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We present a comprehensive first--principles study of the structural stability and superconducting behavior of Li$_2$PdH$_2$ under high pressure. Using random structure searching and phonon calculations, we identify a pressure--induced…

Superconductivity · Physics 2025-08-08 Zahra Alizadeh , Yue-Wen Fang , Ion Errea , M. R. Mohammadizadeh

Marcasite-type compounds have been proposed as promising hosts of exotic magnetic quantum states, yet experimental realizations in stoichiometric, disorder-free systems remain limited. Here, we report the high-pressure stabilization and…

Alkali halides $MX$, have been viewed as typical ionic compounds, characterized by 1:1 ratio necessary for charge balance between M$^+$ and X$^-$. It was proposed that group I elements like Cs can be oxidized further under high pressure.…

Materials Science · Physics 2019-01-03 Qiang Zhu , Artem R. Oganov , Qingfeng Zeng

Processes involving severe plastic deformations (SPD) and phase transformations and chemical reactions (PTs/CRs) under high pressures are widespread for obtaining new nanostructured phases and their processing, mechanochemical synthesis,…

Materials Science · Physics 2025-08-21 Valery I. Levitas

Recently, new Cr-based superconductors, A$_2$Cr$_3$As$_3$ (A = K, Rb, Cs), have gained a strong interest because of their one-dimensional crystal structures and electron correlations. Here we report the crystal structure and physical…

Strongly Correlated Electrons · Physics 2015-08-07 Zhang-Tu Tang , Jin-Ke Bao , Liu Yi , Hua Bai , Hao Jiang , Hui-Fei Zhai , Chun-Mu Feng , Zhu-An Xu , Guang-Han Cao

Solid hydrogen sulfide is well known as a typical molecular crystal but its stability under pressure is still under debate. Particularly, Eremets et al. found the high pressure superconductivity with $T_{c}\approx$ 190 K in a H$_{2}$S…

Superconductivity · Physics 2015-05-20 Defang Duan , Xiaoli Huang , Fubo Tian , Da Li , Hongyu , Yu , Yunxian Liu , Yanbin Ma , Bingbing Liu , Tian Cui

We adopt a global optimization method to predict two-dimensional (2D) nanostructures through the particle-swarm optimization (PSO) algorithm. By performing PSO simulations, we predict new stable structures of 2D boron-carbon (B-C) compounds…

Materials Science · Physics 2011-12-30 Xinyu Luo , Jihui Yang , Hanyu Liu , Xiaojun Wu , Yanchao Wang , Yanming Ma , Su-Huai Wei , Xingao Gong , Hongjun Xiang

As a unique kagome superconductor displaying clear signatures of strong electronic correlations, CsCr$_3$Sb$_5$ has drawn much attention. Its rich temperature-pressure phase diagram features intertwined orders including pressure-induced…

Strongly Correlated Electrons · Physics 2026-04-16 Zikai Zhou , Wenyan Wang , Deng Hu , Zheyu Wang , Ying Kit Tsui , Tsz Fung Poon , Zhiwei Wang , Swee K. Goh

Boron carbide is a ceramic material with unique properties widely used in numerous, including armor, applications. Its mechanical properties, mechanism of compression, and limits of stability are of both scientific and practical value.…

First-principles calculations were carried out to provide a chemical basis for proposed structures associated with the recently reported room-temperature superconductivity in a carbonaceous sulfur hydride material under pressure.…

Superconductivity · Physics 2022-04-28 Xiaoyu Wang , Tiange Bi , Katerina P. Hilleke , Anmol Lamichhane , Russell J. Hemley , Eva Zurek

Using $\textit{ab-initio}$ crystal structure prediction we study the high-pressure phase diagram of $\textit{A}BiO_3$ bismuthates ($A$=Ba, Sr, Ca) in a pressure range up to 100$~$GPa. All compounds show a transition from the low-pressure…

Strongly Correlated Electrons · Physics 2018-10-03 Andriy Smolyanyuk , Cesare Franchini , Lilia Boeri

A multitude of observed boron-based materials have outstanding superconducting, mechanical, and refractory properties. Yet, the structure, the composition, and the very existence of some reported metal boride (M-B) compounds have been a…

Materials Science · Physics 2014-10-03 A. G. Van Der Geest , A. N. Kolmogorov

Understanding the competition between superconductivity and other ordered states (such as antiferromagnetic or charge-density-wave (CDW) state) is a central issue in condensed matter physics. The recently discovered layered kagome metal…

Superconductivity · Physics 2021-06-16 F. H. Yu , D. H. Ma , W. Z. Zhuo , S. Q. Liu , X. K. Wen , B. Lei , J. J. Ying , X. H. Chen

The make-up of the outer planets, and many of their moons, are dominated by matter from the H-C-N-O chemical space, commonly assumed to originate from mixtures of hydrogen and the planetary ices H$_2$O, CH$_4$, and NH$_3$. In their…

Materials Science · Physics 2020-11-30 Lewis J. Conway , Chris J. Pickard , Andreas Hermann

Sub-oxides with the anti-perovskite structure constitute a large part of the interstitial stabilized compounds with novel chemical and physical properties, especially in the systems containing rare earth elements and/or early transition…

Materials Science · Physics 2022-01-24 Hanshang Jin , Jackson Badger , Peter Klavins , Jing-Tai Zhao , Valentin Taufour

Hydrides are considered to be one of the most promising families of compounds for achieving high temperature superconductivity. However, there are very few experimental reports of ambient-pressure hydride superconductivity, and the…

Superconductivity · Physics 2026-03-18 Antonio Sanna , Tiago F. T. Cerqueira , Ekin Dogus Cubuk , Ion Errea , Yue-Wen Fang

The discovery of a superconducting phase in sulfur hydride under high pressure with a critical temperature above 200 K has provided a new impetus to the search for even higher $T_c$. Theory predicted and experiment confirmed that the phase…

Recently a new family of Cr-based A2Cr3As3 (A = K, Rb, Cs) superconductors were reported, which own a rare quasi-one-dimensional (Q1D) crystal structure with infinite (Cr3As3)2- chains and exhibit intriguing superconducting characteristics…

Superconductivity · Physics 2017-10-18 Qing-Ge Mu , Bin-Bin Ruan , Bo-Jin Pan , Tong Liu , Jia Yu , Kang Zhao , Gen-Fu Chen , Zhi-An Ren

Hydrogen-rich superhydrides are believed to be very promising high-Tc superconductors as they are expected to mimic characteristics of metallic hydrogen. Recent experiments discovered superhydrides at very high pressures, e.g. FeH5 at 130…

The superconducting state of the newly discovered superconductor K$_2$Cr$_3$As$_3$ with a quasi-one-dimensional crystal structure ($T_{\bf c}\sim$ 6 K) has been investigated by using magnetization and muon-spin relaxation or rotation…