Related papers: Computing Anharmonic Infrared Spectra of Polycycli…
We present a new method for generating emission spectra from polycyclic aromatic hydrocarbons (PAHs) in arbitrary radiation fields. We utilize the single-photon limit for PAH heating and emission to treat individual photon absorptions as…
The unidentified infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, and 11.3 micrometer, commonly attributed to polycyclic aromatic hydrocarbon (PAH) molecules, have been recently ascribed to coal- or kerogen-like organic nanoparticles…
The PHANGS survey uses ALMA, HST, VLT, and JWST to obtain an unprecedented high-resolution view of nearby galaxies, covering millions of spatially independent regions. The high dimensionality of such a diverse multi-wavelength dataset makes…
Ratios of polycyclic aromatic hydrocarbon (PAH) vibrational bands are a promising tool for measuring the properties of the PAH population and their effect on star formation. The photometric bands of the MIRI and NIRCam instruments on JWST…
Using the Mid-Infrared Spectrometer on board the Infrared Telescope in Space and the low-resolution grating spectrometer (PHT-S) on board the Infrared Space Observatory, we obtained 820 mid-infrared (5 to 12 $\mu$m) spectra of the diffuse…
Emission from a class of benzene-based molecules known as Polycyclic Aromatic Hydrocarbons (PAHs) dominates the infrared spectrum of star-forming regions. The observed emission appears to arise from the combined emission of numerous PAH…
We report new correlations between ratios of band intensities of the 15-20 {\mu}m emission bands of polycyclic aromatic hydrocarbons (PAHs) in a sample of fifty-seven sources observed with Spitzer/IRS. This sample includes Large Magellanic…
The structure and chemistry of the dusty interstellar medium (ISM) are shaped by complex processes that depend on the local radiation field, gas composition, and dust grain properties. Of particular importance are Polycyclic Aromatic…
We report on the absorption spectra of the polycyclic aromatic hydrocarbon (PAH) molecules anthracene, phenanthrene, and pyrene carrying either an ethynyl (-C2H) or a butadiynyl (-C4H) group. Measurements were carried out in the mid…
We present the results of near- to mid-infrared slit spectroscopic observations (2.55--13.4 um) of the diffuse emission toward nine positions in the Large Magellanic Cloud with the Infrared Camera (IRC) on board AKARI. The target positions…
Molecular dynamics (MD) employing machine-learned interatomic potentials (MLIPs) serve as an efficient, urgently needed complement to ab initio molecular dynamics (aiMD). By training these potentials on data generated from ab initio…
Linear resonance (LR) absorption of an intense 800~nm laser light in a nano-cluster requires a long laser pulse > 100~fs when Mie-plasma frequency ($\omegaMie$) of electrons in the expanding cluster matches the laser frequency~($\omega$).…
Context. In the framework of the interstellar polycyclic aromatic hydrocarbons (PAHs) hypothesis, far-IR skeletal bands are expected to be a fingerprint of single species in this class. Aims. We address the question of detectability of low…
Planet-forming disks of gas and dust around young stars contain polycyclic aromatic hydrocarbons (PAHs). We aim to characterize how the charge state of PAHs can be used as a probe of flows of gas through protoplanetary gaps. In this…
Polycyclic Aromatic Hydrocarbons (PAHs) have long been invoked in the study of interstellar and protostellar sources, but the unambiguous identification of any individual PAH has proven elusive until very recently. As a result, the…
One of the major challenges to identification of the 3.3, 6.2, 7.7, 8.6, and 11.3um interstellar IR emission bands with polycyclic aromatic hydrocarbon (PAH) molecules has been the recent detection of these bands in regions with little UV…
Interstellar dust shows ubiquitous interstellar infrared spectrum (IR) due to polycyclic aromatic hydrocarbon (PAH). By our previous quantum chemistry calculation, it was suggested that a molecule group having hydrocarbon pentagon-hexagon…
A gas-phase optical spectrum of a large polycyclic aromatic hydrocarbon (PAH) cation - C78H26 +- in the 410-610 nm range is presented. This large all-benzenoid PAH should be large enough to be stable with respect to photodissociation in the…
The unidentified infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, 11.3 and 12.7 micron are ubiquitously seen in a wide variety of astrophysical regions and commonly attributed to polycyclic aromatic hydrocarbon (PAH) molecules.…
Polycyclic aromatic hydrocarbons (PAHs) appear to be ubiquitous in terrestrial atmosphere as well as in the interstellar medium (ISM). In the astrophysical context presence of PAHs is interpreted by the observations of mid-IR emission bands…