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Using a break junction technique, we find a clear signature for the formation of conducting hybrid junctions composed of a single organic molecule (benzene, naphthalene or anthracene) connected to chains of platinum atoms. The hybrid…

Mesoscale and Nanoscale Physics · Physics 2015-06-23 Tamar Yelin , Ran Vardimon , Natalia Kuritz , Richard Korytár , Alexei Bagrets , Ferdinand Evers , Leeor Kronik , Oren Tal

We have studied charge transport through individual Borromean Ring complexes, both with and without anchor groups, in gated double barrier tunneling junctions (DBTJs) formed using the electrical breakjunction technique on gold nanowires.…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 G. D. Scott , K. S. Chichak , A. J. Peters , S. J. Cantrill , J. F. Stoddart , H. W. Jiang

Accurate electrical amplification is essential in molecular electronics for measuring conductance through atomic and molecular junctions, where currents often span several orders of magnitude. In this work, we present a systematic design…

Mesoscale and Nanoscale Physics · Physics 2026-04-20 J. Escorza , G. Pellicer , T. de Ara , J. Hurtado-Gallego , E. Scheer , C. Untiedt , C. Sabater

Breakjunction experiments allow investigating electronic and spintronic properties at the atomic and molecular scale. These experiments generate by their very nature broad and asymmetric distributions of the observables of interest, and…

Mesoscale and Nanoscale Physics · Physics 2023-09-20 Dylan Dyer , Oliver L. A. Monti

Using first-principles calculations based on density functional theory combined with the non-equilibrium Green's function approach, the transport behaviors of a single-molecule junction formed by benzenedithiol connected to gold electrodes…

Materials Science · Physics 2022-09-20 Rigao Wang , Feng Shuang , Xiaowen Shi , Mingyan Chen

We consider a model inspired by a metal break-junction hypothetically caught at its breaking point, where the non-adiabatic center-of-mass motion of the bridging atom can be treated as a two-level system. By means of Numerical…

Strongly Correlated Electrons · Physics 2009-11-13 P. Lucignano , G. E. Santoro , M. Fabrizio , E. Tosatti

Despite its fundamental importance for nano physics and chemistry and potential device applications, the relationship between atomic structure and electronic transport in molecular nanostructures is not well understood. Thus the…

Mesoscale and Nanoscale Physics · Physics 2014-02-04 Alireza Saffarzadeh , Firuz Demir , George Kirczenow

We review recent results on electronic and thermal transport in two different quasi one-dimensional systems: Silicon nanowires (SiNW) and atomic gold chains. For SiNW's we compute the ballistic electronic and thermal transport properties on…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 A. P. Jauho , M. Engelund , T. Markussen , M. Brandbyge

We have developed an efficient scalable kernel method for thermal transport in open systems, with which we have computed the thermal conductance of a junction between bulk silicon and silicon nanowires with diameter up to 10 nm. We have…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 Ivan Duchemin , Davide Donadio

Molecules with versatile functionalities and well-defined structures, can serve as building blocks for extreme nanoscale devices. This requires their precise integration into functional heterojunctions, most commonly in the form of…

The process of creating an atomically defined and robust metallic tip is described and quantified using measurements of contact conductance between gold electrodes and numerical simulations. Our experiments show how the same conductance…

Materials Science · Physics 2012-05-30 C. Sabater , C. Untiedt , J. J. Palacios , M. J. Caturla

We study the structural and electronic properties of phase III of solid hydrogen using accurate many-electron theories and compare to state-of-the-art experimental findings. The atomic structures of phase III modelled by C2/c-24 crystals…

Materials Science · Physics 2021-02-24 Ke Liao , Tong Shen , Xin-Zheng Li , Ali Alavi , Andreas Grüneis

Functionalization of nanoporous metallic materials enables the tailoring of surface chemistry and morphology in nanostructured materials, optimising their performance for electrocatalytic and sensor applications. Liquid phase chemical…

The conductance of breaking metallic nanojunctions shows plateaus alternated with sudden jumps, corresponding to the stretching of stable atomic configurations and atomic rearrangements, respectively. We investigate the structure of the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 A. Halbritter , Sz. Csonka , G. Mihály , O. I. Shklyarevskii , S. Speller , H. van Kempen

Many experiments have shown that the conductance histograms of metallic atomic-sized contacts exhibit a peak structure, which is characteristic of the corresponding material. The origin of these peaks still remains as an open problem. In…

Mesoscale and Nanoscale Physics · Physics 2007-10-02 M. Dreher , F. Pauly , J. Heurich , J. C. Cuevas , E. Scheer , P. Nielaba

An integrated piecewise thermal equilibrium approach based on the first-principles calculation method has been developed to calculate bias dependent electronic structures and current- and differential conductance-voltage characteristics of…

Other Condensed Matter · Physics 2009-11-13 M. -H. Tsai , T. -H. Lu , Y. -H. Tang

We have developed a technology to reproducibly make gaps with distance control on the single atom scale. The gold contacts are flat on the nanometre scale and are fabricated on an oxidized aluminium film that serves as a gate. We show that…

Materials Science · Physics 2009-11-10 Y. V. Kervennic , D. Vanmaekelbergh , L. P Kouwenhoven , H. S. J Van der Zant

We explore the thermoelectric properties of gold atomic chains bridging gold electrodes by means of \textit{ab initio} and semi-empirical calculations, and heuristic reasoning. We predict the thermoelectric voltage induced by a temperature…

Mesoscale and Nanoscale Physics · Physics 2018-09-28 Alireza Saffarzadeh , Firuz Demir , George Kirczenow

Semi-Empirical Tight Binding (TB) is known to be a scalable and accurate atomistic representation for electron transport for realistically extended nano-scaled semiconductor devices that might contain millions of atoms. In this paper an…

Materials Science · Physics 2015-06-18 Ganesh Hegde , Michael Povolotskyi , Tillmann Kubis , Timothy Boykin , Gerhard Klimeck

Nanowires of different nature have been shown to self-assemble as a function of stress at the contact between two macroscopic metallic leads. Here we demonstrate for gold wires that the balance between various metastable nanowire…

Mesoscale and Nanoscale Physics · Physics 2017-12-11 I. K. Yanson , O. I. Shklyarevskii , Sz. Csonka , H. van Kempen , S. Speller , A. I. Yanson , J. M. van Ruitenbeek