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We extend the Carath\'{e}odory principle of the Second Law to quantum thermodynamics with energy levels depending on macroscopic variables, such as volume and magnetic field. This extension introduces the concept of Quantum Thermodynamic…

Statistical Mechanics · Physics 2025-09-09 Ruo-Xun Zhai , C. P. Sun

A generalization of the thermodynamic uncertainty relations is proposed. It is done by introducing of an additional term proportional to the interior energy into the standard thermodynamic uncertainty relation that leads to existence of the…

General Relativity and Quantum Cosmology · Physics 2007-05-23 A. E. Shalyt-Margolin , A. Ya. Tregubovich

We consider the entropy production of a strongly coupled bipartite system. The total entropy production can be partitioned into various components, which we use to define local versions of the Second Law that are valid without the usual…

Statistical Mechanics · Physics 2022-09-29 Gavin E. Crooks , Susanne E. Still

We extend on ideas from standard thermodynamics to show that temperature can be assigned to a general nonequilibrium quantum system. By choosing a physically motivated complete set of observables and expanding the system state thereupon,…

Quantum Physics · Physics 2021-05-26 S. Alipour , F. Benatti , M. Afsary , F. Bakhshinezhad , M. Ramezani , T. Ala-Nissila , A. T. Rezakhani

The unification of relativity and thermodynamics has been a subject of considerable debate over the last 100 years. The reasons for this are twofold: (i) Thermodynamic variables are nonlocal quantities and, thus, single out a preferred…

Statistical Mechanics · Physics 2009-12-18 Jörn Dunkel , Peter Hänggi , Stefan Hilbert

It is known that the origin of the deviations from standard thermodynamics proceed from the strong coupling to the bath. Here, it is shown that these deviations are related to the power spectrum of the bath. Specifically, it is shown that…

Quantum Physics · Physics 2015-08-26 Johan F. Triana

The zeroth principle of thermodynamics in the form "temperature is uniform at equilibrium" is notoriously violated in relativistic gravity. Temperature uniformity is often derived from the maximization of the total number of microstates of…

General Relativity and Quantum Cosmology · Physics 2014-03-12 Hal M. Haggard , Carlo Rovelli

In a companion article it was shown in a certain precise sense that, for any thermodynamical theory that respects the Kelvin-Planck Second Law, the Hahn-Banach Theorem immediately ensures the existence of a pair of continuous functions of…

Mathematical Physics · Physics 2023-08-22 Martin Feinberg , Richard B. Lavine

In a previous work (M. Campisi. Stud. Hist. Phil. M. P. 36 (2005) 275-290) we have addressed the mechanical foundations of equilibrium thermodynamics on the basis of the Generalized Helmholtz Theorem. It was found that the volume entropy…

Statistical Mechanics · Physics 2008-03-09 Michele Campisi

The second law of thermodynamics places a limitation into which states a system can evolve into. For systems in contact with a heat bath, it can be combined with the law of energy conservation, and it says that a system can only evolve into…

Quantum Physics · Physics 2015-11-20 Piotr Ćwikliński , Michał Studziński , Michał Horodecki , Jonathan Oppenheim

Open quantum systems are studied from the thermodynamical point of view unifying the principle of maximum informational entropy and the hypothesis of relaxation times hierarchy. The result of the unification is a non-Markovian and local in…

Quantum Physics · Physics 2014-11-24 Vitalii Semin , Francesco Petruccione

We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy (H-function) is not just a Lyapunov function…

Statistical Mechanics · Physics 2015-05-13 H. -H. Hasegawa , J. Ishikawa , K. Takara , D. J. Driebe

The recent experimental realization of exotic matter states in isolated quantum systems and the ensuing controversy about the existence of negative absolute temperatures demand a careful analysis of the conceptual foundations underlying…

Statistical Mechanics · Physics 2015-01-05 Stefan Hilbert , Peter Hänggi , Jörn Dunkel

In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

A key feature of non-equilibrium thermodynamics is the Markovian, deterministic relaxation of coarse observables such as, for example, the temperature difference between two macroscopic objects which evolves independently of almost all…

Quantum Physics · Physics 2014-04-08 Hendrik Niemeyer , Kristel Michielsen , Hans de Raedt , Jochen Gemmer

We analyze the temperature relaxation phenomena of systems in contact with a thermal reservoir that undergo a non-Markovian diffusion process. From a generalized Langevin equation, we show that the temperature is governed by a law of…

Statistical Mechanics · Physics 2015-06-23 Luciano C. Lapas , Rogelma M. S. Ferreira , Fernando A. Oliveira , J. Miguel Rubí

We challenge the statement that the principle of Thomson and the principle of Clausius are equivalent. A logical mistake in the supposed textbook proof of their equivalency is indicated. On this account we refine the heat-engine axiomatics.…

General Physics · Physics 2007-05-23 Valery P. Dmitriyev

Markovian master equations provide a versatile tool for describing open quantum systems when memory effects of the environment may be neglected. As these equations are of an approximate nature, they often do not respect the laws of…

Quantum Physics · Physics 2021-12-09 Patrick P. Potts , Alex Arash Sand Kalaee , Andreas Wacker

We provide a quantum statistical thermodynamical solution of the long standing problem of temperature transformations of uniformly moving bodies. Our treatment of this question is based on the well established quantum statistical result…

Mathematical Physics · Physics 2009-11-13 Geoffrey L. Sewell

We analyze an autonomous micro-engine as a closed quantum mechanical system, including the work it performs and the fuel it consumes. Our model system shows by example that it is possible to transfer energy steadily and spontaneously…

Statistical Mechanics · Physics 2013-04-12 Lukas Gilz , Eike P. Thesing , James R. Anglin