Related papers: Symmetry Breaking as Predicted by a Phase Space Ha…
Phase-space electronic structure theory offers up a new and powerful approach for tackling problems with coupled nuclear-electronic dynamics in a fashion that goes beyond Born-Oppenheimer (BO) theory. Whereas BO theory stipulates that we…
Recent progresses in condensed matter physics, such as graphene, topological insulator and Weyl semimetal, often origin from the specific topological symmetries of their lattice structures. Quantum states with different degrees of freedom,…
We show that following the standard mantra of quantum chemistry and diagonalizing the Born-Oppenheimer (BO) Hamiltonian $\hat H_{\rm BO}(\bm R)$ is not the optimal means to construct potential energy surfaces. A better approach is to…
We present a phase-space electronic Hamiltonian $\hat{H}_{PS}$ (parameterized by both nuclear position $\mathbf{X}$ and momentum $\mathbf{P}$) that boosts each electron into the moving frame of the nuclei that are closest in real space --…
A class of above-barrier quantum-scattering problems is shown to provide an experimentally-accessible platform for studying $\mathcal{PT}$-symmetric Schr\"odinger equations that exhibit spontaneous $\mathcal{PT}$ symmetry breaking despite…
A fundamental task of statistical physics is to start with a microscopic Hamiltonian, predict the system's statistical properties and compare them with observable data. A notable current fundamental challenge is to tell whether and how an…
$\Lambda$-doubling of diatomic molecules is a subtle microscopic phenomenon that has long attracted the attention of experimental groups, insofar as rotation of molecular $\textit{nuclei}$ induces small energetic changes in the (degenerate)…
In this article, we derived a rigorous lower bound on the ground-state energy for a class of one-dimensional quantum systems in deformed space with minimal coordinate and momentum uncertainties, representing the absolute minimum energy that…
An effective Hamiltonian without symmetry restriction has been developed to model the rotational and fine structure of two nearly degenerate electronic states of an open-shell molecule. In addition to the rotational Hamiltonian for an…
Deformed ground state of $^{32}$Mg is investigated using the axially deformed relativistic Hartree-Fock-Bogoliubov (D-RHFB) model with the effective Lagrangian PKA1, which provides coincident description with the experimental measurements.…
We investigate the structure of a prototypical two-state conical intersection (BeH$_2$) using a phase space electronic Hamiltonian $\hat{H}_{PS}(\bR,\bP)$ that goes beyond the Born-Oppenheimer framework. By parameterizing the electronic…
The quantum ground state properties of two independent chains of spins (two-levels systems) interacting with the same bosonic field are theoretically investigated. Each chain is coupled to a different quadrature of the field, leading to two…
Spontaneous symmetry breaking in non-relativistic quantum systems has previously been addressed in the framework of effective field theory. Low-lying excitations are constructed from Nambu-Goldstone modes using symmetry arguments only. We…
In this paper, based on a one-dimensional non-Hermitian spin model with $\mathcal{RT}$-invariant term, we study the non-Hermitian physics for the two (nearly) degenerate ground states. By using the high-order perturbation method, an…
As a continuation of our previous work on the conservation and breaking of the pseudospin symmetry (PSS) in resonant states [Phys. Lett. B 847, 138320 (2023)}], in this work, the PSS in nuclear single-particle bound and resonant states are…
We consider an electron, spin 1/2, minimally coupled to the quantized radiation field in the nonrelativistic approximation, a situation defined by the Pauli-Fierz Hamiltonian $H$. There is no external potential and $H$ fibers according to…
Quantum phase transition in the spin-boson model was claimed on the basis of various numerical studies, but not strictly proven. Here by using a unitary transformation to decompose the Hamiltonian into two branches of odd and even parity we…
We show that homogeneous superconductors with broken spin/isospin symmetry lower their energy via a transition to a novel superconducting state where the Fermi-surfaces are deformed to a quasi-ellipsoidal form at zero total momentum of…
We study the asymptotic behavior of ground state energy for Schr\"odinger-Poisson-Slater energy functional. We show that ground state energy restricted to radially symmetric functions is above the ground state energy when the number of…
The quantum description of a particle moving in a deformed potential is investigated. A pseudostate (PS) basis is used to represent the states of the composite system. This PS basis is obtained by diagonalizing the system Hamiltonian in a…