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Despite its simplicity and relatively low computational cost, second-order M{\o}ller-Plesset perturbation theory (MP2) is well-known to overbind noncovalent interactions between polarizable monomers and some organometallic bonds. In such…

Chemical Physics · Physics 2023-11-09 Kevin Carter-Fenk , James Shee , Martin Head-Gordon

Mixed precision training (MPT) is becoming a practical technique to improve the speed and energy efficiency of training deep neural networks by leveraging the fast hardware support for IEEE half-precision floating point that is available in…

Machine Learning · Computer Science 2019-10-29 Ruizhe Zhao , Brian Vogel , Tanvir Ahmed

A hybrid stochastic-deterministic approach for computing the second-order perturbative contribution $E^{(2)}$ within multireference perturbation theory (MRPT) is presented. The idea at the heart of our hybrid scheme --- based on a…

Chemical Physics · Physics 2018-05-31 Yann Garniron , Anthony Scemama , Pierre-François Loos , Michel Caffarel

We present a perturbative method for ab initio calculations of rotational and rovibrational effective Hamiltonians of both rigid and non-rigid molecules. Our approach is based on a curvilinear implementation of second order vibrational…

Chemical Physics · Physics 2016-11-04 P. Bryan Changala , Joshua H. Baraban

An extension of the synchronous parallel kinetic Monte Carlo (pkMC) algorithm developed by Martinez {\it et al} [{\it J.\ Comp.\ Phys.} {\bf 227} (2008) 3804] to discrete lattices is presented. The method solves the master equation…

Statistical Mechanics · Physics 2015-05-19 Enrique Martinez , Paul R Monasterio , Jaime Marian

The extension of least-squares tensor hypercontracted second- and third-order M{\o}ller-Plessett perturbation theory (LS-THC-MP2 and LS-THC-MP3) to open-shell systems is an important development due to the scaling reduction afforded by THC…

Chemical Physics · Physics 2025-03-26 Tingting Zhao , Megan Simons , Devin A. Matthews

We discuss a new algorithm to generate multi-scale initial conditions with multiple levels of refinements for cosmological "zoom-in" simulations. The method uses an adaptive convolution of Gaussian white noise with a real space transfer…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-27 Oliver Hahn , Tom Abel

Despite its reasonable accuracy for ground-state properties of semiconductors and insulators, second-order Moller-Plesset perturbation theory (MP2) significantly underestimates band gaps. Here, we evaluate the band gap predictions of…

Materials Science · Physics 2021-09-15 Malte F. Lange , Timothy C. Berkelbach

This work has been submitted to the IEEE for possible publication. Copyright may be transferred without notice, after which this version may no longer be accessible. Numerous renowned algorithms for tackling the compressed sensing problem…

Information Theory · Computer Science 2026-03-11 Xu Zhu , Yufei Ma , Xiaoguang Li , Tiejun Li

The random-phase approximation with second-order screened exchange (RPA+SOSEX) is a model of electron correlation energy with two caveats: its accuracy depends on an arbitrary choice of mean field, and it scales as $\mathcal{O}(n^5)$…

Materials Science · Physics 2014-01-16 Jonathan E. Moussa

The micropolar Rayleigh-B{\'e}nard convection system, which consists of Navier-Stokes equations, the angular momentum equation, and the heat equation, is a strongly nonlinear, coupled, and saddle point structural multiphysics system. A…

Numerical Analysis · Mathematics 2025-12-03 Ming Cui , Akang Hou , Xiaoyu Dong

The extension of the highly-optimized local natural orbital (LNO) CCSD(T) method is presented for high-spin open-shell molecules. The techniques enabling the outstanding efficiency of the closed-shell LNO-CCSD(T) variant are adopted,…

Chemical Physics · Physics 2023-11-17 P. Bernát Szabó , József Csóka , Mihály Kállay , Péter R. Nagy

In the present article, we show how to formulate the partially contracted n-electron valence second order perturbation theory (NEVPT2) energies in the atomic and active molecular orbital basis by employing the Laplace transformation of…

Chemical Physics · Physics 2017-06-28 Benjamin Helmich-Paris , Stefan Knecht

We present a faster interior-point method for optimizing sum-of-squares (SOS) polynomials, which are a central tool in polynomial optimization and capture convex programming in the Lasserre hierarchy. Let $p = \sum_i q^2_i$ be an…

Optimization and Control · Mathematics 2022-02-18 Shunhua Jiang , Bento Natura , Omri Weinstein

We propose a robust model predictive control (MPC) method for discrete-time linear time-invariant systems with norm-bounded additive disturbances and model uncertainty. In our method, at each time step we solve a finite time robust optimal…

Systems and Control · Electrical Eng. & Systems 2021-11-11 Shaoru Chen , Nikolai Matni , Manfred Morari , Victor M. Preciado

We have presented the theory, implementation, and benchmark results for the one-electronic variant of spin-free exact two-component (SFX2C1e) linear response coupled cluster (LRCCSD) theory for static and dynamic polarizabilities of atoms…

Chemical Physics · Physics 2024-05-31 Sudipta Chakraborty , Tamoghna Mukhopadhyay , Achintya Kumar Dutta

We propose a covariant orbital-spin ($LS$) decomposed amplitude for the partial wave analysis using the massive spinor-helicity formalism. First we review the traditional-$LS$ method in the little group space and the Zemach tensor method in…

High Energy Physics - Phenomenology · Physics 2026-03-06 Hong Huang , Yi-Ning Wang , Jiang-Hao Yu

We present a new adaptive method for electronic structure calculations based on novel fast algorithms for reduction of multivariate mixtures. In our calculations, spatial orbitals are maintained as Gaussian mixtures whose terms are selected…

Numerical Analysis · Mathematics 2019-06-19 Gregory Beylkin , Lucas Monzon , Xinshuo Yang

Subspace-based signal processing techniques, such as the Estimation of Signal Parameters via Rotational Invariant Techniques (ESPRIT) algorithm, are popular methods for spectral estimation. These algorithms can achieve the so-called…

Information Theory · Computer Science 2024-10-29 Zhiyan Ding , Ethan N. Epperly , Lin Lin , Ruizhe Zhang

This paper addresses a multi-scale finite element method for second order linear elliptic equations with arbitrarily rough coefficient. We propose a local oversampling method to construct basis functions that have optimal local…

Numerical Analysis · Mathematics 2015-08-04 Thomas Y. Hou , Pengfei Liu