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A path integral ground state approach has been used to estimate the ground-state energy and structural properties of hydrogen fluoride molecules pinned to a one-dimensional lattice. In the simulations, the molecules are assumed to be rigid,…

Chemical Physics · Physics 2023-08-10 Tapas Sahoo , Gautam Gangopadhyay

A new numerical method is introduced for calculating the polarizability of an arbitrary dielectric object with position dependent complex permittivity. Three separate numerical approaches are provided to calculate the dipole moment of a…

Materials Science · Physics 2022-03-18 Daniel B. Murray , Caleb H. Netting , Robin D. Mercer , Lucien Saviot

We formulate the theory for a diatomic molecule in a spatially degenerate electronic state interacting with a non-resonant laser field and investigate its rovibrational structure in the presence of the field. We report on \textit{ab initio}…

We consider the N-body problem in a layered geometry containing cold polar molecules with dipole moments that are polarized perpendicular to the layers. A harmonic approximation is used to simplify the hamiltonian and bound state properties…

Quantum Gases · Physics 2012-04-02 J. R. Armstrong , N. T. Zinner , D. V. Fedorov , A. S. Jensen

We present an open-source simulation framework for optically detected magnetic resonance, developed in Python. The framework allows users to construct, manipulate, and evolve multipartite quantum systems that consist of spins and electronic…

Quantum Physics · Physics 2025-01-13 Laura A. Völker , John M. Abendroth , Christian L. Degen , Konstantin Herb

Detecting the internal state of polar molecules is a substantial challenge when standard techniques such as resonance-enhanced multi photon ionization (REMPI) or laser-induced fluorescense (LIF) do not work. As this is the case for most…

Atomic Physics · Physics 2014-12-01 Rosa Glöckner , Alexander Prehn , Gerhard Rempe , Martin Zeppenfeld

Rotational spectra of diatomic molecules measured in the high-precision experiments are analyzed. Such a spectrum is usually fitted by an 8th order polynomial in spin. In fact, from the theoretical point of view, the rotational spectrum is…

Atomic Physics · Physics 2007-05-23 K. Hara , G. A. Lalazissis

With advancements in computational molecular modeling and powerful structure search methods, it is now possible to systematically screen crystal structures for small organic molecules. In this context, we introduce the Python package…

Materials Science · Physics 2025-06-06 Qiang Zhu , Shinnosuke Hattori

We have developed an all particle Fock-space relativistic coupled-cluster method for two-valence atomic systems. We then describe a scheme to employ the coupled-cluster wave function to calculate atomic properties. Based on these…

Atomic Physics · Physics 2011-01-11 B. K. Mani , D. Angom

Ultracold polar molecules in multilayered systems have been experimentally realized very recently. While experiments study these systems almost exclusively through their chemical reactivity, the outlook for creating and manipulating exotic…

Quantum Physics · Physics 2013-04-19 A. G. Volosniev , J. R. Armstrong , D. V. Fedorov , A. S. Jensen , N. T. Zinner

We establish a correspondence between the electric dipole matrix elements of a polyatomic symmetric top molecule in a state with nonzero projection of the total angular momentum on the symmetry axis of the molecule and the magnetic dipole…

Quantum Gases · Physics 2015-03-20 Michael L Wall , Kenji Maeda , Lincoln D Carr

We describe Rabacus, a Python package for calculating the transfer of hydrogen ionizing radiation in simplified geometries relevant to astronomy and cosmology. We present example solutions for three specific cases: 1) a semi-infinite slab…

Cosmology and Nongalactic Astrophysics · Physics 2015-02-26 Gabriel Altay , John Wise

Polarized atomic beam sources have been in operation since many years to produce either nuclear polarized atomic hydrogen or deuterium beams. In recent experiments such a source was used to polarize both isotopes independently at the same…

Density functional theory (DFT) calculation has had huge success as a tool capable of predicting important physical and chemical properties of condensed matter systems. We calculate the electric dipole moment of a molecule by using the…

Chemical Physics · Physics 2019-03-12 Byeong June Min

In a companion paper, we have developed a phase-space electronic structure theory of molecules in magnetic fields, whereby the electronic energy levels arise from diagonalizing a phase-space Hamiltonian $\hat H_{PS}(\bf{X},\bf{\Pi})$ that…

Chemical Physics · Physics 2024-11-25 Mansi Bhati , Zhen Tao , Xuezhi Bian , Jonathan Rawlinson , Robert Littlejohn , Joseph E. Subotnik

Computation of electromagnetic fields due to point sources (Hertzian dipoles) in cylindrically stratified media is a classical problem for which analytical expressions of the associated tensor Green's function have been long known. However,…

Mathematical Physics · Physics 2014-05-30 H. Moon , F. L. Teixeira , B. Donderici

Reliable quantum chemical methods for the description of molecules with dense-lying frontier orbitals are needed in the context of many chemical compounds and reactions. Here, we review developments that led to our newcomputational toolbo x…

The calculation of (co)irreducible representations of energy bands at high-symmetry points (HSPs) is essential for high-throughput research on topological materials based on symmetry-indicators or topological quantum chemistry. However,…

Materials Science · Physics 2025-09-17 Liangliang Huang , Xiangang Wan , Feng Tang

A common technique in the study of complex quantum-mechanical systems is to reduce the number of degrees of freedom in the Hamiltonian by using quasi-degenerate perturbation theory. While the Schrieffer--Wolff transformation achieves this…

Quantum Physics · Physics 2025-02-19 Isidora Araya Day , Sebastian Miles , Hugo K. Kerstens , Daniel Varjas , Anton R. Akhmerov