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This paper investigates the identifiability and estimation of the parameters of the single particle model (SPM) for lithium-ion battery simulation. Identifiability is addressed both in principle and in practice. The approach begins by…

Systems and Control · Computer Science 2018-10-03 Adrien M. Bizeray , Jin-Ho Kim , Stephen R. Duncan , David A. Howey

The Single-Particle Model (SPM) of Li ion cell \cite{Santhanagopalan06, Guo2011} is a computationally efficient and fairly accurate model for simulating Li ion cell cycling behavior at weak to moderate currents. The model depends on a large…

Computational Physics · Physics 2019-12-13 Michael Khasin , Chetan S. Kulkarni , Kai Goebel

The single particle model (SPM) is a reduced electrochemical model that holds promise for applications in battery management systems due to its ability to accurately capture battery dynamics; however, the numerical discretization of the SPM…

Systems and Control · Electrical Eng. & Systems 2024-10-11 Joseph N. E. Lucero , Le Xu , Simona Onori

The rapid spread of Lithium-ions batteries (LiBs) for electric vehicles calls for the development of accurate physical models for Battery Management Systems (BMSs). In this work, the electrochemical Single Particle Model (SPM) for a…

Systems and Control · Electrical Eng. & Systems 2023-11-30 Andrea Trivella , Matteo Corno , Stefano Radrizzani , Sergio M. Savaresi

Lithium-ion battery (LIB) sources have played an essential role in self-sustained transportation energy systems and have been widely deployed in the last few years. To realize reliable battery maintenance, identifying its electrochemical…

Systems and Control · Electrical Eng. & Systems 2023-03-15 Yuxuan Gu , Jianxiao Wang , Yuanbo Chen , Kedi Zheng , Zhongwei Deng , Qixin Chen

Parameter identification for electrochemical battery models has always been challenging due to the multitude of parameters involved, most of which cannot be directly measured. This paper evaluates the efficiency and optimality of three…

Systems and Control · Electrical Eng. & Systems 2025-11-04 Feng Guo , Luis D. Couto , Guillaume Thenaisie

A derivation of the single particle model (SPM) is made from a porous electrode theory model (or Newman model) of half-cell (dis)charge for an electrode composed of uniformly sized spherical electrode particles of a single chemistry. The…

Chemical Physics · Physics 2019-07-23 G. Richardson , I. Korotkin , R. Ranom. M. Castle , J. M. Foster

Lithium-ion battery packs are usually composed of hundreds of cells arranged in series and parallel connections. The proper functioning of these complex devices requires suitable Battery Management Systems (BMSs). Advanced BMSs rely on…

Systems and Control · Electrical Eng. & Systems 2019-09-30 Andrea Pozzi , Marcello Torchio , Richard D. Braatz , Davide M. Raimondo

The widely used Doyler-Fuller-Newman (DFN) model for lithium-ion batteries is too computationally expensive for certain applications, which has motivated the appearance of a plethora of simpler models. These models are usually posed in an…

Chemical Physics · Physics 2021-05-03 Ferran Brosa Planella , Muhammad Sheikh , W. Dhammika Widanage

Advanced battery management systems rely on mathematical models to guarantee optimal functioning of Lithium-ion batteries. The Pseudo-Two Dimensional (P2D) model is a very detailed electrochemical model suitable for simulations. On the…

Systems and Control · Computer Science 2019-10-01 Andrea Pozzi , Gabriele Ciaramella , Stefan Volkwein , Davide M. Raimondo

Non-invasive parametrisation of physics-based battery models can be performed by fitting the model to electrochemical impedance spectroscopy (EIS) data containing features related to the different physical processes. However, this requires…

Systems and Control · Electrical Eng. & Systems 2025-06-11 Noël Hallemans , Nicola E. Courtier , Colin P. Please , Brady Planden , Rishit Dhoot , Robert Timms , S. Jon chapman , David Howey , Stephen R. Duncan

The standard continuum model of a lithium-ion battery, the Doyle-Fuller-Newman (DFN) model, is computationally expensive to solve. Typically simpler models, such as the single particle model (SPM), are used to provide insight for control…

Chemical Physics · Physics 2019-11-07 Scott G. Marquis , Valentin Sulzer , Robert Timms , Colin P. Please , S. Jon Chapman

Degradation prognosis for lithium-ion cells requires forecasting the state-of-health (SOH) trajectory over future cycles. Existing data-driven approaches can produce trajectory outputs through direct regression, but lack a mechanism to…

Machine Learning · Computer Science 2026-03-12 Kai Chin Lim , Khay Wai See

This work presents a comparative study of optimization techniques for parameter identification in equivalent electrical models of lithium-ion batteries. The 2RC model is applied to a set of twelve batteries using four publicly available…

Optimization and Control · Mathematics 2025-12-03 Johan Sebastian Suarez Sepúlveda , Edgar Hernando Sepúlveda-Oviedo , Bruno Jammes , Corinne Alonso

Battery management systems may rely on mathematical models to provide higher performance than standard charging protocols. Electrochemical models allow us to capture the phenomena occurring inside a lithium-ion cell and therefore, could be…

Computational Engineering, Finance, and Science · Computer Science 2020-05-12 Andrea Pozzi , Xiangzhong Xie , Davide M Raimondo , René Schenkendorf

This paper presents a Bayesian parameter estimation approach and identifiability analysis for a lithium-ion battery model, to determine the uniqueness, evaluate the sensitivity and quantify the uncertainty of a subset of the model…

Systems and Control · Electrical Eng. & Systems 2023-09-04 Antti Aitio , Scott G. Marquis , Pedro Ascencio , David Howey

In mathematical models of lithium-ion batteries, the highly heterogeneous porous electrodes are frequently approximated as comprising spherical particles of uniform size, leading to the commonly-used single-particle model (SPM) when…

Applied Physics · Physics 2020-06-24 Toby L. Kirk , Jack Evans , Colin P. Please , S. Jonathan Chapman

Efficient parameter identification of electrochemical models is crucial for accurate monitoring and control of lithium-ion cells. This process becomes challenging when applied to complex models that rely on a considerable number of…

Systems and Control · Electrical Eng. & Systems 2024-05-20 Jianzong Pi , Samuel Filgueira da Silva , Mehmet Fatih Ozkan , Abhishek Gupta , Marcello Canova

Lithium-ion (Li-ion) batteries are ubiquitous in modern energy storage systems, highlighting the critical need to comprehend and optimize their performance. Yet, battery models often exhibit poor parameter identifiability which hinders the…

Systems and Control · Electrical Eng. & Systems 2024-06-14 Jorge Espin , Yuichi Kajiura , Dong Zhang

Parameter estimation in electrochemical models remains a significant challenge in their application. This study investigates the impact of different operating profiles on electrochemical model parameter estimation to identify the optimal…

Systems and Control · Electrical Eng. & Systems 2025-12-09 Feng Guo , Luis D. Couto , Khiem Trad , Grietus Mulder , Keivan Haghverdi , Guillaume Thenaisie
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