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Bilayers of two-dimensional van der Waals materials that lack an inversion centre can show a novel form of ferroelectricity, where certain stacking arrangements of the two layers lead to an interlayer polarization. Under an external…

Superconductivity · Physics 2024-06-27 Gaurav Chaudhary , Ivar Martin

Conventional perovskite-type ferroelectrics are based on octahedral units of oxygen, and often comprise toxic Pb to achieve robust ferroelectricity. Here, we report the ferroelectricity in a silicate-based compound, Bi2SiO5 (BSO), induced…

Ferroelectric hafnia exhibits promising robust polarization and silicon compatibility for ferroelectric devices. Unfortunately, it suffers from difficult polarization switching. Methods to enable easier polarization switching are needed,…

Materials Science · Physics 2024-04-24 Songsong Zhou , Andrew M. Rappe

Hidden spin polarization (HSP) emerges in centrosymmetric crystals where visible spin splittings in the real space can be observed because of the lack of inversion symmetry in each local sector. Starting from tight-binding models, we…

Materials Science · Physics 2020-11-18 Shan Guan , Jun-Wei Luo

Materials that can produce large controllable strains are widely used in shape memory devices, actuators and sensors. Great efforts have been made to improve the strain outputs of various material systems. Among them, ferroelastic…

Switching in magnetic materials gives rise to rich physical phenomena and lies at the heart of their technological applications. Although domain wall motion in ferro- and antiferromagnets has been studied, in spiral magnets it is still…

Strongly Correlated Electrons · Physics 2024-02-19 Francesco Foggetti , Margherita Parodi , Naoto Nagaosa , Sergey Artyukhin

Simultaneous imaging of the piezoresponse phase, amplitude and bare surface topography of displacive ferroelectric thin films by scanning probe microscopy directly shows the nature of domain wall pinning and its relation to morphological…

Mesoscale and Nanoscale Physics · Physics 2010-01-05 S. Bhattacharya , M. J. Higgins

We present a first-principles study of ferroelectric domain walls (FE-DWs) in multiferroic BiFeO$_3$ (BFO), a material in which the FE order parameter coexists with anti-ferrodistortive (AFD) modes involving rotations of the O$_6$…

Materials Science · Physics 2015-06-12 Oswaldo Diéguez , Pablo Aguado-Puente , Javier Junquera , Jorge Íñiguez

We present a first-principles study of model domain walls (DWs) in prototypic ferroelectric PbTiO3. At high temperature the DW structure is somewhat trivial, with atoms occupying high- symmetry positions. However, upon cooling the DW…

Materials Science · Physics 2014-06-24 Jacek C. Wojdel , Jorge Iniguez

Smart electronic circuits that support neuromorphic computing on the hardware level necessitate materials with memristive, memcapacitive, and neuromorphic-like functional properties; in short, the electronic response must depend on the…

Pseudospin models are proposed for description of the phase transitions, dielectric characteristics, and polarization switching in two crystals of the phenyltetrazole family. One of them, APHTZ, is a canted ferroelectric, whereas the other,…

Materials Science · Physics 2025-11-05 A. P. Moina

While nature provides a plethora of perovskite materials, only a few exhibits large ferroelectricity and possibly multiferroicity. The majority of perovskite materials have the non-polar CaTiO$_3$(CTO)structure, limiting the scope of their…

Materials Science · Physics 2022-05-25 Hongwei Wang , Fujie Tang , Massimiliano Stengel , Hongjun Xiang , Qi An , Tony Low , Xifan Wu

Using a Ginzburg--Landau--Devonshire model that includes the coupling of polarization to strain, we calculate the fluctuation spectra of ferroelectric domain walls. The influence of the strain coupling differs between 180 degree and 90…

Materials Science · Physics 2015-06-16 R. T. Brierley , P. B. Littlewood

Ferroelectric domain walls are boundaries between regions with different polarization orientations in a ferroelectric material. Using first principles calculations, we characterize all different types of domain walls forming on…

Materials Science · Physics 2020-04-16 Đorđe Dangić , Éamonn D. Murray , Stephen Fahy , Ivana Savić

The most characteristic functional property of antiferroelectric materials is the possibility to induce a phase transition from a non-polar to a polar phase by an electric field. Here, we investigate the effect of this field-induced phase…

Interfaces at the two-dimensional limit in oxide materials exhibit a rich span of functionality that differs significantly from the bulk behavior. Among such interfaces, domain walls in ferroelectrics draw special attention because they can…

Materials Science · Physics 2020-02-19 Maya Barzilay , Yachin Ivry

While scandium-doped aluminum nitride (AlScN) exhibits robust ferroelectricity and excellent thermal stability, its utility is limited by an exceptionally high coercive field ($E_c$) for polarization switching. Unraveling the atomistic…

Materials Science · Physics 2026-05-21 Xiangyu Zheng , Charles Paillard , Dawei Wang , Peng Chen , Hong Jian Zhao , Yu Xie , Laurent Bellaiche

Sliding ferroelectricity is highly attractive for its low energy barriers and fatigue resistance. As the origin of these exotic properties, its unconventional switching dynamics remains poorly understood: how an electric field drives a…

Materials Science · Physics 2025-05-30 Ziwen Wang , Shuai Dong

We investigate the polarization switching mechanism in ferroelectric-dielectric (FE-DE) stacks and its dependence on the dielectric thickness (TDE). We fabricate HZO-Al2O3 (FE-DE) stack and experimentally demonstrate a decrease in remnant…

Applied Physics · Physics 2021-10-04 Atanu K. Saha , Mengwei Si , Peide D. Ye , Sumeet K. Gupta

The first switchable electric polarization in metals was recently discovered in bilayer and trilayer WTe2. Strangely, despite the tininess of the ordered polarization, the ferroelectricity survives up to 350 K, rendering the mechanism of…

Materials Science · Physics 2025-07-25 Fangyuan Gu , Ruoshi Jiang , Wei Ku