and consequentially the viscoelastcity of…

Soft Condensed Matter · Physics 2019-06-19 Gaurasundar M. Conley , James L. Harden , Frank Scheffold

Using computer simulations, we identify the mechanisms causing aggregation and structural arrest of colloidal suspensions interacting with a short-ranged attraction at moderate and high densities. Two different non-ergodicity transitions…

Condensed Matter · Physics 2009-11-07 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates

Inorganic nanocrystal gels retain distinct properties of individual nanocrystals while offering tunable, network structure-dependent characteristics. We review different mechanisms for assembling gels from colloidal nanocrystals including…

The Starling principle describes exchanges in tissues based on the balance of hydrostatic and osmotic flows. This balance neglects the coupling between mechanics and hydrodynamics, a questionable assumption in strained elastic tissues due…

We study the structure and the dynamics in the formation of irreversible gels by means of molecular dynamics simulation of a model system where the gelation transition is due to the random percolation of permanent bonds between neighboring…

Soft Condensed Matter · Physics 2015-06-25 T. Abete , A. de Candia , E. Del Gado , A. Fierro , A. Coniglio

In complex crystals close to melting or at finite temperatures, different types of defects are ubiquitous and their role becomes relevant in the mechanical response of these solids. Conventional elasticity theory fails to provide a…

Using Brownian dynamics simulations we study gel-forming colloid-polymer mixtures. The focus of this article lies on the differences of dense and dilute gel networks in terms of structure formation both on a local and a global level. We…

Soft Condensed Matter · Physics 2023-12-19 Matthias Gimperlein , Jasper N. Immink , Michael Schmiedeberg

The elastic response in polymeric gels is studied by means of a percolation dynamic model. By numerical simulations the fluctuations in the gyration radius and in the center of mass motion of the percolating cluster are determined. Their…

Soft Condensed Matter · Physics 2009-11-07 Emanuela Del Gado , Lucilla de Arcangelis , Antonio Coniglio

Strong particulate gels are widely believed to behave poroelastically in compression, e.g. in sedimentation, even though they consolidate irreversibly because of the stickiness of the particles. Particulate gels are usually adhesive as well…

Soft Condensed Matter · Physics 2009-03-06 Richard Buscall

Glasses and gels, widely encountered amorphous solids with diverse industrial and everyday applications, share intriguing similarities such as rigidity without crystalline order and dynamic slowing down during aging. However, the underlying…

Soft Condensed Matter · Physics 2023-08-09 Yinqiao Wang , Michio Tateno , Hajime Tanaka

Recent theories predict that when a supercooled liquid approaches the glass transition, particle clusters with a special "amorphous order" nucleate within the liquid, which lead to static correlations dictating the dramatic slowdown of…

Soft Condensed Matter · Physics 2016-03-04 Bo Zhang , Xiang Cheng

The growing interest in the non-equilibrium assembly of colloidal particles in active liquids is driven by the motivation to create novel structures endowed with tunable properties unattainable within the confines of equilibrium systems.…

Soft Condensed Matter · Physics 2024-03-06 Pragya Kushwaha , Sayan Maity , Anjaly S. Menon , Raghunath Chelakkot , Vijayakumar Chikkadi

The macroscopic mechanical properties of colloidal particle gels strongly depend on the local arrangement of the powder particles. Experiments have shown that more heterogeneous microstructures exhibit up to one order of magnitude higher…

Soft Condensed Matter · Physics 2012-05-11 Iwan Schenker , Frank T. Filser , Markus Hütter , Ludwig J. Gauckler

A mixture of hard-sphere particles and model emulsion droplets is studied with a Brownian dynamics simulation. We find that the addition of nonwetting emulsion droplets to a suspension of pure hard spheres can lead to both gas-liquid and…

Soft Condensed Matter · Physics 2015-03-13 Andrea Fortini

Spinodal demixing of systems into two phases having very different viscosities leads to viscoelastic networks, i.e. gels. Here we consider demixing in a colloidal system where one phase is a nematic liquid crystal with a strongly…

Soft Condensed Matter · Physics 2018-06-19 Claudia Ferreiro-Córdova , C. Patrick Royall , Jeroen S. van Duijneveldt