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Each of the nitriles present in the atmosphere of Titan can be expected to exhibit different \ce{^{14}N/^{15}N} values depending on their production processes, primarily because of the various \ce{N2} dissociation processes induced by…

Earth and Planetary Astrophysics · Physics 2020-02-26 Takahiro Iino , Hideo Sagawa , Takashi Tsukagoshi

Titan harbors a dense, organic-rich atmosphere primarily composed of N$_2$ and CH$_4$, with lesser amounts of hydrocarbons and nitrogen-bearing species. As a result of high sensitivity observations by the Atacama Large…

Earth and Planetary Astrophysics · Physics 2020-11-11 A. E. Thelen , M. A. Cordiner , C. A. Nixon , V. Vuitton , Z. Kisiel , S. B. Charnley , M. Y. Palmer , N. A. Teanby , P. G. J. Irwin

We present the first maps of cyanoacetylene isotopologues in Titan's atmosphere, including H$^{13}$CCCN and HCCC$^{15}$N, detected in the 0.9 mm band using the Atacama Large Millimeter/submillimeter array (ALMA) around the time of Titan's…

Earth and Planetary Astrophysics · Physics 2018-06-06 M. A. Cordiner , C. A. Nixon , S. B. Charnley , N. A. Teanby , E. M. Molter , Z. Kisiel , V. Vuitton

We present sub-millimeter spectra of HCN isotopologues on Titan, derived from publicly available ALMA flux calibration observations of Titan taken in early 2014. We report the detection of a new HCN isotopologue on Titan, H$^{13}$C$^{15}$,…

We present the first determination of the abundance ratios of $^{13}$C substitutions of cyanoacetylene (HC$_{3}$N), [H$^{13}$CCCN]:[HC$^{13}$CCN]:[HCC$^{13}$CN] in Titan's atmosphere measured using millimeter-wave spectra obtained by the…

Earth and Planetary Astrophysics · Physics 2021-08-12 Takahiro Iino , Kotomi Taniguchi , Hideo Sagawa , Takashi Tsukagoshi

The Texas Echelon cross Echelle Spectrograph (TEXES), mounted on NASA's Infrared Telescope Facility (IRTF), was used to map mid-infrared ammonia absorption features on both Jupiter and Saturn in February 2013. Ammonia is the principle…

Titan's atmospheric composition and dynamical state have previously been studied over numerous epochs by both ground- and space-based facilities. However, stratospheric measurements remain sparse during Titan's northern summer and fall. The…

We report interferometric observations of carbon monoxide (CO) and its isotopologues in Titan's atmosphere using the Atacama Large Millimeter/submillimeter Array (ALMA). The following transitions were detected: CO (J = 1-0, 2-1, 3-2, 6-5),…

Previous investigations have employed more than 100 close observations of Titan by the Cassini orbiter to elucidate connections between the production and distribution of Titan's vast, organic-rich chemical inventory and its atmospheric…

Earth and Planetary Astrophysics · Physics 2018-10-01 A. E. Thelen , C. A. Nixon , N. J. Chanover , M. A. Cordiner , E. M. Molter , N. A. Teanby , P. G. J. Irwin , J. Serigano , S. B. Charnley

Shematovich et al. (2003) recently showed plasma induced sputtering in Titan's atmosphere is a source of neutral nitrogen in Saturn's magnetosphere comparable to the photo-dissociation source. These sources form a toroidal nitrogen cloud…

Space Physics · Physics 2015-06-26 H. T. Smith , R. E. Johnson , V. I. Shematovich

Vinyl cyanide (C$_2$H$_3$CN) is theorized to form in Titan's atmosphere via high-altitude photochemistry and is of interest regarding the astrobiology of cold planetary surfaces due to its predicted ability to form cell membrane-like…

We present results of an investigation into the formation of nitrogen-bearing molecules in the atmosphere of Titan. We extend a previous model (Li et al. 2015, 2016) to cover the region below the tropopause, so the new model treats the…

Earth and Planetary Astrophysics · Physics 2016-10-05 Karen Willacy , Mark Allen , Yuk Yung

We report the first spectroscopic detection of ethyl cyanide (C$_2$H$_5$CN) in Titan's atmosphere, obtained using spectrally and spatially resolved observations of multiple emission lines with the Atacama Large Millimeter/submillimeter…

Context. The chemical building blocks of life contain a large proportion of nitrogen, an essential element. Titan, the largest moon of Saturn, with its dense atmosphere of molecular nitrogen and methane, offers an exceptional opportunity to…

Earth and Planetary Astrophysics · Physics 2022-08-03 N. Carrasco , J. Bourgalais , L. Vettier , P. Pernot , E. Giner , R. Spezia

We present spectrally and spatially-resolved maps of HNC and HC$_3$N emission from Titan's atmosphere, obtained using the Atacama Large Millimeter/submillimeter Array (ALMA) on 2013 November 17. These maps show anisotropic spatial…

Titan's abundant atmospheric N2 and CH4 gases are notable characteristics of the moon that may help constrain its origins and evolution. Previous work suggests that atmospheric CH4 is lost on geologically short timescales and may be…

Earth and Planetary Astrophysics · Physics 2024-12-19 Kelly E. Miller , Dionysis I. Foustoukos , George Cody , Conel M. O'D. Alexander

Saturn's largest satellite, Titan, has a thick atmosphere dominated by nitrogen and methane. The dense orange-brown smog hiding the satellite's surface is produced by photochemical reactions of methane, nitrogen and their dissociation…

Astrophysics · Physics 2009-11-13 Olivier Mousis , Bernard Schmitt

This brief review will discuss the current knowledge on the origin and evolution of the nitrogen atmospheres of the icy bodies in the solar system, particularly of Titan, Triton and Pluto. An important tool to analyse and understand the…

Earth and Planetary Astrophysics · Physics 2020-11-03 M. Scherf , H. Lammer , N. V. Erkaev , K. E. Mandt , S. E. Thaller , B. Marty

The chemistry of planetary atmospheres containing molecular nitrogen as a major atmospheric component is strongly influenced by the reactions of atomic nitrogen. Although nitrogen atoms in their ground electronic state N(4S) are mostly…

Earth and Planetary Astrophysics · Physics 2025-11-11 Kevin M. Hickson , Jean-Christophe Loison , Benjamin Benne , Michel Dobrijevic

Chemistry in Titan's N2-CH4 atmosphere produces complex organic aerosols. The chemical processes and the resulting organic compounds are still far from understood, although extensive observations, laboratory, and theoretical simulations…

Earth and Planetary Astrophysics · Physics 2022-09-26 Chao He , Joseph Serigano , Sarah M. Horst , Michael Radke , Joshua A. Sebree
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