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The chemical flexibility of metal-organic frameworks (MOFs) offers an ideal platform to tune structure and composition for specific applications, from gas sensing to catalysis and from photoelectric conversion to energy storage. This…

Materials Science · Physics 2024-02-13 Joshua Edzards , Holger-Dietrich Saßnick , Julia Santana Andreo , Caterina Cocchi

Metal-organic frameworks (MOFs) are an attractive substrate for catalytic reactions due to the high area density of reaction sites and the ability to tailor an array of material attributes. This study focuses on a thermally stable…

Chemical Physics · Physics 2017-04-25 Jiangtian Li , Terence Musho , Joeseph Bright , Nianqiang Wu

We develop a computational workflow for high-throughput Wannierization of density functional theory (DFT) based electronic band structure calculations. We apply this workflow to 1771 materials, and we create a database with the resulting…

Materials Science · Physics 2020-07-03 Kevin F. Garrity , Kamal Choudhary

Metal organic frameworks (MOFs) are promising photocatalytic materials due to their high surface area and tuneability of their electronic structure. We discuss here how to engineer the band structures and optical properties of a family of…

Long-lived emissive materials based on room temperature phosphorescence (RTP) and thermally activated delayed fluorescence (TADF) are considered as the cornerstone of the development of optical sensors, security systems and solid-state…

Materials Science · Physics 2021-10-26 Mario Gutiérrez , Cristina Martín , Johan Hofkens , Jin-Chong Tan

Coordination polymerization leads to various metal-organic frameworks (MOFs) in which symmetrical metal nodes exposed to nano voids lead to unique physical properties and chemical functionalities. One of the challenges towards their…

Mesoscale and Nanoscale Physics · Physics 2016-11-29 Hidetsugu Shiozawa , Bernhard C. Bayer , Herwig Peterlik , Jannik C. Meyer , Wolfgang Lang , Thomas Pichler

Recently, metal-organic frameworks (MOFs) have demonstrated their potential as solid-state electrolytes in proton exchange membrane fuel cells. However, the number of MOFs reported to exhibit proton conductivity remains limited, and the…

Materials Science · Physics 2026-04-21 Seunghee Han , Byeong Gwan Lee , Dae Woon Lim , Jihan Kim

Magnetic metal-organic frameworks (MMOFs), where magnetic metal nodes are connected into a crystal structure by organic linkers, have a potential to host exotic magnetic states. We present a study of bulk magnetic properties of four…

By virtue of their open network structures and low densities, metal--organic frameworks (MOFs) are soft materials that exhibit elastic instabilities at low applied stresses. The conventional strategy for improving elastic stability is to…

We report a molecular-dynamics simulation of a single-component system of particles interacting via a spherically symmetric potential that is found to form, upon cooling from a liquid state, a low-density porous crystalline phase. Its…

Materials Science · Physics 2014-12-17 Alfredo Metere , Peter Oleynikov , Mikhail Dzugutov , Michael O'Keeffe

Metal-organic frameworks (MOFs) are a family of materials that have high porosity and structural tunability and hold great potential in various applications, many of which requiring a proper understanding of the thermal transport…

Materials Science · Physics 2023-08-04 Penghua Ying , Ting Liang , Ke Xu , Jin Zhang , Jianbin Xu , Zheng Zhong , Zheyong Fan

DFT+U is a widely used treatment in the density functional theory (DFT) to deal with correlated materials that contain open-shell elements, whereby the quantitative and sometimes even qualitative failures of local and semilocal…

Computational Physics · Physics 2024-02-09 Zhendong Cao , Guanghui Cai , Fankai Xie , Huaxian Jia , Wei Liu , Yaxian Wang , Feng Liu , Xinguo Ren , Sheng Meng , Miao Liu

Metal-insulator transition (MIT) materials are a useful platform for emerging microelectronic, optoelectronic, and neuromorphic devices, but their discovery is hindered by the high computational cost of electronic structure modeling, the…

Molecular dynamics simulations combined with periodic electronic structure calculations are performed to decipher structural, thermodynamical and dynamical properties of the interfaced vs. confined water adsorbed in hexagonal 1D channels of…

Materials Science · Physics 2020-11-17 Mohammad R. Momeni , Zeyu Zhang , David Dell'Angelo , Farnaz A. Shakib

An in-depth insight into the chemistry and nature of the individual chemical bonds is essential for understanding materials. Bonding analysis is thus expected to provide important features for large-scale data analysis and machine learning…

Materials Science · Physics 2023-09-19 Aakash Ashok Naik , Christina Ertural , Nidal Dhamrait , Philipp Benner , Janine George

Metal-organic frameworks (MOFs) are highly interesting and tunable materials. By incorporating spatial defects into their atomic structure, MOFs can be finetuned to exhibit precise chemical functionalities, extending their applicability in…

Materials Science · Physics 2025-04-08 Pieter Dobbelaere , Sander Vandenhaute , Veronique Van Speybroeck

Carbon capture is vital for decarbonizing heavy industries such as steel and chemicals. Metal-organic frameworks (MOFs), with their high surface area and structural tunability, are promising materials for CO2 capture. This study focuses on…

We present a high-accuracy procedure for electronic structure calculations of strongly correlated materials. To address limitations in current electronic structure methods, we employ density functional theory in combination with the…

Conventionally, high-throughput computational materials searches start from an input set of bulk compounds extracted from material databases, and this set is screened for candidate materials for specific applications. In contrast, many…

Materials Science · Physics 2023-04-11 Rachel Woods-Robinson , Matthew K. Horton , Kristin A. Persson

The removal of leaked radioactive iodine isotopes in humid environments holds significant importance in nuclear waste management and nuclear accident mitigation. In this study, high-throughput computational screening and machine learning…

Machine Learning · Computer Science 2025-04-29 Haoyi Tan , Yukun Teng , Guangcun Shan
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