English
Related papers

Related papers: Highly Accurate Expectation Values Using High-Orde…

200 papers

The AlCrTiV high entropy alloy undergoes an order-disorder transition from body centered cubic (Strukturbericht A2) at high temperatures to the CsCl structure (B2) at intermediate temperatures. We model this transition using first…

Materials Science · Physics 2024-07-02 Michael Widom

An efficiency of the Tucker decomposition of amplitude tensors within the single-reference relativistic coupled cluster method with single and double excitations (RCCSD) was studied in a series of benchmark calculations for (AuCl)$_n$…

Computational Physics · Physics 2025-07-29 Alexander V. Oleynichenko , Artem S. Rumiantsev , Andrei Zaitsevskii , Ephraim Eliav

The multiconfiguration Dirac-Hartree-Fock (MCDHF) model has been employed to calculate the expectation values for the hyperfine splittings of the 5d96s2 2D3/2 and 5d96s2 2D5/2 levels of atomic gold. One-, two-, and three-body electron…

We consider QCD radiative corrections to top-quark pair production at hadron colliders. We use the $q_T$ subtraction formalism to perform a fully-differential computation for this process. Our calculation is accurate up to the…

High Energy Physics - Phenomenology · Physics 2016-01-27 Roberto Bonciani , Stefano Catani , Massimiliano Grazzini , Hayk Sargsyan , Alessandro Torre

We carry out first-principle calculations of scalar and tensor components of the static electric dipole polarizabilities of six low-lying states of lithium (Li), sodium (Na) and potassium (K) alkali atoms in the linear response approach.…

Atomic Physics · Physics 2025-04-22 A. Chakraborty , B. K. Sahoo

Molecules can form myriad crystalline polymorphs, each with distinct properties affecting their performance across diverse applications, from pharmaceuticals to functional materials and more. Predicting the thermodynamically most stable…

We have developed an efficient scheme for the calculation of transition properties within the four-component relativistic equation-of-motion coupled-cluster (EOM-CC) method using the expectation value approach. The calculation of transition…

We introduce a new augmented adaptation of the recently developed full coupled-cluster reduction (FCCR) with a second-order perturbative correction, abbreviated as FCCR(2). FCCR is a selected coupled-cluster expansion aimed at optimally…

Chemical Physics · Physics 2020-11-06 Enhua Xu , Motoyuki Uejima , Seiichiro L. Ten-no

We present a perturbative triples correction to the relativistic quadratic unitary coupled cluster singles and doubles (qUCCSD) method, denoted as qUCCSD[T]. The method builds upon the Hermitian structure of the unitary ansatz and employs a…

Chemical Physics · Physics 2025-10-08 Kamal Majee , Ján Šimunek , Jozef Noga , Achintya Kumar Dutta

Triggered by ongoing dark matter searches in the top quark sector at the Large Hadron Collider we report on the calculation of the next-to-leading order QCD corrections to the Standard Model process $pp\to t\bar{t}+ Z(\to \nu_\ell…

High Energy Physics - Phenomenology · Physics 2019-11-15 G. Bevilacqua , H. B. Hartanto , M. Kraus , T. Weber , M. Worek

Constructing a self-consistent first-principles framework that accurately predicts the properties of electron transfer reactions through finite-temperature molecular dynamics simulations is a dream of theoretical electrochemists and…

Chemical Physics · Physics 2024-09-18 Ryosuke Jinnouchi , Ferenc Karsai , Georg Kresse

This is the first in a series of papers, in which we compute the third-order QCD corrections to top-antitop production near threshold in e+ e- collisions. The present paper provides a detailed outline of the strategy of computation in the…

High Energy Physics - Phenomenology · Physics 2024-09-11 M. Beneke , Y. Kiyo , K. Schuller

We present NN potentials through five orders of chiral effective field theory ranging from leading order (LO) to next-to-next-to-next-to-next-to-leading order (N4LO). The construction may be perceived as consistent in the sense that the…

Nuclear Theory · Physics 2017-08-16 D. R. Entem , R. Machleidt , Y. Nosyk

Following our previous work focussing on compounds containing up to 3 non-hydrogen atoms [\emph{J. Chem. Theory Comput.} {\bfseries 14} (2018) 4360--4379], we present here highly-accurate vertical transition energies obtained for 27…

We have developed one electron detachment theory from a closed-shell atomic configuration in the relativistic Fock-space coupled-cluster ansatz. Using this method, we determine sensitivity coefficients to the variation of the fine structure…

Atomic Physics · Physics 2013-11-20 D. K. Nandy , B. K. Sahoo

We analyze the molecular electric dipole moments (PDMs) and static electric dipole polarizabilities of heteronuclear alkali dimers in their ground states by employing coupled-cluster theory, both in the non-relativistic and four-component…

Atomic Physics · Physics 2020-01-22 R. Mitra , V. S. Prasannaa , B. K. Sahoo

We present precise values of electric polarizabilities for the ground state of Zn due to second-order dipole and quadrupole interactions, and due to third-order dipole-quadrupole interactions. These quantities are evaluated in the linear…

Atomic Physics · Physics 2022-07-13 A. Chakraborty , S. K. Rithvik , B. K. Sahoo

In order to explore the effects of high levels of electron correlation on the real-time coupled cluster formalism and algorithmic behavior, we introduce a time-dependent implementation of the CC3 singles, doubles and approximate triples…

Chemical Physics · Physics 2025-01-23 Zhe Wang , Håkon Emil Kristiansen , Thomas Bondo Pedersen , T. Daniel Crawford

We introduce a new method for the computation of the transition moments between the excited electronic states based on the expectation value formalism of the coupled cluster theory [B. Jeziorski and R. Moszynski, Int. J. Quant. Chem. 48,…

Chemical Physics · Physics 2017-02-01 Aleksandra Tucholska , Michal Lesiuk , Robert Moszynski

We present the first fully differential next-to-next-to-leading order (NNLO) QCD calculation for the production of a top-antitop quark pair in association with a Higgs boson ($t \bar t H$) at hadron colliders. The computation is exact,…

High Energy Physics - Phenomenology · Physics 2025-03-27 Simone Devoto , Massimiliano Grazzini , Stefan Kallweit , Javier Mazzitelli , Chiara Savoini