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The self-consistent field theory (SCFT) is a powerful framework for the study of the phase behavior and structural properties of many-body systems. In particular, polymeric SCFT has been successfully applied to inhomogeneous polymeric…

Soft Condensed Matter · Physics 2019-01-31 An-Chang Shi

Self-consistent field theory (SCFT) has proven to be a powerful tool for modeling equilibrium microstructures of soft materials, particularly for multiblock polymers. A very successful approach to numerically solving the SCFT set of…

Soft Condensed Matter · Physics 2017-01-04 David M. Ackerman , Kris Delaney , Glenn H. Fredrickson , Baskar Ganapathysubramanian

Self-consistent field theory (SCFT) is one of the most widely-used framework in studying the equilibrium phase behaviors of inhomogenous polymers. For liquid crystalline polymeric systems, the main numerical challenges of solving SCFT…

Numerical Analysis · Mathematics 2024-09-16 Zhijuan He , Kai Jiang , Liwei Tan , Xin Wang

Block copolymers provide a wonderful platform in studying the soft condensed matter systems. Many fascinating ordered structures have been discovered in bulk and confined systems. Among various theories, the self-consistent field theory…

Soft Condensed Matter · Physics 2019-05-01 Huayi Wei , Ming Xu , Wei Si , Kai Jiang

We present a self-consistent field theory (SCFT) of semiflexible (wormlike) diblock copolymers, each consisting of a rigid and a flexible part. The segments of the polymers are otherwise identical, in particular with regard to their…

Soft Condensed Matter · Physics 2009-11-07 Dominik Düchs , D. E. Sullivan

An efficient pseudo-spectral numerical method is introduced for calculating a self-consistent field (SCF) approximation for the linear susceptibility of ordered phases in block copolymer melts (sometimes referred to as the random phase…

Soft Condensed Matter · Physics 2009-11-13 Amit Ranjan , Jian Qin , David C. Morse

Self-consistent field theory (SCFT) and strong segregation theory (SST) are used to explore the parameter space governing the self-assembly of cylinder forming block copolymers (BCPs) on a modulated substrate. The stability of in-plane…

Materials Science · Physics 2018-11-16 Karim Gadelrab , Alfredo Alexander-Katz

We introduce a mesoscale technique for simulating the structure and rheology of block copolymer melts and blends in hydrodynamic flows. The technique couples dynamic self consistent field theory (DSCFT) with continuum hydrodynamics and flow…

Soft Condensed Matter · Physics 2009-11-11 David M. Hall , Turab Lookman , Glenn H. Fredrickson , Sanjoy Banerjee

Our work establishes the mathematical equivalence between polymer Self Consistent Field Theory and interfacial SAFT based classical Density Functional Theory by providing an explicit proof that SCFT is the mean field (MF) or saddle point…

Mesoscale and Nanoscale Physics · Physics 2025-12-10 Maximo T. Estrada

We present a self-consistent field theory (SCFT) study of spherical micelle formation in a blend of poly(styrene-butadiene) diblocks and homopolystyrene. The micelle core radii, corona thicknesses and critical micelle concentrations are…

Soft Condensed Matter · Physics 2011-06-28 M. J. Greenall , D. M. A. Buzza , T. C. B. McLeish

We investigate the properties of a system of semi-diluted polymers in the presence of charged groups and counter-ions, by means of self-consistent field theory. We study a system of polyelectrolyte chains grafted to a similarly, as well as…

Soft Condensed Matter · Physics 2015-05-19 Gabriele Migliorini

A self consistent field theory for compressible polymer mixtures is developed by introducing elements of classical density functional theory into the framework of the Helfand theory. It is then applied to study free surfaces of binary (A,B)…

Condensed Matter · Physics 2009-10-28 F. Schmid

This paper concerns the analytic structure of the self-consistent field theory (SCFT) energy functional of multicomponent block copolymer systems which contain more than two chemically distinct blocks. The SCFT has enjoyed considered…

Computational Physics · Physics 2013-10-07 Kai Jiang , Weiquan Xu , Pingwen Zhang

A generalized self-consistent field approach for polymer networks with fixed topology is developed. It is shown that the theory reproduces the localization of crosslinks which is characteristic for gels. The theory is then used to study the…

Soft Condensed Matter · Physics 2015-06-17 Friederike Schmid

A quantum-field approach for describing many-particle Fermi systems at finite temperatures and with spontaneously broken symmetry has been proposed. A generalized model of self-consistent field (SCF), which allows one to describe the states…

Statistical Mechanics · Physics 2013-03-21 Yu. M. Poluektov

We propose a high-speed and accurate hybrid dynamic density functional theory for the computer simulations of the phase separation processes of polymer melts and blends. The proposed theory is a combination of the dynamic self-consistent…

Soft Condensed Matter · Physics 2009-11-11 Takashi Honda , Toshihiro Kawakatsu

Diblock copolymers blended with homopolymer may self-assemble into spherical, cylindrical or lamellar aggregates. Transitions between these structures may be driven by varying the homopolymer molecular weight or the molecular weight or…

Statistical Mechanics · Physics 2011-06-28 M. J. Greenall , D. M. A. Buzza , T. C. B. McLeish

We review various methods to investigate the statics and the dynamics of collective composition fluctuations in dense polymer mixtures within fluctuating-field approaches. The central idea of fluctuating-field theories is to rewrite the…

Soft Condensed Matter · Physics 2007-05-23 Marcus Mueller , Friederike Schmid

The self-consistent field (SCF) theory of dense polymer liquids assumes that short-range correlations are almost independent of how monomers are connected into polymers. Some limits of this idea are explored in the context of a perturbation…

Soft Condensed Matter · Physics 2015-05-13 David C. Morse , Jun Kyung Chung

We describe a version of an algorithm for evolving self-gravitating collections of particles that should be nearly ideal for parallel architectures. Our method is derived from the ``self-consistent field'' (SCF) approach suggested…

Astrophysics · Physics 2016-08-30 Lars Hernquist , Steinn Sigurdsson , Greg L. Bryan
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