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Classical cellular automata represent a class of explicit discrete spacetime lattice models in which complex large-scale phenomena emerge from simple deterministic rules. With the goal to uncover different physically distinct classes of…

Statistical Mechanics · Physics 2026-05-27 Rustem Sharipov , Matija Koterle , Sašo Grozdanov , Tomaž Prosen

Recent advancements in abilities to create and manipulate the electron's transverse wave function within the transmission electron microscope (TEM) and scanning TEM (STEM) have enabled vectorially-resolved electron energy loss (EEL) and…

Mesoscale and Nanoscale Physics · Physics 2024-03-12 Austin G. Nixon , Matthieu Chalifour , Marc R. Bourgeois , Michael Sanchez , David J. Masiello

In pursuit of a colloidal analogue to quantum density functional theory (DFT) predictions of atomic crystal structures, we report a new, classical DFT that predicts the relative thermodynamic stability of colloidal crystals of hard, convex…

Soft Condensed Matter · Physics 2026-01-15 Kristi Pepa , Isaac R. Spivack , Trevor F. G. Teague , Ryn Y. Oliphant , Domagoj Fijan , Sharon C. Glotzer

The study of the electronic properties of charged defects is crucial for our understanding of various electrical properties of materials. However, the high computational cost of density functional theory (DFT) hinders the research on large…

Computational Physics · Physics 2023-06-16 Yuxing Ma , Yang Zhong , Yu Hongyu , Shiyou Chen , Hongjun Xiang

3D kinetic-scale turbulence is studied numerically in the regime where electrons are strongly magnetized (the ratio of plasma species pressure to magnetic pressure is $\beta_e=0.1$ for electrons and $\beta_i=1$ for ions). Such a regime is…

Plasma Physics · Physics 2023-07-05 Cristian Vega , Vadim Roytershteyn , Gian Luca Delzanno , Stanislav Boldyrev

The Kohn-Sham scheme of density functional theory is one of the most widely used methods to solve electronic structure problems for a vast variety of atomistic systems across different scientific fields. While the method is fast relative to…

Employing a local formula for the electron-electron interaction energy, we derive a self-consistent approximation for the total energy of a general $N$-electron system. Our scheme works as a local variant of the Thomas-Fermi approximation…

Chemical Physics · Physics 2013-10-31 E. Rasanen , A. Odriazola , I. Makkonen , A. Harju

We present a comprehensive investigation of electron capture (EC) ratios spanning a broad range of atomic numbers. The study employs a self-consistent computational method that incorporates electron screening, electron correlations, overlap…

Nuclear Theory · Physics 2023-07-26 V. A. Sevestrean , O. Niţescu , S. Ghinescu , S. Stoica

Multi-configurational electronic structure theory delivers the most versatile approximations to many-electron wavefunctions, flexible enough to deal with all sorts of transformations, ranging from electronic excitations, to open-shell…

Chemical Physics · Physics 2024-05-07 Kalman Szenes , Maximilian Moerchen , Paul Fischill , Markus Reiher

The development of efficient machine learning models for molecular systems representation is becoming crucial in scientific research. We introduce TensorNet, an innovative O(3)-equivariant message-passing neural network architecture that…

Machine Learning · Computer Science 2023-10-31 Guillem Simeon , Gianni de Fabritiis

We demonstrate how to determine numerically nearly exact orthonormal orbitals that are optimal for evaluation of the energy of arbitrary (correlated) states of atoms and molecules by minimization of the energy Lagrangian. Orbitals are…

Low-scaling electron correlation theory based on the pair natural orbital approximation, PNO-CCSD(T), has become a powerful computational tool. Motivated by the recent discovery of large errors for organometallic molecules, we assess the…

Chemical Physics · Physics 2023-10-10 Reka A. Horvath , Kesha Sorathia , Isabelle Saint , David P. Tew

We introduce discontinuous spectral-element methods of arbitrary order that are well balanced, conservative of mass, and conservative or dissipative of total energy (i.e., a mathematical entropy function) for a covariant flux formulation of…

Numerical Analysis · Mathematics 2026-02-10 Tristan Montoya , Andrés M. Rueda-Ramírez , Gregor J. Gassner

Wave functions based on electron-pair states provide inexpensive and reliable models to describe quantum many-body problems containing strongly-correlated electrons, given that broken-pair states have been appropriately accounted for by,…

Chemical Physics · Physics 2021-03-17 Artur Nowak , Ors Legeza , Katharina Boguslawski

Efficient electronic structure methods can be built around efficient tensor representations of the wavefunction. Here we describe a general view of tensor factorization for the compact representation of electronic wavefunctions. We use…

Computational Physics · Physics 2015-05-19 Jun Yang , Yuki Kurashige , Frederick R. Manby , Garnet K. L. Chan

The accuracy of density-functional theory (DFT) is determined by the quality of the approximate functionals, such as exchange-correlation in electronic DFT and the excess functional in the classical DFT formalism of fluids. The exact…

The reduced-density-matrix method is an promising candidate for the next generation electronic structure calculation method; it is equivalent to solve the Schr\"odinger equation for the ground state. The number of variables is the same as a…

Strongly Correlated Electrons · Physics 2011-06-27 Maho Nakata , Mituhiro Fukuda , Katsuki Fujisawa

We propose a setup enabling electron energy loss spectroscopy to determine the density of the electrons accumulated by an electro-positive dielectric in contact with a plasma. It is based on a two-layer structure inserted into a recess of…

Applied Physics · Physics 2020-01-08 E. Thiessen , F. X. Bronold , H. Fehske

It was recently shown [Y. Suzuki, L. Lacombe, K. Watanabe, and N. T. Maitra, Phys. Rev. Lett. 119, 263401 (2017)] that peak and valley structures in the exact exchange-correlation potential of time-dependent density functional theory are…

Chemical Physics · Physics 2018-07-04 Lionel Lacombe , Yasumitsu Suzuki , Kazuyuki Watanabe , Neepa T. Maitra

The general procedure underlying Hartree-Fock and Kohn-Sham density functional theory calculations consists in optimizing orbitals for a self-consistent solution of the Roothaan-Hall equations in an iterative process. It is often ignored…

Chemical Physics · Physics 2017-03-16 Alain C. Vaucher , Markus Reiher