Related papers: Tracing long-lived atomic coherences generated via…
The basic properties of atoms, molecules and solids are governed by electron dynamics which take place on extremely short time scales. To measure and control these dynamics therefore requires ultrafast sources of radiation combined with…
Quantum coherence remains a fundamental challenge for advancing quantum technologies. Although dynamical decoupling can suppress decoherence noise, it frequently misestimates decoherence times due to control errors -- a previously…
A scattering resonance is one of the most striking quantum effects in low-temperature molecular collisions. Predicted decades ago theoretically, they have only been resolved experimentally for systems involving at most four atoms. Extension…
Establishing the fundamental chemical principles that govern molecular electronic quantum decoherence has remained an outstanding challenge. Fundamental questions such as how solvent and intramolecular vibrations or chemical…
Minimizing decoherence due to coupling of a quantum system to its fluctuating environment is at the forefront of quantum information science and photonics research. Nature sets the ultimate limit, however, given by the strength of the…
Quantum states inevitably decay with time into a probabilistic mixture of classical states, due to their interaction with the environment and measurement instrumentation. We present the first measurement of the decoherence dynamics of…
(The systematics of photon absorption cross sections in nuclei and small metal particles are examined as a function of the number of constituent fermions $A$. It is pointed out that the shell-structure-linked oscillations in the full width…
We investigate orbital alignment dynamics within the valence shell of atoms in coherently excited $j=3/2,1/2$ fine-structure manifolds generated by short-pulse photodetachment of F$^-$, Cl$^-$ and Br$^-$ anions. Using Keldysh-type theory,…
Modern imaging techniques at the molecular scale rely on utilizing novel coherent light sources like X-ray free electron lasers for the ultimate goal of visualizing such objects as individual biomolecules rather than crystals. Here, unlike…
The nuclear spin, being much more isolated from the environment than its electronic counterpart, enables quantum experiments with prolonged coherence times and presents a gateway towards uncovering the intricate dynamics within an atom.…
Semiconductor quantum dot molecules are considered as promising candidates for quantum technological applications due to their wide tunability of optical properties and coverage of different energy scales associated with charge and spin…
We have investigated the structural dynamics in photoexcited 1,2-diiodotetrafluoroethane molecules (C2F4I2) in the gas phase experimentally using ultrafast electron diffraction and theoretically using FOMO-CASCI excited state dynamics…
High harmonic light sources make it possible to access attosecond time-scales, thus opening up the prospect of manipulating electronic wave packets for steering molecular dynamics. However, two decades after the birth of attosecond physics,…
The effect of conical intersections (CIs) on electronic relaxation, transitions from excited states to ground states, is well studied, but their influence on hyperfine quenching in a reactant molecule is not known. Here, we report on…
Rydberg atoms excited by cold blackbody radiation are shown to display long-lived quantum coherences on timescales of tens of picoseconds. By solving non-Markovian equations of motion with no free parameters we obtain the time evolution of…
We studied the mechanism of half-metallicity (HM) formation in transition metal doped (TM) conjugated carbon based structures by first-principles electronic structure simulations. It is found that the HM is a rather complex phenomenon,…
The electronic spin degrees of freedom in semiconductors typically have decoherence times that are several orders of magnitude longer than other relevant timescales. A solid-state quantum computer based on localized electron spins as qubits…
In the quantum degenerate regime, atoms and molecules can occupy a single quantum state, forming coherent matter waves. Here reactions are described by nonlinear mixing of the matter waves, giving rise to quantum many-body chemistry, where…
Conical intersections constitute the conceptual bedrock of our working understanding of ultrafast, nonadiabatic processes within photochemistry (and photophysics). Accurate calculation of potential energy surfaces within the vicinity of…
Photosystem II (PSII) reaction center is a unique protein-chromophore complex that is capable of efficiently separating electronic charges across the membrane after photoexcitation. In the PSII reaction center, the primary energy- and…