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Intermetallic compounds with sizable band gaps are attractive for their unusual properties but rare. Here, we present a new family of stable semiconducting quaternary Heusler compounds, designed and discovered by means of high-throughput…

Materials Science · Physics 2018-02-15 Jiangang He , S. Shahab Naghavi , Vinay I. Hegde , Maximilian Amsler , Chris Wolverton

The XYZ half-Heusler crystal structure can conveniently be described as a tetrahedral zinc blende YZ structure which is stuffed by a slightly ionic X species. This description is well suited to understand the electronic structure of…

Materials Science · Physics 2008-01-13 Frederick Casper , Claudia Felser , Ram Seshadri , C. Peter Sebastian , Rainer Poettgen

Intermetallic Heusler alloys are amongst the most attractive half-metallic systems due to the high Curie temperatures and the structural similarity to the binary semiconductors. In this review we present an overview of the basic electronic…

Materials Science · Physics 2007-05-23 I. Galanakis , Ph. Mavropoulos , P. H. Dederichs

Half-metallic ferromagnetic (HMF) materials show high spin polarization and are therefore interesting to researchers due to their possible applications in spintronic devices. In these materials, while one spin sub band has a finite density…

Materials Science · Physics 2016-08-11 Lakhan Bainsla , K. G. Suresh

Half-Heuslers are a promising family for thermoelectric (TE) applications, yet only a small fraction of their potential chemistries has been experimentally explored. In this work, we introduce a distinct computational high-throughput…

Materials Science · Physics 2025-01-22 Angela Pak , Kamil Ciesielski , Maria Wróblewska , Eric S. Toberer , Elif Ertekin

In this work, we provide important insights into the evolution of half-metallicity in quaternary Heusler alloys. Employing {\it ab initio} electronic structure methods we study 18 quaternary Heusler compounds having the chemical formula…

Materials Science · Physics 2019-09-04 Srikrishna Ghosh , Subhradip Ghosh

In this letter, we investigate the magnetic properties, electronic structures, Slater-Pauling behaviours of some quanternary Heusler alloys with 4d and 3d transition metal elements. The energy levels of the minority-spin electronic band…

Materials Science · Physics 2015-01-19 Qiang Gao , Huan-Huan Xie , Lei Li , Gang Lei , Ke Wang , Jian-Bo Deng , Xian-Ru Hu

It is shown by rigorous ab initio calculations that half-Heusler alloys of transition metals and $d^0$ metals, defined by the valence electronic configuration $ns^{1,2},(n-1)d^0$, can produce all kinds of half-metallic behavior including…

Materials Science · Physics 2017-02-28 S. Davatolhagh , A. Dehghan

Ternary semiconducting or metallic half-Heusler compounds with an atomic composition 1:1:1 are widely studied for their flexible electronic properties and functionalities. Recently, a new material property of half-Heusler compounds was…

Materials Science · Physics 2014-10-28 Binghai Yan , Anne de Visser

The review treats Heusler alloys that display distinctive functional properties, including shape-memory behavior and magnetocaloric effects. Particular emphasis is placed on Heusler systems in which half-metallic ferromagnetism and…

Materials Science · Physics 2025-12-25 V. V. Marchenkov , V. Yu. Irkhin , Yu. A. Perevozchikova

A review of theoretical and experimental studies of the electronic structure, electronic and magnetic properties of various systems of Heusler alloys in the states of a half-metallic ferromagnet, a spin gapless semiconductor, and a…

Materials Science · Physics 2021-11-30 V. V. Marchenkov , V. Yu. Irkhin

Heusler compounds have emerged as important thermoelectric materials due to their combination of promising electronic transport properties, mechanical robustness and chemical stability -- key aspects for practical device integration. While…

We present extensive first-principles calculations on the inverse full-Heusler compounds having the chemical formula X$_2$YZ where (X = Sc, Ti, V, Cr or Mn), (Z = Al, Si or As) and the Y ranges from Ti to Zn. Several of these alloys are…

Materials Science · Physics 2013-02-20 S. Skaftouros , K. Ozdogan , E. Sasioglu , I. Galanakis

Using the full-potential local orbital minimum-basis method,the Ti2-based full-Heusler alloys are studied. The results show that these compounds exhibit a half-metallic behavior, however, in contrast to the conventional full-Heusler…

Materials Science · Physics 2011-10-26 Xiao-Ping Wei , Jian-Bo Deng , Ge-Yong Mao , Shi-Bin Chu , Xian-Ru Hu

Half-Heusler (HH) phases have garnered much attention as thermally stable and non-toxic thermoelectric materials for power conversion. The most studied alloys to date utilize Hf, Zr, and Ti as the base components. These alloys can achieve a…

Materials Science · Physics 2022-10-26 Mousumi Mitra , Allen Benton , Md Sabbir Akhanda , Jie Qi , Mona Zebarjadi , David J. Singh , S. Joseph Poon

The review considers various groups of Heusler compounds, which can have the properties of a semiconductor, a half-metallic ferromagnet, a spin gapless semiconductor, a topological semimetal, and a noncollinear antiferromagnet. In these…

Materials Science · Physics 2022-09-01 V. V. Marchenkov , V. Yu. Irkhin , A. A. Semiannikova

Semiconducting half- and, to a lesser extent, full-Heusler compounds are promising thermoelectric materials due to their compelling electronic properties with large power factors. However, intrinsically high thermal conductivity resulting…

We search for new fully compensated half metals, in which only one electronic spin channel is conducting and there exists no net magnetic moment. We focus on half Heusler alloys and we examine the physical consequence of different crystal…

Materials Science · Physics 2011-08-19 Michael Shaughnessy , C. Y. Fong , Lin H. Yang , Claudia Felser

We review the electronic and magnetic properties of the quinternary full Heusler alloys of the type Co$_2$[Cr$_{1-x}$Mn$_x$][Al$_{1-y}$Si$_y$] employing three different approaches : (i) the coherent potential approximation (CPA), (ii) the…

Materials Science · Physics 2015-05-13 K. Ozdogan , E. Sasioglu , I. Galanakis

Metallic conductors that are optically transparent represent a rare breed of generally contraindicated physical properties that are nevertheless critically needed for application where both functionalities are crucial. Such rare materials…

Materials Science · Physics 2019-06-26 Feng Yan , Xiuwen Zhang , Yonggang Yu , Liping Yu , Arpun Nagaraja , Thomas O. Mason , Alex Zunger
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