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The bulk photovoltaic effect (BPVE) -- generation of electric currents by light in noncentrosymmetric materials in the absence of electric fields and gradients -- has been intensively investigated in the end of the last century. The…

Mesoscale and Nanoscale Physics · Physics 2019-11-28 Boris Sturman

The nonlinear shift current, also known as the bulk photovoltaic current generated by linearly polarized light, has long been known to be absent in crystals with inversion symmetry. Here we argue that a non-zero shift current in…

Mesoscale and Nanoscale Physics · Physics 2021-05-19 Li-kun Shi , Dong Zhang , Kai Chang , Justin C. W. Song

The bulk photovoltaic effect (BPVE) refers to the direct current generation in a noncentrosymmetric material under illumination and can be applied to solar energy technology. BPVE includes injection and shift currents, led by the change of…

Mesoscale and Nanoscale Physics · Physics 2025-11-04 Bo-Xin Lin , Hsiu-Chuan Hsu

The bulk photovoltaic effect (BPVE) occurs in solids with broken inversion symmetry and refers to DC current generation due to uniform illumination, without the need of heterostructures or interfaces, a feature that is distinct from the…

Materials Science · Physics 2022-06-02 Zhenbang Dai , Andrew M. Rappe

A bulk material without inversion symmetry can generate a direct current under illumination. This interface-free current generation mechanism, referred to as the bulk photovoltaic effect (BPVE), does not rely on $p$-$n$ junctions. Here, we…

Materials Science · Physics 2023-05-01 Zhuang Qian , Jian Zhou , Hua Wang , Shi Liu

The bulk photovoltaic effect provides a fundamental pathway for direct light-to-current conversion in quantum materials. However, these nonlinear currents are often strictly constrained or forbidden by crystal symmetries, hindering their…

Mesoscale and Nanoscale Physics · Physics 2026-05-25 Zhuocheng Lu , Zhuang Qian , Zhichao Guo , Likun Shi , Shi Liu , Hua Wang , Kai Chang

The bulk photovoltaic effect (BPVE) is a second-order optical process in noncentrosymmetric materials that converts the light into DC currents. BPVE is classified into shift current and injection current according to the generation…

Materials Science · Physics 2023-02-21 Hanqi Pi , Shuai Zhang , Hongming Weng

The bulk photovoltaic effect (BPVE) refers to the phenomenon of generating photocurrent or photovoltage in homogeneous noncentrosymmetric materials under illumination, and the intrinsic contribution to the BPVE is known as the shift current…

Materials Science · Physics 2023-02-01 Gan Jin , Lixin He

We study the bulk photovoltaic effect (BPVE) in Dirac and Weyl semimetals under two-frequency light irradiation. We show that the BPVE emerges for centrosymmetric Dirac and Weyl semimetals in the presence of light fields with frequencies…

Mesoscale and Nanoscale Physics · Physics 2025-01-15 Yuya Ikeda , Sota Kitamura , Takahiro Morimoto

The bulk photovoltaic effect (BPVE), a manifestation of broken centrosymmetry, has attracted interest as a probe of the symmetry and quantum geometry of materials, and for use in novel optoelectronic devices. Despite its bulk nature, the…

Photodetection is an indispensable function of optoelectronic devices in modern communication and sensing systems. Contrary to the near-infrared/visible regions, the fast and sensitive photodetectors operated at room temperature for the…

The two-dimensional (2D) bulk photovoltaic effect (BPVE) is a cornerstone for future highly efficient 2D solar cells and optoelectronics. The ferromagnetic semiconductor 2H-FeCl2 is shown to realize a new type of BPVE in which spatial…

Materials Science · Physics 2023-06-16 Liang Liu , Xiaolin Li , Luping Du , Xi Zhang

The correlation between the shift current mechanism for the bulk photovoltaic effect (BPVE) and the structural and electronic properties of ferroelectric perovskite oxides is not well understood. Here, we study and engineer the shift…

Materials Science · Physics 2015-03-03 Fenggong Wang , Steve M. Young , Fan Zheng , Ilya Grinberg , Andrew M. Rappe

The bulk photovoltaic effect (BPVE) refers to current generation due to illumination by light in a homogeneous bulk material lacking inversion symmetry. In addition to the intensively studied shift current, the ballistic current, which…

Materials Science · Physics 2021-05-05 Zhenbang Dai , Aaron M. Schankler , Lingyuan Gao , Liang Z. Tan , Andrew M. Rappe

Spontaneous polarization and bulk photovoltaic effect (BPVE) are two concomitant physical properties in ferroelectric materials. The flipping of ferroelectric order usually accompanies with the switching of BPVE as both of them are reversed…

Materials Science · Physics 2022-07-04 Rui-Chun Xiao , Yang Gao , Hua Jiang , Wei Gan , Changjin Zhang , Hui Li

Broadband, efficient and fast conversion of light to electricity is crucial for sensing and clean energy. Here we reveal the largest observed bulk photo-voltaic effect (BPVE), an intrinsic mechanism predicted to be ultrafast and exceed the…

Shift current and ballistic current have been proposed to explain the bulk photovoltaic effect (BPVE), and there have been experiments designed to separate the two mechanisms. These experiments are based on the assumption that under…

Materials Science · Physics 2023-05-24 Zhenbang Dai , Andrew M. Rappe

The bulk photovoltaic effect (BPVE) converts light into a coherent dc current at zero bias, through what is commonly known as the shift current. This current has previously been attributed to the displacement of the electronic wave function…

Mesoscale and Nanoscale Physics · Physics 2022-03-24 Daniel Kaplan , Tobias Holder , Binghai Yan

Bulk photovoltaic (BPV) effect, a second order nonlinear process that generates static current under light irradiation, requires centrosymmetric broken systems as its application platform. In order to realize measurable BPV photocurrent in…

Materials Science · Physics 2023-01-05 Xingchi Mu , Qianqian Xue , Yan Sun , Jian Zhou

The bulk photovoltaic (BPV) effect that converts light into electric current is highly sensitive to the system symmetry and its electronic Bloch wavefunction. To create a sizable net electric current, it is necessary to break the…

Materials Science · Physics 2024-07-08 Chunmei Zhang , Jian Zhou
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