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When the atomic layers in a non-centrosymmetric van der Waals structure slide against each other, the interfacial charge transfer results in a reversal of the structures spontaneous polarization. This phenomenon is known as sliding…

Ferroelectricity has a wide range of applications in functional electronics and is extremely important for the development of next-generation information storage technology, but it is difficult to achieve due to its special symmetry…

Materials Science · Physics 2023-07-24 Yuwen Zhang , Chunfeng Cui , Chaoyu He , Tao Ouyang , Jin Li , Mingxing Chen , Chao Tang

The so-called interlayer-sliding ferroelectricity was recently proposed as an unconventional route to pursuit electric polarity in van der Waals multi-layers, which was already experimentally confirmed in WTe$_2$ bilayer even though it is…

Materials Science · Physics 2021-08-17 Ning Ding , Jun Chen , Churen Gui , Haipeng You , Xiaoyan Yao , Shuai Dong

Two-dimensional sliding ferroelectrics, with their unique stacking degrees of freedom, offer a different approach to manipulate polarization by interlayer sliding. Bending sliding ferroelectrics inevitably leads to interlayer sliding…

Materials Science · Physics 2024-08-02 Ri He , Hua Wang , Fenglin Deng , Yuxiang Gao , Binwen Zhang , Yubai Shi , Run-Wei Li , Zhicheng Zhong

Light-induced sliding ferroelectricity in two-dimensional van der Waals materials enables polarization control via relative layer motion. However, polarization switching occurs on the time scale of shear modes (tens of ps) and requires very…

Materials Science · Physics 2026-05-26 Xiangzhou Zhu , Stefano Mocatti , Matteo Calandra

Ferroelectricity in atomically thin bilayer structures has been recently predicted1 and measured[2-4] in two-dimensional (2D) materials with hexagonal non-centrosymmetric unit-cells. Interestingly, the crystal symmetry translates lateral…

Interlayer stacking order has recently emerged as a unique degree of freedom to control crystal symmetry and physical properties in two-dimensional van der Waals (vdW) materials and heterostructures. By tuning the layer stacking pattern,…

Recent studies highlight the scientific importance and broad application prospects of two-dimensional (2D) sliding ferroelectrics, which prevalently exhibit vertical polarization with suitable stackings. It is crucial to understand the…

Materials Science · Physics 2024-07-23 Shihan Deng , Hongyu Yu , Junyi Ji , Changsong Xu , Hongjun Xiang

Despite their ionic nature, many layered diatomic crystals avoid internal electric polarization by forming a centrosymmetric lattice at their optimal anti-parallel van-der-Waals stacking. Here, we report a stable ferroelectric order…

Going beyond the bistability paradigm of the charge polarizations in ferroelectrics is highly desired for ferroelectric (FE) memory devices toward ultra-high-density information storage. Here, we propose to build multistates by combining…

Materials Science · Physics 2025-03-03 Chuhan Tang , Zhiqiang Tian , Tao Ouyang , Anlian Pan , Mingxing Chen

The bistability of charge polarization in ferroelectric materials has long been the basis of ferroelectric devices. However, the ferroelectricity tends to be vanishing as the thickness of materials is reduced to a few nanometers or thinner…

Materials Science · Physics 2023-12-22 Guoliang Yu , Shengxian Li , Anlian Pan , Mingxing Chen , Zhenyu Zhang

We address the sliding thermodynamics of van der Waals-bonded bilayers by the continuum elasticity theory. We attribute the robustness of the ferroelectricity recently observed in h-BN and WTe2 bilayers to large monolayer in-plane…

Mesoscale and Nanoscale Physics · Physics 2023-05-10 Ping Tang , Gerrit E. W. Bauer

Van der Waals (vdW) polytypes of broken inversion and mirror symmetries were recently shown to exhibit switchable electric polarization even at the ultimate two-layer thin limit. Their out-of-plane polarization was found to accumulate in a…

According to the recent studies on sliding/moire ferroelectricity, most 2D van der Waals nonferroelectric monolayers can become ferroelectric via multilayer stacking. In this paper we propose that similar strategy can be used to induce…

Materials Science · Physics 2025-07-24 Yuxuan Sheng , Junwei Liu , Jia Zhang , Menghao Wu

The recent discovery of ferroelectric behavior in few-layer materials, accompanied by the observation of antipolar domains in hexagonal boron nitride and transition metal dichalcogenide moir\'e bilayers, is paving the way for revolutionary…

Materials Science · Physics 2024-03-20 Pacheco-Sanjuan Alejandro , Kumar Pradeep , Barraza-Lopez Salvador

We propose ferroelectric layer sliding as a new approach to realize and manipulate topological quantum states in two-dimensional (2D) bilayer magnetic van der Waals materials. We show that stacking monolayer ferromagnetic topological states…

Materials Science · Physics 2025-08-13 Ning-Jing Yang , Jian-Min Zhang , Xiao-Ping Li , Zeying Zhang , Zhi-Ming Yu , Zhigao Huang , Yugui Yao

In a recent letter [Phys. Rev. Lett. {\bf 75}, 2360 (1996)] we briefly discussed the existence and nature of ferroelectric order in positionally disordered dipolar materials. Here we report further results and give a complete description of…

Disordered Systems and Neural Networks · Physics 2009-10-30 G. Ayton , M. J. P. Gingras , G. N. Patey

Sliding ferroelectricity is a unique type of polarity recently observed in a properly stacked van der Waals bilayer. However, electric-field control of sliding ferroelectricity is hard and could induce large coercive electric fields and…

Materials Science · Physics 2024-03-13 Jian Wang , Xu Li , Xingyue Ma , Lan Chen , Jun-Ming Liu , Chun-Gang Duan , Jorge Íñiguez-González , Di Wu , Yurong Yang

Two-dimensional (2D) van der Waals ferroelectrics are recognized for enabling many applications, from memory and logic to neuromorphic computing, as well as transforming other materials to control electronic phase transitions and…

Although most two-dimensional (2D) materials are non-ferroelectric with highly symmetric lattices, symmetry breaking may take place in their bilayers upon certain stacking order, giving rise to so-called sliding ferroelectricity where the…

Mesoscale and Nanoscale Physics · Physics 2023-04-10 Liu Yang , Menghao Wu
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