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Stable and switchable polarization of ferroelectric materials opens a possibility to electrically control their functional behavior. A particularly promising approach is to employ ferroelectric tunnel junctions where the polarization…

We investigate the lattice structure of heterostructures comprising of ferroelectric BaTiO$_3$ (BTO) thin films and BaBiO$_3$ (BBO), the insulating parent-compound of the high Tc superconductor. Motivated by theoretical predictions of…

Materials Science · Physics 2024-05-29 Merve Baksi , Divine P. Kumah

Spontaneous polarization is essential for ferroelectric functionality in non-centrosymmetric crystals. High-integration-density ferroelectric devices require the stabilization of ferroelectric polarization in small volumes. Here,…

BaTiO$_3$ (BTO) is a prototypical perovskite ferroelectric, whose dielectric permittivity and loss spectra -- which are strongly temperature and frequency dependent -- include contributions from inhomogeneous polarization patterns, with…

Materials Science · Physics 2024-07-31 Ashok Gurung , Mohammad Fatin Ishtiyaq , S. Pamir Alpay , John Mangeri , Serge Nakhmanson

We performed first principles calculations for epitaxially strained orthorhombic CaTiO$_3$. The computational results reveal the existence of a metastable ferroelectric phase at compressive strain with unexpected in-plane polarization.…

Materials Science · Physics 2013-08-27 Qibin Zhou , Karin M. Rabe

Polarons, quasiparticles formed through interactions between lattice and charge carriers (electrons and holes), strongly influence the electronic and optical properties of functional materials. In nanostructured BiVO$_{4}$, polaron…

Materials Science · Physics 2025-11-26 Seyeon Park , Yajing Zhang , Michele Reticcioli , Cesare Franchini , Bongjae Kim

First-principles density functional calculations are performed to investigate the interplay between inplane strains and interface effects in 1by1 PbTiO3/SrTiO3 and BaTiO3/SrTiO3 superlattices of tetragonal symmetry. One particular emphasis…

Materials Science · Physics 2010-04-19 Yanpeng Yao , Huaxiang Fu

The bulk photovoltaic effect exhibited by the non-centrosymmetric system gains research interest due to the observed large open-circuit voltage. The ferroelectric systems exhibiting anomalous photovoltaic effect are mostly crystallized with…

Materials Science · Physics 2021-04-08 Subhajit Pal , S. Muthukrishnan , Banasree Sadhukhan , Sarath N. , D. Murali , Pattukkannu Murugavel

In ferroelectrics, complex interactions among various degrees of freedom enable the condensation of topologically protected polarization textures. Known as ferroelectric solitons, these particle-like structures represent a new class of…

Materials Science · Physics 2023-08-02 V. Govinden , P. R. Tong , X. Guo , Q. Zhang , S. Mantri , S. Prokhorenko , Y. Nahas , Y. Wu , L. Bellaiche , H. Tian , Z. Hong , D. Sando , V. Nagarajan

Ferroelectric membranes transferred onto arbitrary substrates provide reduced mechanical clamping at the interfaces that can diminish the effective polarization-rotation barrier offering a pathway to engineer larger electromechanical and…

A recent muon spin rotation ($\mu^+$SR) study on a paramagnetic defect complex formed upon implantation of $\mu^+$ pseudo-proton into SrTiO$_3$ is reviewed with a specific focus on the relation with experimental signatures of coexisting…

Materials Science · Physics 2022-08-24 Takashi U. Ito

The question whether ferroelectricity (FE) may coexist with a metallic or highly conducting state, or rather it must be suppressed by the screening from the free charges, is the focus of a rapidly increasing number of theoretical studies…

Materials Science · Physics 2019-02-20 F. Cordero , F. Trequattrini , F. Craciun , H. T. Langhammer , D. A. B. Quiroga , P. S. Silva

Despite the technological significance of the tetragonal PbTiO3 for the piezoelectric transducer industry, its high pressure behaviour is quite controversial as two entirely different scenarios, involving pressure induced (1) morphotropic…

We carry out first-principles calculations for CaTiO$_3$/BaTiO$_3$ superlattices with epitaxial strain corresponding to growth on a SrTiO$_3$ substrate, and consider octahedral rotations as well as ferroelectric distortions. The…

Materials Science · Physics 2015-05-19 Xifan Wu , Karin M. Rabe , David Vanderbilt

We have investigated the crystal structure and the ferroelectric properties of BaTiO3 thin films with YBa2Cu3O7-d as the bottom and Au as the top electrode. Epitaxial heterostructures of YBa2Cu3O7-d and BaTiO3 were prepared by dc and rf…

Materials Science · Physics 2009-10-31 Ch. Schwan , F. Martin , G. Jakob , J. C. Martinez , H. Adrian

Piezoelectrics interconvert mechanical energy and electric charge and are widely used in actuators and sensors. The best performing materials are ferroelectrics at a morphotropic phase boundary (MPB), where several phases can intimately…

Low-dimensional ferroelectricity and polar materials have attracted considerable attentions for their fascinating physics and potential applications. Based on first-principles calculations, here we investigate the stacking modes and polar…

Materials Science · Physics 2022-10-12 Wencong Sun , Ning Ding , Jun Chen , Hai-Peng You , Jin Peng , Shan-Shan Wang , Shuai Dong

The rotational instability of the electric polarization P during phase transformations between ferroelectric phases is of great practical interest, since it may be accompanied by extremely large values of the piezoelectric coefficient, and…

Materials Science · Physics 2016-02-24 F. Cordero , H. T. Langhammer , T. Müller , V. Buscaglia , P. Nanni

BiFeO$_3$ is the most famous multiferroic material, but it has no strong spontaneous magnetization due to its antiferromagnetism. Here we show that giant ferroelectric polarization and strong spontaneous magnetization can be both realized…

Materials Science · Physics 2019-06-13 Peng Chen , Bang-Gui Liu

Ferroelectricity is observed in orthorhombic $HoMnO_3$ and $YMnO_3$ at the magnetic lock-in transitions into an E-type structure or an incommensurate phase with a temperature independent wave vector, respectively. In $HoMnO_3$ the…

Strongly Correlated Electrons · Physics 2011-11-09 B. Lorenz , Y. Q. Wang , C. W. Chu
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