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We consider a class of deterministic local collisional dynamics, showing how to approximate them by means of stochastic models and then studying the fluctuations of the current of energy. We show first that the variance of the…

Mathematical Physics · Physics 2015-05-19 Raphael Lefevere , Mauro Mariani , Lorenzo Zambotti

Markov State Models (MSM) are widely used to elucidate dynamic properties of molecular systems from unbiased Molecular Dynamics (MD). However, the implementation of reweighting schemes for MSMs to analyze biased simulations, for example…

Chemical Physics · Physics 2020-11-26 Stefanie Kieninger , Luca Donati , Bettina G. Keller

In this work we elaborate on two recently discovered invariance principles, according to which transport coefficients are, to a large extent, independent of the microscopic definition of the densities and currents of the conserved…

Statistical Mechanics · Physics 2021-07-20 Federico Grasselli , Stefano Baroni

The transport coefficient of shear viscosity is studied for a hadron matter through microscopic transport model, the Ultra--relativistic Quantum Molecular Dynamics (UrQMD), using the Green--Kubo formulas. Molecular--dynamical simulations…

Nuclear Theory · Physics 2009-11-10 Azwinndini Muronga

We propose an adaptive importance sampling scheme for the simulation of rare events when the underlying dynamics is given by a diffusion. The scheme is based on a Gibbs variational principle that is used to determine the optimal (i.e.…

Probability · Mathematics 2019-07-24 Carsten Hartmann , Omar Kebiri , Lara Neureither , Lorenz Richter

We show how to evaluate mobility profiles, characterizing the transport of confined fluids under a perturbation, from equilibrium molecular simulations. The correlation functions derived with the Green-Kubo formalism are difficult to sample…

Chemical Physics · Physics 2020-08-26 Etienne Mangaud , Benjamin Rotenberg

The purpose of this study is to provide a reproducible framework in the use of the Green-Kubo formalism to extract transport coefficients. More specifically, in the case of shear viscosity, we investigate the limitations and technical…

Nuclear Theory · Physics 2018-07-04 J. -B. Rose , J. M. Torres-Rincon , D. Oliinychenko , A. Schäfer , H. Petersen

Directly computing mass transport coefficients in stochastic models requires integrating over time the equilibrium correlations between atomic displacements. Here, we show how to accelerate the computations via \green{correlation splitting…

Materials Science · Physics 2021-12-06 Manuel Athènes , Gilles Adjanor , Jérôme Creuze

Thermal transport coefficients are independent of the specific microscopic expression for the energy density and current from which they can be derived through the Green-Kubo formula. We discuss this independence in terms of a kind of gauge…

Statistical Mechanics · Physics 2017-06-09 Loris Ercole , Aris Marcolongo , Paolo Umari , Stefano Baroni

Molecular dynamics (MD) simulations are used to calculate transport coefficients in a two-component plasma interacting through a repulsive Coulomb potential. The thermal conductivity, electrical conductivity, electrothermal coefficient,…

Plasma Physics · Physics 2025-11-14 Briggs Damman , Jarett LeVan , Scott Baalrud

Near equilibrium, Green-Kubo relations provide microscopic expressions for macroscopic transport coefficients in terms of equilibrium correlation functions. At their core, they are based on the intimate relationship between response and…

Statistical Mechanics · Physics 2021-12-16 Hyun-Myung Chun , Qi Gao , Jordan M. Horowitz

Green-Kubo and Einstein expressions for the transport coefficients of a fluid in a nonequilibrium steady state can be derived using the Fluctuation Theorem and by assuming the probability distribution of the time-averaged dissipative flux…

Statistical Mechanics · Physics 2009-10-31 Debra J. Searles , Denis J. Evans

We introduce $\pi$-Girsanov, a new method for constructing Markov state models from biased enhanced-sampling molecular dynamics simulations based on Girsanov reweighting. The key idea behind this new method is to separate the reweighting…

Biological Physics · Physics 2026-03-24 Mingyuan Zhang , Yong Wang , Bettina G. Keller , Hao Wu

We present a microscopic derivation of the laws of continuum mechanics of nonideal ordered solids including dissipation, defect diffusion, and heat transport. Starting point is the classical many-body Hamiltonian. The approach relies on the…

Statistical Mechanics · Physics 2022-11-23 Florian Miserez , Saswati Ganguly , Rudolf Haussmann , Matthias Fuchs

Gribov quantization is a method to improve the infrared dynamics of Yang-Mills theory. We study the thermodynamics and transport properties of a plasma consisting of gluons whose propagator is improved by the Gribov prescription. We first…

High Energy Physics - Phenomenology · Physics 2020-11-17 Amaresh Jaiswal , Najmul Haque

We propose a first-principles method of efficiently evaluating electron-transport properties of very long systems. Implementing the recursive Green's function method and the shifted conjugate gradient method in the transport simulator based…

Mesoscale and Nanoscale Physics · Physics 2021-01-20 Yoshiyuki Egami , Shigeru Tsukamoto , Tomoya Ono

In Part I of this two-part series, the reverse perturbation method for shearing simple liquids [Phys. Rev. E 59, 4894 (1999)] was extended to systems of interacting particles with time-discrete stochastic dynamics. For verification, in this…

Soft Condensed Matter · Physics 2019-10-16 Arash Nikoubashman , Thomas Ihle

We commonly encounter the problem of identifying an optimally weight adjusted version of the empirical distribution of observed data, adhering to predefined constraints on the weights. Such constraints often manifest as restrictions on the…

Machine Learning · Statistics 2024-01-17 Abhisek Chakraborty , Anirban Bhattacharya , Debdeep Pati

Building upon recent developments of force-based estimators with a reduced variance for the computation of densities, radial distribution functions or local transport properties from molecular simulations, we show that the variance can be…

Chemical Physics · Physics 2021-05-18 Samuel W. Coles , Etienne Mangaud , Daan Frenkel , Benjamin Rotenberg

We implement, optimize, and validate the linear-scaling Kubo-Greenwood quantum transport simulation on graphics processing units by examining resonant scattering in graphene. We consider two practical representations of the Kubo-Greenwood…

Mesoscale and Nanoscale Physics · Physics 2014-02-14 Zheyong Fan , Andreas Uppstu , Topi Siro , Ari Harju