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Recently (Science, 355, 6320, 2017, 49-52) it was argued that density functionals stray from the path towards exactness due to errors in densities (\rho) of 14 atoms and ions computed with several recent functionals. However, this…

Chemical Physics · Physics 2017-11-16 Kasper Planeta Kepp

Robust tests of general composite hypothesis under non-identically distributed observations is always a challenge. Ghosh and Basu (2018, Statistica Sinica, 28, 1133--1155) have proposed a new class of test statistics for such problems based…

Statistics Theory · Mathematics 2019-01-08 Abhik Ghosh , Ayanendranath Basu

A homogenization result for a family of integral energies is presented, where the fields are subjected to periodic first order oscillating differential constraints in divergence form. The work is based on the theory of A -quasiconvexity…

Analysis of PDEs · Mathematics 2015-08-21 Elisa Davoli , Irene Fonseca

In order to assess the accuracy of commonly used approximate exchange-correlation density functionals, we present a comparison of accurate exchange and correlation potentials, exchange energy densities and energy components with the…

Condensed Matter · Physics 2007-05-23 Claudia Filippi , Xavier Gonze , C. J. Umrigar

It is by now well known that, at subleading power in scale ratios, factorization theorems for high-energy cross sections and decay amplitudes contain endpoint-divergent convolution integrals. The presence of these divergences hints at a…

High Energy Physics - Phenomenology · Physics 2020-04-06 Ze Long Liu , Matthias Neubert

The universal density functional $F$ of density-functional theory is a complicated and ill-behaved function of the density-in particular, $F$ is not differentiable, making many formal manipulations more complicated. Whilst $F$ has been well…

Chemical Physics · Physics 2015-06-18 Simen Kvaal , Ulf Ekström , Andrew M. Teale , Trygve Helgaker

Density functional theory is the workhorse of chemistry and materials science, and novel density functional approximations (DFAs) are published every year. To become available in program packages, the novel DFAs need to be (re)implemented.…

Computational Physics · Physics 2023-09-20 Susi Lehtola , Miguel A. L. Marques

We study the interactions between two negatively charged macroscopic surfaces confining positive counterions. A density-functional approach is introduced which, besides the usual mean-field interactions, takes into account the correlations…

Soft Condensed Matter · Physics 2015-06-25 A. Diehl , M. N. Tamashiro , Marcia C. Barbosa , Yan Levin

We introduce the concept of a disjoint partial difference family (DPDF) and an external partial difference family (EPDF), a natural generalisation of the much-studied structures of disjoint difference family (DDF), external difference…

Combinatorics · Mathematics 2022-12-21 Sophie Huczynska , Laura Johnson

The Hohenberg-Kohn theorem of density-functional theory (DFT) is broadly considered the conceptual basis for a full characterization of an electronic system in its ground state by just the one-body particle density. Part I of this review…

Density functional theory (DFT) is a powerful theoretical tool widely used in such diverse fields as computational condensed matter physics, atomic physics, and quantum chemistry. DFT establishes that a system of $N$ interacting electrons…

Plasma Physics · Physics 2020-04-29 Giovanni Manfredi

To speak about fundamental measure theory obliges to mention dimensional crossover. This feature, inherent to the systems themselves, was incorporated in the theory almost from the beginning. Although at first it was thought to be a…

Statistical Mechanics · Physics 2009-11-10 Luis Lafuente , Jose A. Cuesta

For a family $\mathcal{F}$ of subsets of a finite set, define $\mathcal{D}(\mathcal{F})=\{F\setminus F': F, F'\in\mathcal{F}\}$. A family $\mathcal{F}$ is called intersecting if $F\cap F'\not=\emptyset$ for all $F, F'\in\mathcal{F}$. Frankl…

Combinatorics · Mathematics 2024-12-02 Yan zilong , Peng Yuejian

In this work, we define a family of probability densities involving the generalized trigonometric functions defined by Dr\'abek and Man\'asevich [1], which we name Generalized Trigonometric Densities. We show their relationship with the…

Mathematical Physics · Physics 2025-04-01 David Puertas-Centeno , Steeve Zozor

Introduced by M\"uller et al. in their seminal paper \cite{muller}, fractional stochastic dominance (SD) offers a nuanced approach to ordering distributions. In this paper, we propose a fundamentally new framework by replacing the fixed…

Mathematical Finance · Quantitative Finance 2025-02-13 Ehsan Azmoodeh , Ozan Hür

The crucial step in density-corrected Hartree-Fock density functional theory (DC(HF)-DFT) is to decide whether the density produced by the density functional for a specific calculation is erroneous and hence should be replaced by, in this…

Chemical Physics · Physics 2023-09-20 Daniel Graf , Alex J. W. Thom

A density-functional theory is developed based on the Maxwell--Schr\"odinger equation with an internal magnetic field in addition to the external electromagnetic potentials. The basic variables of this theory are the electron density and…

Chemical Physics · Physics 2018-01-17 Erik Tellgren

(Abridged) We investigate the power of void statistics to constrain galaxy bias and the amplitude of dark matter fluctuations. We use the halo occupation distribution (HOD) framework to describe the relation between galaxies and dark…

Astrophysics · Physics 2011-02-11 Jeremy L. Tinker , David H. Weinberg , Michael S. Warren

Density functional theory (DFT) is an essential building block for modern theoretical physics, chemistry, and engineering, especially those concerning electronic properties. Through decades of development, various program packages for…

Materials Science · Physics 2022-11-21 Yusuke Nomura , Ryosuke Akashi

Standard density functional approximations often give questionable results for odd-electron radical complexes, with the error typically attributed to self-interaction. In density corrected density functional theory (DC-DFT), certain classes…

Chemical Physics · Physics 2015-06-19 Min-Cheol Kim , Eunji Sim , Kieron Burke