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Materials that exhibit high nonlinear optical (NLO) susceptibilities are considered as promising candidates for a wide range of photonic and electronic applications. Here we argue that the ferroelectric nematic (NF) materials have…

Soft Condensed Matter · Physics 2022-03-22 C. L. Folcia , J. Ortega , R. Vidal , T. Sierra , J. Etxebarria

The organic mesogens RM734 and DIO are members of separate molecular families featuring distinct molecular structures. These families, at the present time, are the only ones known to exhibit a ferroelectric nematic liquid crystal (LC)…

Ferroelectric nematic fluids are promising materials for tunable nonlinear photonics, with applications ranging from second harmonic generation to sources of entangled photons. However, the few reported values of second-order…

True phase-matched second-harmonic generation in a waveguide of crosslinkable ferroelectric liquid crystals is demonstrated. These materials allow the formation of macroscopically polar structures whose order can be frozen by…

Soft Condensed Matter · Physics 2009-10-31 Valentina S. U. Fazio , S. T. Lagerwall , P. Busson , A. Hult , H. Motschmann

Ferroelectric nematic liquid crystals exhibit unique non-linear optical properties, with the potential to become transformative materials for photonic applications. A promising direction relies on the fabrication of tailored polar…

Herein we report the first examples of reactive mesogenic materials (RMs) which exhibit fluid ferroelectric order based on the recently discovered ferroelectric nematic (NF) phase. We term these materials NF RMs and they provide the first…

Materials Science · Physics 2025-04-25 Stuart R Berrow , Jordan Hobbs , Calum J Gibb

Thermotropic liquid crystals are versatile optical materials that exhibit a state of matter intermediate between liquids and solids. Their properties can change significantly with temperature, pressure, or other external factors, leading to…

Ferroelectric nematic phase (NF) represents an attractive and foremost field of liquid crystals, combining fluidity with ferroelectricity. NF materials exhibit large polarization values and remarkable non-linear optical properties. We have…

Soft Condensed Matter · Physics 2026-03-06 Martin Cigl , Natalia Podoliak , Dalibor Repček , Pavlo Golub , Marta Lavrič , Vladimíra Novotná

Dielectric metasurfaces have shown prominent applications in nonlinear optics due to strong field enhancement and low dissipation losses at the nanoscale. Chalcogenide glasses are one of the promising materials for the observation of…

A comparative experimental investigation of the dependence of second harmonic generation (SHG) on applied external voltage between the standard nematic liquid crystalline material and an analogue ferromagnetic nematic liquid crystalline…

Soft Condensed Matter · Physics 2019-09-30 Jure Brence , Luka Cmok , Nerea Sebastian , Alenka Mertelj , Darja Lisjak , Irena Drevensek-Olenik

Ferroelectric nematic (NF) liquid crystals combine liquid-like fluidity and orientational order of conventional nematics with macroscopic electric polarization comparable in magnitude to solid state ferroelectric materials. Here, we present…

Soft Condensed Matter · Physics 2025-02-04 Calum J. Gibb , Jordan Hobbs , Richard J. Mandle

The ferroelectric nematic phase (NF) is a recently discovered phase of matter in which the orientational order of the conventional nematic liquid crystal state is augmented with polar order. Atomistic simulations suggest that the polar NF…

Soft Condensed Matter · Physics 2023-09-26 Charles Parton-Barr , Helen Gleeson , Richard Mandle

Lyotropic chromonic liquid crystals are formed by the self-assembly of aromatic compounds in concentrated solutions. Despite numerous applications of chromonic systems in optical and photonic devices, they all make use of the anisotropic…

Soft Condensed Matter · Physics 2025-12-17 Dennys Reis , Renato Mafra Moysés , Lino Misoguti , Antônio Martins Figueiredo Neto

We report the fabrication of artificial unidimensional crystals exhibiting an effective bulk second-order nonlinearity. The crystals are created by cycling atomic layer deposition of three dielectric materials such that the resulting…

Ferroelectric nematic liquid crystals represent not only interesting fundamental science, but they also hold promise for storage capacitors with high power density or new information display technology having sub-millisecond switching. In…

Electronic electro-optic (EEO) phase modulation is a key emerging technology for the chip-scale inter-conversion of signals between the electronic and photonic domains. The recent discovery of the ferroelectric nematic ($N_F$) liquid…

The recent discovery of the ferroelectric splay nematic phase has opened the door to experimental investigation of one of the most searched liquid crystal phases in decades, with high expectations for future applications. However, at this…

Soft Condensed Matter · Physics 2021-08-03 Nerea Sebastián , Richard. J. Mandle , Andrej Petelin , Alexey Eremin , Alenka Mertelj

The recent discovery of ferroelectric nematic liquid crystalline phases marks a major breakthrough in soft matter research. An intermediate phase, often observed between the nonpolar and the ferroelectric nematic phase, shows a distinct…

Second harmonic generation is a powerful tool directly connected to the symmetry of materials. Phase transitions, lattice rotations or electromagnetic coupling in multiferroic compounds can be revealed by using second harmonic…

Optics · Physics 2010-01-11 Pablo Molina , Mariola O Ramirez , Basilio J. Garcia , Luisa E. Bausa

Fluid molecular ferroelectrics are a new class of organic materials where ferroelectricity is found in conjunction with 3D fluidity whilst still retaining spontaneous polarization values comparable to their traditional solid state…

Soft Condensed Matter · Physics 2026-02-19 Calum J Gibb , Jordan Hobbs , William C Ogle , Richard J Mandle
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