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Excitation energy transfer between photosynthetic light-harvesting complexes is vital for highly efficient primary photosynthesis. Controlling this process is the key for advancing the emerging artificial photosynthetic systems. Here, we…

Optics · Physics 2025-02-17 Fan Wu , Tu C. Nguyen- Phan , Richard Cogdell , Tonu Pullerits

Two distinct approaches, the Frenkel-Dirac time-dependent variation and the Haken-Strobl model, are adopted to study energy transfer dynamics in single-ring and double-ring light-harvesting systems in purple bacteria. It is found that…

Chemical Physics · Physics 2015-06-05 Jun Ye , Kewei Sun , Yang Zhao , Yunjin Yu , Chee Kong Lee , Jianshu Cao

Recently, exciton-photon strong coupling has been proposed as a means to control and enhance energy transfer in ensembles of organic molecules. Here, we demonstrate that the exciton dynamics in an archetypal purple bacterial photosynthetic…

The recently suggested possibility that weak vibronic transitions can be excitonically enhanced in light-harvesting complexes is studied in detail. A vibronic exciton dimer model which includes ground state vibrations is investigated using…

Chemical Physics · Physics 2014-10-09 Jan Schulze , Magne Torbjörnsson , Oliver Kühn , Tõnu Pullerits

Aggregates of light harvesting 2 (LH2) complexes form the major exciton-relaying domain in the photosynthetic unit of purple bacteria. Application of a generalized master equation to pairs of the B850 units of LH2 complexes, where excitons…

Chemical Physics · Physics 2026-01-08 Seogjoo J. Jang

Unravelling the nature of energy transport in multi-chromophoric photosynthetic complexes is essential to extract valuable design blueprints for light-harvesting applications. Long-range exciton transport in such systems is facilitated by a…

We discuss our recent theoretical work on vibronic coupling mechanisms in a model energy transfer system in the context of previous 2DEV experiments on a natural light-harvesting system, light-harvesting complex II (LHCII), where vibronic…

Chemical Physics · Physics 2021-09-22 Eric A. Arsenault , Addison J. Schile , David T. Limmer , Graham R. Fleming

Two-dimensional optical spectroscopy experiments have shown that exciton transfer pathways in the Fenna-Matthews-Olson (FMO) photosynthetic complex differ drastically under reduced and oxidised conditions, suggesting a functional role for…

Usually the study of energy-transfer in the light harvesting complex is limited by a single-exciton motion along the antenna. Starting from the many-body Schr\"odinger equation, we derived Lindblad-type Master equations describing the…

Chemical Physics · Physics 2017-06-13 Shmuel Gurvitz , Gennady P. Berman , Richard T. Sayre

Exciton transport can be enhanced in the strong coupling regime where excitons hybridise with confined light modes to form polaritons. Because polaritons have group velocity, their propagation should be ballistic and long-ranged. However,…

Chemical Physics · Physics 2024-03-20 Ilia Sokolovskii , Ruth H. Tichauer , Dmitry Morozov , Johannes Feist , Gerrit Groenhof

Using the reduced density matrix formalism the exciton scattering in light-harvesting systems of purple bacteria is calculated. The static disorder (fluctuations of the site energies) as well as the dynamic disorder (dissipation) is taken…

Chemical Physics · Physics 2009-11-07 Pavel Herman , Ulrich Kleinekathoefer , Ivan Barvik , Michael Schreiber

The performance of various quantum devices is fundamentally linked to the control of exciton transport. To explore this, we study the exciton transport of the two-dimensional multi-chain systems with different coupling configurations in an…

Quantum Physics · Physics 2025-07-02 Jia-Hui Wang , Yu-Ren Shi , Ji-Ming Gao , Zi-Fa Yu , Ju-Kui Xue , Fang-Qi Hu

We explore the dynamics of energy transfer between two nanocrystal quantum dots placed within an optical microcavity. By adjusting the coupling strength between the cavity photon mode and the quantum dots, we have the capacity to fine-tune…

Mesoscale and Nanoscale Physics · Physics 2024-10-02 Kaiyue Peng , Eran Rabani

We describe a method for simulating exciton dynamics in protein-pigment complexes, including effects from charge transfer as well as fluorescence. The method combines the hierarchical equations of motion, which are used to describe quantum…

Chemical Physics · Physics 2022-11-23 Thomas P. Fay , David T. Limmer

The theoretical and experimental study of energy transfer in photosynthesis has revealed an interesting transport regime, which lies at the borderline between classical transport dynamics and quantum-mechanical interference effects.…

Biological Physics · Physics 2014-02-13 Tobias Kramer , Christoph Kreisbeck

Exciton transport in molecular aggregates with magic-angle orientation is expected to be strongly suppressed due to their negligible dipole-dipole interactions. However, recent reports show that light-matter interactions can significantly…

Chemical Physics · Physics 2026-03-10 Siwei Wang , Liang-Yan Hsu , Hsing-Ta Chen

We study the role of the dimer structure of light-harvesting complex II (LH2) in excitation transfer from the LH2 (without a reaction center (RC)) to the LH1 (surrounding the RC), or from the LH2 to another LH2. The excited and un-excited…

Biological Physics · Physics 2010-06-28 S. Yang , D. Z. Xu , Z. Song , C. P. Sun

Photo-active systems are characterized by their capacity of absorbing light energy and transforming it. Usually, more than one chromophore is involved in the light absorption and excitation transport processes in complex systems.…

Materials Science · Physics 2019-05-21 Joaquim Jornet-Somoza , Irina Lebedeva

We analytically derive transfer probabilities and efficiencies for an artificial light-harvesting photosynthetic system, which consists of a ring coupled to a central acceptor. For an incident photon pair, we find near-perfect single…

Chemical Physics · Physics 2025-04-22 Stephon Alexander , Roger Andrews , Oliver Fox , Sarben Sarkar

Exciton harvesting is demonstrated in an ensemble of quantum emitters coupled to localized surface plasmons. When the interaction between emitters and the dipole mode of a metallic nanosphere reaches the strong coupling regime, the exciton…

Mesoscale and Nanoscale Physics · Physics 2015-09-16 Carlos Gonzalez-Ballestero , Johannes Feist , Esteban Moreno , Francisco J. Garcia-Vidal
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