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Rare-earth nickelates RNiO3 (R=rare-earth element) exhibit three kinds of phase transitions with decreasing temperature: a structural transition from a pseudo-cubic to a monoclinic phase, a metal- insulator transition (MIT), and a magnetic…

By means of molecular-dynamics simulations, temperature driven diffusionless structural phase transitions in equi- and nearly equiatomic ordered nickel-titanium alloys were investigated. For this purpose, a model potential from the…

Materials Science · Physics 2022-01-04 Daniel Mutter , Peter Nielaba

While most of the rare-earth nickelates exhibit a temperature-driven sharp metal-insulator transition, LaNiO$_3$ is the only exception remaining metallic down to low temperatures. Using local density approximation as an input to dynamical…

Strongly Correlated Electrons · Physics 2014-03-04 Debolina Misra

We report on a metal-insulator transition (MIT) that is observed in an electron system at the SmTiO3/SrTiO3 interface. This MIT is characterized by an abrupt transition at a critical temperature, below which the resistance changes by more…

Strongly Correlated Electrons · Physics 2017-06-13 Kaveh Ahadi , Susanne Stemmera

We develop a procedure to determine the portion of exact Hartree-Fock exchange interaction contained in a hybrid density functional to treat the range of electronic correlation governing the physics of a system as a function of a…

Materials Science · Physics 2016-02-26 Pablo Rivero , Vincent Meunier , William Shelton

We show that the pressure-induced metal-insulator transition (MIT) in LaMnO$_3$ is fundamentally different from the Mott-Hubbard transition and is percolative in nature, with the measured resistivity obeying the percolation scaling laws.…

Strongly Correlated Electrons · Physics 2016-01-14 M. Sherafati , M. Baldini , L. Malavasi , S. Satpathy

Interaction between the lattice and the orbital degrees of freedom not only makes rare-earth nickelates unusually "bad metal", but also introduces a temperature driven insulator-metal phase transition. Here we investigate this…

Strongly Correlated Electrons · Physics 2014-08-20 Anindita Sahoo , Sieu D. Ha , Shriram Ramanathan , Arindam Ghosh

The metal-insulator transition (MIT) of bulk rare-earth nickelates is accompanied by a simultaneous charge ordering (CO) transition. We have investigated low-frequency resistance fluctuations (noise) across the MIT and magnetic transition…

Strongly Correlated Electrons · Physics 2019-09-05 Gopi Nath Daptary , Siddharth Kumar , M. Kareev , J. Chakhalian , Aveek Bid , S. Middey

Rare-earth nickelates form an intriguing series of correlated perovskite oxides. Apart from LaNiO3, they exhibit on cooling a sharp metal-insulator electronic phase transition, a concurrent structural phase transition and a magnetic phase…

Materials Science · Physics 2018-02-07 Alain Mercy , Jordan Bieder , Jorge Iniguez , Philippe Ghosez

The recent observation of a insulator to metal transition (IMT) [I. Loa et al, PRL 87, 125501 (2001)] in pure LaMnO$_3$ at 32 GPa and room temperature, well above the Neel temperature (145 K) and below the Jahn-Teller transition temperature…

Strongly Correlated Electrons · Physics 2009-04-16 Javier D. Fuhr , Blas Alascio , Michel Avignon

Bulk NdNiO3 exhibits a metal-to-insulator transition (MIT) as the temperature is lowered that is also seen in tensile strained films. In contrast, films that are under a large compressive strain typically remain metallic at all…

Strongly Correlated Electrons · Physics 2016-04-05 Jack Y. Zhang , Honggyu Kim , Evgeny Mikheev , Adam J. Hauser , Susanne Stemmer

In complex oxide materials, changes in electronic properties are often associated with changes in crystal structure, raising the question of the relative roles of the electronic and lattice effects in driving the metal-insulator transition.…

Strongly Correlated Electrons · Physics 2019-07-23 Alexandru B. Georgescu , Oleg E. Peil , Ankit Disa , Antoine Georges , Andrew J. Millis

The metal to insulator transition (MIT) in Mott-Hubbard systems is one of the most important discoveries in condensed matter physics, and results in abrupt orbital transitions from the insulating to metallic phases by elevating temperature…

Applied Physics · Physics 2019-04-02 Jikun Chen , Haiyang Hu , Takeaki Yajima , Jiaou Wang , Binghui Ge , Hongliang Dong , Yong Jiang , Nuofu Chen

With the development of electronic structure theory, a new class of materials - quantum ones has been recognized by the community. Traditionally, it has been believed that the properties of such compounds cannot be described within the…

Materials Science · Physics 2023-11-10 Himanshu Joshi , Mateusz Wlazło , Harshan Reddy Gopidi , Oleksandr I. Malyi

The origin of simultaneous electronic, structural and magnetic transitions in bulk rare-earth nickelates ($RE$NiO$_3$) remains puzzling with multiple conflicting reports on the nature of these entangled phase transitions. Heterostructure…

Strongly Correlated Electrons · Physics 2019-07-15 Shashank Kumar Ojha , Sujay Ray , Tanmoy Das , S. Middey , Sagar Sarkar , Priya Mahadevan , Zhen Wang , Yimei Zhu , Xiaoran Liu , M. Kareev , J. Chakhalian

The temperature dependence of the local structure of V_2O_3 in the vicinity of the metal to insulator transition (MIT) has been investigated using hard X-ray absorption spectroscopy. It is shown that the vanadium pair distance along the…

Strongly Correlated Electrons · Physics 2009-11-11 P. Pfalzer , G. Obermeier , M. Klemm , S. Horn , M. L. denBoer

Metal to insulator transitions (MITs) driven by strong electronic correlations are common in condensed matter systems, and are associated with some of the most remarkable collective phenomena in solids, including superconductivity and…

Strongly Correlated Electrons · Physics 2019-12-20 G. G. Guzmán-Verri , R. T. Brierley , P. B. Littlewood

Symmetry-lowering structural phase transitions result in multiple degenerate structures whose coexistence is determined by macroscopic strain compatibility. In quantum materials, these structural transformations often couple to electronic…

Available simulation methods, suitable to describe solid-solid phase transitions occurring upon increasing of presssure and/or temperature, are based on empirical interatomic potentials: this restriction reduces the predictive power, and…

Condensed Matter · Physics 2016-08-31 P. Focher , G. L. Chiarotti , M. Bernasconi , E. Tosatti , M. Parrinello

Rare-earth nickelates exhibit a remarkable metal-insulator transition accompanied by a structural transition associated with a lattice `breathing' mode. Using model considerations and first-principles calculations, we present a theory of…

Strongly Correlated Electrons · Physics 2019-06-19 Oleg E. Peil , Alexander Hampel , Claude Ederer , Antoine Georges
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