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Density matrix downfolding (DMD) is a technique for regressing low-energy effective Hamiltonians from quantum many-body Hamiltonians. One limiting factor in the accuracy of classical implementations of DMD is the presence of…

Quantum computing offers a scalable approach to solving the nuclear shell model, a highly complex and exponentially scaled many-body problem. This work presents a numerical simulation of the subspace search variational quantum eigensolver…

Nuclear Theory · Physics 2025-12-16 Bhoomika Maheshwari , Paul Stevenson , P. Van Isacker

In quantum chemistry, the variational quantum eigensolver (VQE) is a promising algorithm for molecular simulations on near-term quantum computers. However, VQEs using hardware-efficient circuits face scaling challenges due to the barren…

Quantum Physics · Physics 2024-09-27 Rui Mao , Guojing Tian , Xiaoming Sun

Accurate determination of ground-state energies for molecules remains a challenge in quantum chemistry and a cornerstone for progress in fields such as drug discovery and materials design. The Variational Quantum Eigensolver (VQE)…

Quantum-classical hybrid algorithms are emerging as promising candidates for near-term practical applications of quantum information processors in a wide variety of fields ranging from chemistry to physics and materials science. We report…

Efficient representations of the Hamiltonian such as double factorization drastically reduce circuit depth or number of repetitions in error corrected and noisy intermediate scale quantum (NISQ) algorithms for chemistry. We report a…

The unitary coupled cluster (UCC) ansatz is a promising tool for achieving high-precision results using the variational quantum eigensolver (VQE) algorithm in the NISQ era. However, results on quantum hardware are thus far very limited and…

Quantum Physics · Physics 2024-11-27 Mark R. Hirsbrunner , Diana Chamaki , J. Wayne Mullinax , Norm M. Tubman

Quantum chemistry is one of the most promising applications for which quantum computing is expected to have significant impact. Despite considerable research in the field of electronic structure, calculating the vibrational properties of…

Quantum Physics · Physics 2025-05-23 Marco Majland , Patrick Ettenhuber , Nikolaj Thomas Zinner , Ove Christiansen

We perform a series of calculations using simulated QPUs, accelerated by the NVIDIA CUDA-Q platform, focusing on a molecular analog of an amine-functionalized metal-organic framework (MOF), a promising class of materials for CO$_2$ capture.…

Chemical Physics · Physics 2025-12-16 Jonathan R. Owens , Marwa H. Farag , Pooja Rao , Annarita Giani

Designing compact and accurate circuits for the variational quantum eigensolver (VQE) is a central challenge in near-term quantum chemistry. Existing adaptive methods such as ADAPT-VQE design circuits by iteratively selecting operators from…

Quantum Physics · Physics 2026-05-28 Jianpeng Chen , Zirui Sheng , Cunxi Gong , Weitang Li

We present a systematic hierarchy of approximations for {\it local} exact-decoupling of four-component quantum chemical Hamiltonians based on the Dirac equation. Our ansatz reaches beyond the trivial local approximation that is based on a…

Chemical Physics · Physics 2012-06-28 Daoling Peng , Markus Reiher

We extend Quantum Computing Quantum Monte Carlo (QCQMC) beyond ground-state energy estimation by systematically constructing the quantum circuits used for state preparation. Replacing the original Variational Quantum Eigensolver (VQE)…

The electron pair approximation offers a resource efficient variational quantum eigensolver (VQE) approach for quantum chemistry simulations on quantum computers. With the number of entangling gates scaling quadratically with system size…

Variational quantum eigensolver(VQE) typically minimizes energy with hybrid quantum-classical optimization, which aims to find the ground state. Here, we propose a VQE by minimizing energy variance, which is called as variance-VQE(VVQE).…

Quantum Physics · Physics 2020-06-30 Dan-Bo Zhang , Zhan-Hao Yuan , Tao Yin

In this paper, we firstly briefly review the duality quantum computer. Distinctly, the generalized quantum gates, the basic evolution operators in a duality quantum computer are no longer unitary, and they can be expressed in terms of…

Quantum Physics · Physics 2015-07-14 Shi-Jie Wei , Gui-Lu Long

We present a hybrid classical-quantum algorithm to solve optimization problems in current quantum computers, whose basic idea is to assist variational quantum eigensolvers (VQE) with adiabatic change of the Hamiltonian. The rational for…

Quantum Physics · Physics 2018-06-07 A. Garcia-Saez , J. I. Latorre

ADAPT-VQE is a robust algorithm for hybrid quantum-classical simulations of quantum chemical systems on near-term quantum computers. While its iterative process systematically reaches the ground state energy, ADAPT-VQE is sensitive to local…

We outline a procedure for applying Hamiltonian Truncation to Quantum Field Theories (QFTs) that have UV divergences. To do this, we derive a novel representation of an Effective Hamiltonian which makes manifest some of its important…

High Energy Physics - Theory · Physics 2023-07-26 Joan Elias Miro , James Ingoldby

Quantum control in large dimensional Hilbert spaces is essential for realizing the power of quantum information processing. For closed quantum systems the relevant input/output maps are unitary transformations, and the fundamental challenge…

Quantum Physics · Physics 2014-10-17 B. E. Anderson , H. Sosa-Martinez , C. A. Riofrío , I. H. Deutsch , P. S. Jessen

The relative power of quantum algorithms, using an adaptive access to quantum devices, versus classical post-processing methods that rely only on an initial quantum data set, remains the subject of active debate. Here, we present evidence…

Quantum Physics · Physics 2025-10-02 Oleksandr Kyriienko , Chukwudubem Umeano , Zoë Holmes
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