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Dynamic nuclear polarization (DNP) is used in nuclear magnetic resonance (NMR) to transfer polarization from electron spins to nuclear spins. The resulting nuclear polarization enhancement can, in theory, be two or three orders of magnitude…

Quantum Physics · Physics 2015-10-14 Sarah Sheldon , David G. Cory

We introduce a method for the measurement of the lower bound on the initial polarization of spinful nuclei in a diamond by following the coherence evolution of an NV center spin qubit after a simple scheme is operated on the qubit to…

Quantum Physics · Physics 2026-02-24 Mateusz Kuniej , Katarzyna Roszak

Isolated nuclear spins offer a promising building block for quantum information processing systems, but their weak interactions often impede preparation, control, and detection. Hyperfine coupling to a proximal electronic spin can enhance…

Quantum Physics · Physics 2013-05-29 Benjamin Smeltzer , Jean McIntyre , Lilian Childress

Dynamic nuclear polarization (DNP) can increase nuclear magnetic resonance (NMR) signals by orders of magnitude. DNP in diamond proceeds through different DNP mechanisms with a possible temperature-dependence. We report on 13C dynamic…

Precise knowledge of a quantum system's Hamiltonian is a critical pre-requisite for its use in many quantum information technologies. Here, we report a method for the precise characterization of the non-secular part of the excited-state…

Quantum Physics · Physics 2017-06-20 F. Poggiali , P. Cappellaro , N. Fabbri

We experimentally isolate, characterize and coherently control up to six individual nuclear spins that are weakly coupled to an electron spin in diamond. Our method employs multi-pulse sequences on the electron spin that resonantly amplify…

Mesoscale and Nanoscale Physics · Physics 2012-10-23 T. H. Taminiau , J. J. T. Wagenaar , T. van der Sar , F. Jelezko , V. V. Dobrovitski , R. Hanson

We experimentally demonstrate a method for obtaining nuclear spin hyperpolarization, that is, polarization significantly in excess of that expected for a thermal equilibrium. By exploiting a modified Overhauser process, we obtain more than…

Materials Science · Physics 2009-02-26 D. R. McCamey , J. van Tol , G. W. Morley , C. Boehme

Dynamic nuclear polarization (DNP) enhances the intensity of NMR signals by transferring polarization from electron spins to nuclei via microwave irradiation. Pulsed DNP methods offer more control on the spin dynamics than conventional…

Chemical Physics · Physics 2026-01-07 Lorenzo Niccoli , Gian-Marco Camenisch , Matías Chávez , Matthias Ernst

An efficient technique to generate ensembles of spins that are highly polarized by external magnetic fields is the Holy Grail in Nuclear Magnetic Resonance (NMR) spectroscopy. Since spin-half nuclei have steady-state polarization biases…

Quantum Physics · Physics 2007-05-23 Jose M. Fernandez , Seth Lloyd , Tal Mor , Vwani Roychowdhury

We discuss the polarization dynamics during solid effect dynamic nuclear polarization (DNP) in a central spin model that consists of an electron surrounded by many nuclei. To this end we use a recently developed formalism and validate first…

Other Condensed Matter · Physics 2016-03-23 Daniel Wiśniewski , Alexander Karabanov , Igor Lesanovsky , Walter Köckenberger

Hyperpolarization of nuclear spins enhances nuclear magnetic resonance signals, which play a key role for imaging and spectroscopy in the natural and life sciences. This signal amplification unlocks previously inaccessible techniques, such…

Dynamic polarization protocols aim to hyperpolarize a spin bath by transferring spin polarization from a well-controlled qubit such as a quantum dot or a color defect. Building on techniques from shortcuts to adiabaticity, we design fast…

Quantum Physics · Physics 2021-02-17 Tamiro Villazon , Pieter W. Claeys , Anatoli Polkovnikov , Anushya Chandran

We consider the problem of determining the spectrum of an electronic spin via polarization transfer to coupled nuclear spins and their subsequent readout. This suggests applications for employing dynamic nuclear polarization (DNP) for…

Quantum Physics · Physics 2021-10-19 Moniish Elanchezhian , Arjun Pillai , Teemu Virtanen , Ashok Ajoy

Optically addressable molecular triplet spins provide a chemically tunable platform for quantum application, but their coherence is often limited by interactions with surrounding spin baths. Here we demonstrate controlled suppression of…

Nuclear spins in the solid state environment of diamond are highly coherent, but difficult to rapidly control due to the small nuclear gyromagnetic ratio. Here we demonstrate a more than 50-fold enhancement of the effective nuclear…

Mesoscale and Nanoscale Physics · Physics 2016-08-05 S. Sangtawesin , J. R. Petta

We report hyperpolarization of the electronic spins associated with substitutional nitrogen defects in bulk diamond crystal. Hyperpolarization is achieved by optical pumping of nitrogen vacancy centers followed by rapid cross relaxation at…

Mesoscale and Nanoscale Physics · Physics 2017-02-22 M. Loretz , H. Takahashi , T. F. Segawa , J. M. Boss , C. L. Degen

SABRE (Signal Amplification By Reversible Exchange) has become a widely used method for hyper-polarizing nuclear spins, thereby enhancing their Nuclear Magnetic Resonance (NMR) signals by orders of magnitude. In SABRE experiments,…

Chemical Physics · Physics 2020-12-02 Stephan Knecht , Danila A. Barskiy , Gerd Buntkowsky , Konstantin L. Ivanov

In this work we investigated the time behavior of the polarization of bulk 13C nuclei in diamond above the thermal equilibrium. This nonthermal nuclear hyperpolarization is achieved by cross relaxation between two nitrogen related…

Mesoscale and Nanoscale Physics · Physics 2018-08-01 Ralf Wunderlich , Jonas Kohlrautz , Bernd Abel , Jürgen Haase , Jan Meijer

Dynamic nuclear polarization (DNP) involves a polarization transfer from unpaired electrons to hyperfine coupled nuclei and can increase the sensitivity of nuclear magnetic resonance (NMR) signals by several orders of magnitude. The…

Chemical Physics · Physics 2024-07-16 Gevin von Witte , Sebastian Kozerke , Matthias Ernst

Nuclear spin polarization plays a crucial role in quantum information processing and quantum sensing. In this work, we demonstrate a robust and efficient method for nuclear spin polarization with boron vacancy ($\mathrm{V_B^-}$) defects in…

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