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Cu$_2$O has appealing properties as an electrode for photo-electrochemical water splitting, yet its practical performance is severely limited by inefficient charge extraction at the interface. Using hybrid DFT calculations, we investigate…

Materials Science · Physics 2021-03-09 Chiara Ricca , Lisa Grad , Matthias Hengsberger , Jürg Osterwalder , Ulrich Aschauer

Surface electronic structures of the photoelectrodes determine the activity and efficiency of the photoelectrochemical water splitting, but the controls of their surface structures and interfacial chemical reactions remain challenging.…

Solar driven photoelectrochemical water splitting (PEC-WS) using semiconductor photoelectrodes represents a promising approach for a sustainable and environmentally friendly production of renewable energy vectors and fuel sources, such as…

Composite oxides have been indeed proved to be valuable materials in optoelectronic applications. The combination of indium oxide and gallium oxide and other materials can lead to enhanced optical and electronic properties, making them…

Materials Science · Physics 2024-03-20 Chrislene Lionel , Shubham Das , Diparnab Banik , S. Koley

Recent experiments demonstrated that interfacial water dissociation (H2O = H+ + OH-) could be accelerated exponentially by an electric field applied to graphene electrodes, a phenomenon related to the Wien effect. Here we report an…

This fluid dynamics video showcases how optically induced electrokinetic forces can be used to drive three-dimensional micro-vortices. The strong microfluidic vortices are used constructively in conjunction with other electrokinetic forces…

Fluid Dynamics · Physics 2015-05-13 Stuart J. Williams , Aloke Kumar , Steven T. Wereley

Emergent phenomena at complex-oxide interfaces have become a vibrant field of study in the past two decades due to the rich physics and a wide range of possibilities for creating new states of matter and novel functionalities for potential…

Materials Science · Physics 2024-06-19 C. -T. Kuo , G. Conti , J. E. Rault , C. M. Schneider , S. Nemšák , A. X. Gray

The chemical modification of electrodes with organic materials is a common approach to tune the electronic and electrostatic landscape between interlayers in optoelectronic devices, thus facilitating charge injection at the…

Vanadium dioxide (VO$_2$) is a strongly-correlated material that exhibits insulator-to-metal transition (IMT) near room temperature, which makes it a promising candidate for applications in nanophotonics or optoelectronics. However,…

In2S3(1-x)O3x is known from preceding studies to have a bandgap varying continuously as a function of x, the reason why this solid solution is potentially interesting in the field of photovoltaics. In this work, we present results on…

Materials Science · Physics 2014-03-25 Souad Laghrib , Melia Hamici , Yaovi Gagou , Lidice Vaillant Roca , Pierre Saint-Grégoire

We report the development of indium oxide (In2O3) transistors via a single step laser-induced photochemical conversion process of a sol-gel metal oxide precursor. Through careful optimization of the laser annealing conditions we…

Materials Science · Physics 2017-05-26 S. Dellis , I. Isakov , N. Kalfagiannis , K. Tetzner , T. D. Anthopoulos , D. C. Koutsogeorgis

Polar perovskite oxide surfaces are subject to structural reconstruction as a possible stabilisation mechanisms, which changes the surface structure and hence the surface chemistry. To investigate this effect, we study the oxygen evolution…

Materials Science · Physics 2019-04-08 Hassan Ouhbi , Ulrich Aschauer

(Photo)electrocatalysts capture sunlight and use it to drive chemical reactions such as water splitting to produce H2. A major factor limiting photocatalyst development is their large heterogeneity which spatially modulates reactivity and…

The last decade has witnessed the emergence of hydrovoltaic technology, which can harvest electricity from different forms of water movement, such as raindrops, waves, flows, moisture, and natural evaporation. In particular, the…

Chemical Physics · Physics 2023-04-10 Chunxiao Zheng , Sunmiao Fang , Weicun Chu , Jin Tan , Bingkun Tian , Xiaofeng Jiang , Wanlin Guo

The photo-induced desorption and oxidation of CO on Ru(0001) is simulated using ab initio molecular dynamics with electronic friction that accounts for the non-equilibrated excited electrons and phonons. Different (O,CO) coverages are…

Materials Science · Physics 2023-07-06 Auguste Tetenoire , J. Iñaki Juaristi , Maite Alducin

The ground and excited state electronic structure of the molecular photoswitches quadricyclane and norbornadiene is examined qualitatively and quantitatively. A new custom basis set is introduced, optimised for efficient yet accurate…

Chemical Physics · Physics 2025-10-07 Joseph C. Cooper , Adam Kirrander

Selective two-electron oxygen reduction reaction (ORR) offers a promising route for hydrogen peroxide synthesis, and defective sp2 carbon-based materials are attractive, low-cost electrocatalysts for this process. However, due to a wide…

The oxygen reduction reaction (ORR) plays a pivotal role in clean energy generation and sustainable chemical production, particularly in the synthesis of hydrogen peroxide (H\textsubscript{2}O\textsubscript{2}). In this study,…

$V_2O_3$ has long been studied as a prototypical strongly correlated material. The difficulty in obtaining clean, well ordered surfaces, however, hindered the use of surface sensitive techniques to study its electronic structure. Here we…

Metal-Organic frameworks (MOFs) are promising candidates for advanced photocatalytically active materials. These porous crystalline compounds have large active surface areas and structural tunability and are thus highly competitive with…