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An intrinsic measure of the quality of a variational wave function is given by its overlap with the ground state of the system. We derive a general formula to compute this overlap when quantum dynamics in imaginary time is accessible. The…

Statistical Mechanics · Physics 2007-07-26 Christophe Mora , Xavier Waintal

Accurately estimating the overlap between quantum states is a fundamental task in quantum information processing. While various strategies using distinct quantum measurements have been proposed for overlap estimation, the lack of…

Quantum Physics · Physics 2025-02-13 Hao Zhan , Ben Wang , Minghao Mi , Jie Xie , Liang Xu , Aonan Zhang , Lijian Zhang

Preparing the ground state of a given Hamiltonian and estimating its ground energy are important but computationally hard tasks. However, given some additional information, these problems can be solved efficiently on a quantum computer. We…

Quantum Physics · Physics 2020-12-16 Lin Lin , Yu Tong

The preparation of Hamiltonian eigenstates is essential for many applications in quantum computing; the efficiency with which this can be done is of key interest. A canonical approach exploits the quantum phase estimation (QPE) algorithm.…

Quantum Physics · Physics 2022-12-05 Richard Meister , Simon C. Benjamin

Phase estimation, due to Kitaev [arXiv'95], is one of the most fundamental subroutines in quantum computing. In the basic scenario, one is given black-box access to a unitary $U$, and an eigenstate $\lvert \psi \rangle$ of $U$ with unknown…

Quantum Physics · Physics 2025-12-15 Nikhil S. Mande , Ronald de Wolf

The computational cost of quantum algorithms for physics and chemistry is closely linked to the spectrum of the Hamiltonian, a property that manifests in the necessary rescaling of its eigenvalues. The typical approach of using the 1-norm…

The calculation of excited state energies of electronic structure Hamiltonians has many important applications, such as the calculation of optical spectra and reaction rates. While low-depth quantum algorithms, such as the variational…

Quantum Physics · Physics 2019-07-03 Oscar Higgott , Daochen Wang , Stephen Brierley

We present an efficient method for estimating the eigenvalues of a Hamiltonian $H$ from the expectation values of the evolution operator for various times. For a given quantum state $\rho$, our method outputs a list of eigenvalue estimates…

Quantum Physics · Physics 2020-09-08 Rolando D. Somma

A method is presented to compute approximate solutions for eigenequations in quantum mechanics with an arbitrary kinetic part. In some cases, the approximate eigenvalues can be analytically determined and they can be lower or upper bounds.…

Quantum Physics · Physics 2012-10-01 Claude Semay

There is widespread interest in calculating the energy spectrum of a Hamiltonian, for example to analyze optical spectra and energy deposition by ions in materials. In this study, we propose a quantum algorithm that samples the set of…

We upper- and lower-bound the optimal precision with which one can estimate an unknown Hamiltonian parameter via measurements of Gibbs thermal states with a known temperature. The bounds depend on the uncertainty in the Hamiltonian term…

The bound state wave functions for a wide class of exactly solvable potentials are found utilizing the quantum Hamilton-Jacobi formalism. It is shown that, exploiting the singularity structure of the quantum momentum function, until now…

Quantum Physics · Physics 2009-11-07 S. Sree Ranjani , K. G. Geojo , A. K. Kapoor , P. K. Panigrahi

The laws of quantum mechanics place fundamental limits on the accuracy of measurements and therefore on the estimation of unknown parameters of a quantum system. In this work, we prove lower bounds on the size of confidence regions reported…

Quantum Physics · Physics 2014-12-23 Michael Walter , Joseph M. Renes

Iterative phase estimation has long been used in quantum computing to estimate Hamiltonian eigenvalues. This is done by applying many repetitions of the same fundamental simulation circuit to an initial state, and using statistical…

Quantum Physics · Physics 2019-07-25 Ian D. Kivlichan , Christopher E. Granade , Nathan Wiebe

We propose a hybrid quantum-classical algorithm for approximating the ground state and ground state energy of a Hamiltonian. Once the Ansatz has been decided, the quantum part of the algorithm involves the calculation of two overlap…

Quantum Physics · Physics 2020-10-13 Kishor Bharti

Phase estimation is a quantum algorithm for measuring the eigenvalues of a Hamiltonian. We propose and rigorously analyse a randomized phase estimation algorithm with two distinctive features. First, our algorithm has complexity independent…

Quantum Physics · Physics 2022-08-09 Kianna Wan , Mario Berta , Earl T. Campbell

Quantum algorithms for diverse problems, including search and optimization problems, require the implementation of a reflection operator over a target state. Commonly, such reflections are approximately implemented using phase estimation.…

Quantum Physics · Physics 2018-03-08 Anirban Narayan Chowdhury , Yigit Subasi , Rolando D. Somma

Many quantum algorithms can be seen as a transition from a well-defined initial quantum state of a complex quantum system, to an unknown target quantum state, corresponding to a certain eigenvalue either of the Hamiltonian or of a…

Quantum Physics · Physics 2022-07-19 Aikaterini Mandilara , Daniil Fedotov , Vladimir M. Akulin

Estimating the ground-state energy of Hamiltonians is a fundamental task for which it is believed that quantum computers can be helpful. Several approaches have been proposed toward this goal, including algorithms based on quantum phase…

Quantum Physics · Physics 2025-11-26 Dhrumil Patel , Daniel Koch , Saahil Patel , Mark M. Wilde

Quantum mode parameter estimation determines parameters governing the shape of electromagnetic modes occupied by a quantum state of radiation. Canonical examples, time delays and frequency shifts, underpin radar, lidar, and optical clocks.…

Quantum Physics · Physics 2026-03-27 Maximilian Reichert , Mikel Sanz , Nicolas Fabre
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