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The dynamical effects of ground state correlations for excitation energies and transition strengths near the superfluid phase transition are studied in the soluble two level pairing model, in the context of the particle-particle self…

Nuclear Theory · Physics 2008-11-26 E. J. V. de Passos , A. F. R. de Toledo Piza , F. Krmpotić

A new Quasiparticle Random Phase Approximation approach is presented. The corresponding ground state is variationally determined and exhibits a minimum energy. New solutions for the ground state, some with spontaneously broken symmetry, of…

Nuclear Theory · Physics 2008-11-26 F. Simkovic , M. Smotlak , A. A. Raduta

We recently demonstrated a connection between the random phase approximation (RPA) and coupled cluster theory [J. Chem. Phys. 129, 231101 (2008)]. Based on this result, we here propose and test a simple scheme for introducing long-range RPA…

Materials Science · Physics 2009-11-13 Benjamin G. Janesko , Thomas M. Henderson , Gustavo E. Scuseria

We introduce a spectral density functional theory which can be used to compute energetics and spectra of real strongly--correlated materials using methods, algorithms and computer programs of the electronic structure theory of solids. The…

Strongly Correlated Electrons · Physics 2009-11-10 S. Y. Savrasov , G. Kotliar

We develop a stochastic formulation of the optimally-tuned range-separated hybrid density functional theory which enables significant reduction of the computational effort and scaling of the non-local exchange operator at the price of…

Chemical Physics · Physics 2016-09-28 Daniel Neuhauser , Eran Rabani , Yael Cytter , Roi Baer

We introduce an alternative route to quasiparticle self-consistent $GW$ calculations ($\mathrm{qs}GW$) on the basis of a Joint Approximate Diagonalization of the one-body $GW$ Green's functions $G(\varepsilon_n^{QP})$ taken at the input…

Materials Science · Physics 2024-12-05 Ivan Duchemin , Xavier Blase

The action of the long-range residual force on the expectation value of observables in the nuclear ground states is evaluated by finding optimal values for the coefficients of the canonical transformation which connects the phonon vacuum…

Nuclear Theory · Physics 2015-06-12 S. Mishev

We study the reliability of the constrained random phase approximation (cRPA) method for the calculation of low-energy effective Hamiltonians by considering multi-orbital lattice models with one strongly correlated "target" band and two…

Strongly Correlated Electrons · Physics 2015-07-24 Hiroshi Shinaoka , Matthias Troyer , Philipp Werner

During the last decade, ab initio methods to calculate electronic structure of materials based on hybrid functionals are increasingly becoming widely popular. In this Letter, we show that, in the case of small gap transition metal oxides,…

Strongly Correlated Electrons · Physics 2013-06-21 John E. Coulter , Efstratios Manousakis , Adam Gali

The Gaussian expansion method (GEM) is extensively applied to the calculations in the random-phase approximation (RPA). We adopt the mass-independent basis-set that has been tested in the mean-field calculations. By comparing the RPA…

Nuclear Theory · Physics 2015-05-13 H. Nakada , K. Mizuyama , M. Yamagami , M. Matsuo

By using the quantum Ising chain as a test bed and treating the spin polarization along the external transverse field as the "generalized density", we examine the performance of different levels of density functional approximations parallel…

Computational Physics · Physics 2021-10-27 Jiahao Mao , Haifeng Tang , Wenhui Duan , Zheng Liu

The self-consistent random-phase approximation (SCRPA) is reexamined within a multilevel-pairing model with double degeneracy. It is shown that the expressions for occupation numbers used in the original version of SCRPA violate the…

Nuclear Theory · Physics 2009-11-10 Nguyen Dinh Dang

We use a fully self-consistent Hartree$-$Fock (HF) based continuum random phase approximation (CRPA) to calculate strength functions $S(E)$ and transition densities $\rho_t(r)$ for isoscalar giant resonances with multipolarities $L = 0$, 1…

Nuclear Theory · Physics 2009-11-07 B. K. Agrawal , S. Shlomo , A. I. Sanzhur

The accuracy of calculations of atomic Rydberg excitations cannot be judged by the usual measures, such as mean unsigned errors of many transitions. We show how to use quantum defect theory to (a) separate errors due to approximate…

Chemical Physics · Physics 2016-05-04 Yang Yang , Kieron Burke , Weitao Yang

We recently introduced an efficient methodology to perform density-corrected Hartree-Fock density functional theory (DC(HF)-DFT) calculations and an extension to it we called "corrected" HF DFT (C(HF)-DFT). In this work, we take a further…

Chemical Physics · Physics 2023-11-10 Daniel Graf , Alex J. W. Thom

In recent work, generalized gradient approximations (GGA's) have been constructed from the energy density of the Airy gas for exchange but not for correlation. We report the random phase approximation (RPA) conventional correlation energy…

Materials Science · Physics 2009-06-30 Lucian A. Constantin , Adrienn Ruzsinszky , John P. Perdew

The partition function by means of the static path approximation (SPA) plus the random-phase approximation (RPA) treatment can be written as a contour integral form without solving the RPA equations for a separable interaction. This method…

Nuclear Theory · Physics 2009-11-11 K. Kaneko , M. Hasegawa

A low-cost approach for stochastically sampling static exchange during TDHF-type propagation is presented. This enables the use of an excellent hybrid DFT starting point for stochastic GW quasiparticle energy calculations. Generalized…

Chemical Physics · Physics 2025-03-11 Tucker Allen , Minh Nguyen , Daniel Neuhauser

Accurately modeling the electronic structure of materials is a persistent challenge to high-throughput screening. A promising means of balancing accuracy against computational cost are non-self-consistent calculations with hybrid…

Materials Science · Physics 2020-05-04 Jonathan M. Skelton , David S. D. Gunn , Sebastian Metz , Stephen C. Parker

Kohn-Sham density functional theory (DFT) is the standard method for first-principles calculations in computational chemistry and materials science. More accurate theories such as the random-phase approximation (RPA) are limited in…

Materials Science · Physics 2023-10-25 Stefan Riemelmoser , Carla Verdi , Merzuk Kaltak , Georg Kresse