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We report a giant magnetocaloric effect near room temperature in an off-stoichiometric Mn-Co-Ge alloy, across the magnetostructural transition. The isothermal entropy change accompanying this transition has a peak value of nearly 40 J/kg-K…

Materials Science · Physics 2016-12-21 V. K. Sharma , M. A. Manekar , Himanshu Srivastava , S. B. Roy

Off-stoichiometric alloys based on Ni 2 MnIn have drawn attention due to the coupled first order magnetic and structural transformations, and the large magnetocaloric entropy associated with the transformations. Here we describe…

Materials Science · Physics 2016-01-05 Jing-Han Chen , Nickolaus M. Bruno , Ibrahim Karaman , Yujin Huang , Jianguo Li , Joseph H. Ross

The efficient coupling between lattice degrees of freedom and spin degrees of freedom in magnetic materials can be used for refrigeration and energy conversion. This coupling is enhanced in materials exhibiting the giant magnetocaloric…

In the present work, two successive magneto-structural transformations (MSTs) consisting of martensitic and intermartensitic transitions have been reported in polycrystalline Ni55.8Mn18.1Ga26.1 Heusler alloy. Benefiting from the additional…

Materials Science · Physics 2015-09-25 Z. Li , K. Xu , Y. L. Zhang , C. Tao , D. Zheng , C. Jing

Ni-Mn-based Heusler alloys, in particular all-d-metal Ni(-Co)-Mn-Ti, are highly promising materials for energy-efficient solid-state refrigeration as large multicaloric effects can be achieved across their magnetostructural martensitic…

First-order magnetostructural phase transitions underpin giant magnetocaloric effects, yet the microscopic role of lattice dynamics in these transitions remains controversial. Here we use first-principles spin-lattice dynamics simulations…

Materials Science · Physics 2026-01-12 Lokanath Patra , Zeyu Xiang , Yubi Chen , Bolin Liao

Giant magnetocaloric effect is widely achieved in hexagonal MnMX-based (M = Co or Ni, X = Si or Ge) ferromagnets at their first-order magnetostructural transition. However, the thermal hysteresis and the low sensitivity of the…

Magnetocaloric materials can be useful in magnetic refrigeration applications, but to be practical the magneto-refrigerant needs to have a very large magnetocaloric effect (MCE) near room temperature for modest applied fields (<2 Tesla)…

The hydrostatic pressure is expected to be an effective knob to tune the magnetostructural phase transitions of hexagonal MMX alloy. In this study, magnetization measurements under hydrostatic pressure were performed on a MMX martensitic…

Materials Science · Physics 2021-06-08 Qingqi Zeng , Jianlei Shen , Enke Liu , Xuekui Xi , Wenhong Wang , Guangheng Wu , Xixiang Zhang

The first order magneto-structural transition ($T_t\simeq95$ K) and magnetocaloric effect in MnNiGe$_{0.9}$Ga$_{0.1}$ are studied via powder x-ray diffraction and magnetization measurements. Temperature dependent x-ray diffraction…

Materials Science · Physics 2018-01-17 Pallab Bag , R. Nath

We report a detailed study of the magnetocaloric effect in heterostructures of La2NiMnO6 and La2/3Sr1/3MnO3. The shape, width and magnitude of the temperature dependence of the magnetic entropy change ($\Delta S_{m}$) for these multilayer…

Applied Physics · Physics 2022-11-08 Mohammad Abbasi Eskandari , Seyedeh Sara Ghotb , Mohamed balli , Patrick Fournier

The search for energy-efficient and environmentally friendly cooling technologies is a key driver for the development of magnetic refrigeration based on the magnetocaloric effect (MCE). This phenomenon arises from the interplay between…

Novel Ni-Co-Mn-Ti all-d-metal Heusler alloys are exciting due to large multicaloric effects combined with enhanced mechanical properties. An optimized heat treatment for a series of these compounds leads to very sharp phase transitions in…

Ni-Mn-In magnetic shape-memory Heusler alloys exhibit generally a large thermal hysteresis at their first-order martensitic phase transition which hinder a technological application in magnetic refrigeration. By optimizing the Cu content in…

Materials Science · Physics 2020-04-16 P. Devi , C. Salazar Mejia , L. Caron , Sanjay Singh , M. Nicklas , C. Felser

A coupling of the first-order paramagnetic-to-induced-ferromagnetic martensitic and the second-order antiferromagnetic-to-ferromagnetic metamagnetic transitions was found in MnNi0.8Fe0.2Ge alloy. Based on the coupling, a magneto-volume…

Materials Science · Physics 2014-08-26 E. K. Liu , Z. Y. Wei , Y. Li , G. D. Liu , H. Z. Luo , W. H. Wang , H. W. Zhang , G. H. Wu

The entropy and cooling rate of the both antiferromagnetic spin-1/2 double sawtooth IsingHeisenberg model and mixed-spin (1,1/2) double sawtooth Ising-Heisenberg model on the distorted ladders are rigorously investigated under an adiabatic…

Statistical Mechanics · Physics 2018-05-29 Hamid Arian Zad , Vadim Ohanyan

The NiTi shape memory alloy exhibited excellent superelastic property and elastocaloric effect. Large temperature changes of 30 K upon loading and -19 K upon unloading were obtained at room temperature, which were higher than those of the…

Materials Science · Physics 2018-11-14 Min Zhou , Yushuang Li , Chen Zhang , Laifeng Li

We have studied the effect of magnetic field on a non-stoichiometric Heusler alloy Ni$_{50}$Mn$_{35}$In$_{15}$ that undergoes a martensitic as well as a magnetic transition near room temperature. Temperature dependent magnetization…

Materials Science · Physics 2009-11-13 P. A. Bhobe , K. R. Priolkar , A. K. Nigam

A remarkable decrease of the structural transition temperature of MnNiSi from 1200 K to <300 K by chemically alloying it with MnFeGe results in a coupling of the magnetic and structural transitions, leading to a large magnetocaloric effect…

High entropy alloys (HEAs) are promising magnetocaloric materials with tunable operating temperature conditions using compositional modifications. Here, we combine experiments and first principles based spin modelling to engineer…

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