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Coulomb attraction between electrons and holes in a narrow-gap semiconductor or a semimetal is predicted to lead to an elusive phase of matter dubbed 'excitonic insulator'. However, direct observation of such electronic instability remains…

Strongly Correlated Electrons · Physics 2021-08-09 Kwangrae Kim , Hoon Kim , Jonghwan Kim , Changil Kwon , Jun Sung Kim , B. J. Kim

Ta$_2$NiSe$_5$ is an excitonic insulator candidate showing the semiconductor/semimetal-to-insulator (SI) transition below $T_{\text{c}}$ = 326 K. However, since a structural transition accompanies the SI transition, deciphering the role of…

The structural phase transition in Ta$_2$NiSe$_5$ has been envisioned as driven by the formation of an excitonic insulating phase. However, the role of structural and electronic instabilities on crystal symmetry breaking has yet to be…

The formation of excitonic insulator phases in quantum materials is often masked by structural distortions caused by the coupling between electronic and phononic order parameters. Here we show that the candidate material Ta$_2$NiSe$_5$ is…

Strongly Correlated Electrons · Physics 2026-02-02 Giacomo Mazza

The origin of the second order phase transition at 328K in Ta$_2$NiSe$_5$, a prominent candidate for direct gap excitonic insulator, remains under fervent debate. The driving force for the transition can be revealed by identification of the…

Strongly Correlated Electrons · Physics 2021-03-05 G. Blumberg

Recently, we employed electronic polarization-resolved Raman spectroscopy to reveal the strongly correlated excitonic insulator (EI) nature of Ta2NiSe5, Volkov et al. [arXiv:2007.07344], and also showed that for…

Strongly Correlated Electrons · Physics 2021-07-20 Mai Ye , Pavel A. Volkov , Himanshu Lohani , Irena Feldman , Minsung Kim , Amit Kanigel , Girsh Blumberg

Realizing an excitonic insulator phase from narrow-gap semiconductors remains challenging, as unambiguous experimental signatures are difficult to establish. Ta$_2$NiSe$_5$ has been widely regarded as a leading candidate, yet the nature of…

Materials Science · Physics 2025-12-11 Keyu Wei , Yixuan Luo , Kenji Watanabe , Takashi Taniguchi , Yanfeng Guo , Xiaoxiang Xi

The excitonic insulator is an electronically-driven phase of matter that emerges upon the spontaneous formation and Bose condensation of excitons. Detecting this exotic order in candidate materials is a subject of paramount importance, as…

Ta$_2$NiSe$_5$ became one of the most investigated candidate materials for hosting an excitonic insulator ground state. Many studies describe the corresponding phase transition as a condensation of excitons breaking a continuous symmetry.…

Strongly Correlated Electrons · Physics 2021-03-04 Min-Jae Kim , Armin Schulz , Tomohiro Takayama , Masahiko Isobe , Hidenori Takagi , Stefan Kaiser

The high-temperature phase of Ta$_\mathrm{2}$NiSe$_\mathrm{5}$, a near-zero-gap semiconductor ($E_G$ = 0), is a promising candidate for an excitonic insulator. Given the dome-like evolution expected for an excitonic insulator around $E_G$,…

Ta$_2$NiSe$_5$ continues to draw interest for its 326 K phase transition, whose dual electronic and structural nature reflects a complex interplay of electron-hole (excitonic) and electron-lattice interactions. Most studies that have…

Strongly Correlated Electrons · Physics 2025-12-16 Yuan-Shan Zhang , Zichen Yang , Chuanlian Xiao , Masahiko Isobe , Matteo Minola , Hidenori Takagi , Dennis Huang

We present a combined study from angle-resolved photoemission and density-functional theory calculations of the temperature-dependent electronic structure in the excitonic insulator candidate Ta$_2$NiSe$_5$. Our experimental measurements…

We investigate an interesting anisotropic van der Waals material, Ta$_{2}$NiSe$_{5}$, using optical spectroscopy. Ta$_{2}$NiSe$_{5}$ has been known as one of the few excitonic insulators proposed over 50 years ago. Ta$_{2}$NiSe$_{5}$ has…

Materials Science · Physics 2018-08-21 Yu-Seong Seo , Man Jin Eom , Jun Sung Kim , Chang-Jong Kang , Byung Il Min , Jungseek Hwang

TiSe$_2$ is thought to be an insulator with a bandgap of ~0.1eV. It has attracted a much interest because, among of a rich array of unique properties, many have thought TiSe$_2$ is a rare realisation of an excitonic insulator. Below 200 K,…

Materials Science · Physics 2025-06-10 Ross E. Larsen , Dimitar Pashov , Matthew D. Watson , Swagata Acharya , Mark van Schilfgaarde

The microscopic quantum interference associated with excitonic condensation in Ta$_2$NiSe$_5$ is studied in the BCS-type mean-field approximation. We show that in ultrasonic attenuation the coherence peak appears just below the transition…

Strongly Correlated Electrons · Physics 2016-01-19 Koudai Sugimoto , Tatsuya Kaneko , Yukinori Ohta

Excitonic insulator is a coherent electronic phase that results from the formation of a macroscopic population of bound particle-hole pairs - excitons. With only a few candidate materials known, the collective excitonic behavior is…

Strongly Correlated Electrons · Physics 2021-05-27 Pavel A. Volkov , Mai Ye , Himanshu Lohani , Irena Feldman , Amit Kanigel , Girsh Blumberg

The excitonic insulator is an intriguing correlated electron phase formed of condensed excitons. A promising candidate is the small band gap semiconductor Ta2NiSe5. Here we investigate the quasiparticle and coherent phonon dynamics in…

Strongly Correlated Electrons · Physics 2018-08-01 Daniel Werdehausen , Tomohiro Takayama , Gelon Albrecht , Yangfan Lu , Hidenori Takagi , Stefan Kaiser

Excitonic insulator (EI) was proposed in 60's as a distinct insulating state originating from pure electronic interaction, but its material realization has been elusive with extremely few material candidates and with only limited evidence…

Materials Science · Physics 2019-03-06 Jinwon Lee , Chang-Jong Kang , Man Jin Eom , Jun Sung Kim , Byung Il Min , Han Woong Yeom

We study the electronic phase diagram of the excitonic insulator candidates Ta$_2$Ni(Se$_{1-x}$S$_x$)$_5$ [x=0, ... ,1] using Raman spectroscopy. Critical excitonic fluctuations are observed, that diminish with $x$ and ultimately shift to…

Strongly Correlated Electrons · Physics 2021-12-30 Pavel A. Volkov , Mai Ye , Himanshu Lohani , Irena Feldman , Amit Kanigel , Girsh Blumberg

The spontaneous condensation of excitons in the excitonic insulating phase has been reported in Ta$_2$NiSe$_5$ below 325 K. In this context, we present the temperature-dependent optical pump optical probe spectroscopy of Ta$_2$NiSe$_5$,…

Materials Science · Physics 2024-12-02 Vikas Arora , Sukanya Pal , Luminita Harnagea , D. V. S. Muthu , A K Sood
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