Related papers: Gas-phase formation routes of dimethyl sulfide in …
Following the discovery of dimethyl sulfide (CH$_3$SCH$_3$, DMS) signatures in comet 67P/Churyumov-Gerasimenko, we report the first detection of this organosulfur species in the interstellar medium, during the exploration of an ultradeep…
Dimethyl ether is one of the most abundant interstellar complex organic molecules. Yet its formation route remains elusive. In this work, we have performed electronic structure and kinetics calculations to derive the rate coefficients for…
The formation pathways of sulfur-bearing species in the interstellar medium are crucial to understand astrochemical processes in cold molecular clouds and to gain new insights about the sulfur budget in these regions. We aim to explore the…
The organosulfur biosignature gases dimethylsulfide (DMS) and dimethlydisulfide (DMDS) have recently been claimed to be present in the atmosphere of sub-Neptune exoplanet K2-18b, leading to the suggestion of possible extraterrestrial life.…
Recent astronomical observations have shown that interstellar complex organic molecules (COMs) exist even in cold environments ($\sim$10 K), while various interstellar COMs have conventionally been detected in the hot gas ($\gtrsim$ 100 K)…
Technological progress related to astronomical observatories such as the recently launched James Webb Space Telescope (JWST) allows searching for signs of life beyond our Solar System, namely in the form of unambiguous biosignature gases in…
Methyl cyanide (CH$_3$CN) is one of the most abundant and widely spread interstellar complex organic molecules (iCOMs). Several studies found that, in hot corinos, methyl cyanide and methanol abundances are correlated suggesting a chemical…
This work was carried out with using the Caltech Submillimeter Observatory and presents the observational study of HDS and D2S towards a sample of Class 0 sources, and dense cores. We report the first detection of doubly deuterated hydrogen…
The interaction between dust, ice, and gas during the formation of stars produces complex organic molecules. While observations indicate that several species are formed on ice-covered dust grains and are released into the gas phase, the…
Among all the interstellar complex organic molecules (iCOMs), acetaldehyde is one of the most widely detected species. The question of its formation route(s) is, therefore, of a major interest regarding astrochemical models. In this paper,…
Context. Recent Monte Carlo simulations and laboratory studies of interstellar ices have proposed an alternative pathway involving the radical-molecule H-atom abstraction reaction in the overall mechanism of methanol (CH3OH) formation in…
Our automated reaction discovery program, AutoMeKin, has been utilized to investigate the formation of glycolonitrile (HOCH$_{2}$CN) in the gas phase under the low temperatures of the interstellar medium (ISM). The feasibility of a proposed…
In recent years the chemistry of sulfur in the interstellar medium has experienced a renewed interest due to the detection of a large variety of molecules containing sulfur. Here we report the first identification in space of a new…
The chemical network governing interstellar sulfur has been the topic of unrelenting discussion for the past decades due to the conspicuous discrepancy between its expected and observed abundances in different interstellar environments.…
Grain-surface chemistry plays a crucial role in the formation of molecules of astrobiological interest, including H$_{2}$S and complex organic molecules (COMs). They are commonly observed in the gas phase toward star-forming regions, but…
The formation of complex organic molecules in the interstellar medium (ISM) is central to astrochemistry and prebiotic chemistry, as these species may act as precursors to biomolecules essential for life. Although glyceraldehyde…
The complex organic molecules (COMs) detected in star-forming regions are the precursors of the prebiotic molecules that can lead to the emergence of life. By studying COMs in more evolved protoplanetary disks we can gain a better…
Methyl formate, HCOOCH$_3$, and many of its isotopologues have been detected in astrophysical regions with considerable abundances. However, the recipe for the formation of this molecule and its isotopologues is not yet known. In this work,…
Forty years ago it was proposed that gas phase organic chemistry in the interstellar medium was initiated by the methyl cation CH3+, but hitherto it has not been observed outside the Solar System. Alternative routes involving processes on…
The formation of methanol (CH3OH) on icy grain mantles during the star formation cycle is mainly associated with the CO freeze-out stage. Yet there are reasons to believe that CH3OH also can form at an earlier period of interstellar ice…