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Related papers: Inducing And Probing Charge Migration In Molecular…

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We review theoretical foundations and some recent progress related to the quest of controlling the motion of charge carriers with intense laser pulses and optical waveforms. The tools and techniques of attosecond science enable detailed…

Mesoscale and Nanoscale Physics · Physics 2017-03-10 Vladislav S. Yakovlev , Stanislav Yu. Kruchinin , Tim Paasch-Colberg , Mark I. Stockman , Ferenc Krausz

We theoretically investigate field-induced charge-transport processes from the viewpoint of time-reversal symmetry. We analytically demonstrate that breaking of the time-reversal symmetry is a necessary condition to induce charge-transport…

Mesoscale and Nanoscale Physics · Physics 2019-10-14 Shunsuke A. Sato

Using a master-equation approach for the description of coherent and incoherent dynamics in `artificial atoms and molecules', we present a theoretical analysis of situations where intense laser fields lead to pronounced renormalizations of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Ulrich Hohenester , Filippo Troiani , Elisa Molinari

Sub-angstrom spatial resolution of electron density coupled with sub-femtosecond temporal resolution is required to directly observe the dynamics of the electronic structure of a molecule after photoinitiation or some other ultrafast…

New features of molecular wires can be observed when they are irradiated by laser fields. These effects can be achieved by periodically oscillating fields but also by short laser pulses. The theoretical foundation used for these…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Sven Welack , Michael Schreiber , Ulrich Kleinekathoefer

A mixed quantum-classical approach to simulate the coupled dynamics of electrons and nuclei in nanoscale molecular systems is presented. The method relies on a second order expansion of the Lagrangian in time-dependent density functional…

Chemical Physics · Physics 2009-11-10 T. A. Niehaus , D. Heringer , B. Torralva , Th. Frauenheim

In recent years, photon drag has attracted enormous attention owing to both fundamental and practical interests. In this paper, by presenting a density-matrix approach, we have theoretically demonstrated an enhanced photon drag in a moving…

Optics · Physics 2018-10-02 Seyedeh Hamideh Kazemi , Mohammad Mahmoudi

Molecular absorption and photo-electron spectra can be efficiently predicted with real-time time-dependent density-functional theory (TDDFT). We show here how these techniques can be easily extended to study time-resolved pump-probe…

Atomic and Molecular Clusters · Physics 2013-01-10 Umberto De Giovannini , Gustavo Brunetto , Alberto Castro , Jessica Walkenhorst , Angel Rubio

Ultrafast, time-resolved spectroscopies enable the direct observation of non-equilibrium processes in condensed-phase systems and have revealed key insights into energy transport, hydrogen-bond dynamics, and vibrational coupling. While ab…

Chemical Physics · Physics 2025-09-01 Kit Joll , Philipp Schienbein

Attosecond laser pulses open the door to resolve microscopic electron dynamics in time. Experiments performed include the decay of a core hole, the time-resolved measurement of photo ionization and electron tunneling. The processes…

Atomic and Molecular Clusters · Physics 2011-11-09 Ionut Georgescu , Ulf Saalmann , Jan M. Rost

At molecular scales, fluctuations play a significant role and prevent biomolecular processes from always proceeding in a preferred direction, raising the question of how limited amounts of free energy can be dissipated to obtain directed…

Statistical Mechanics · Physics 2016-10-05 Aidan I. Brown , David A. Sivak

Hybrid systems, which take advantage of low material dimensionality, have great potential for designing nanoscale devices. Quantum dots (QDs) -- a 0D nanostructure -- can be combined with 2D monolayers to achieve success in photovoltaics…

Computational Physics · Physics 2022-11-23 Matthew Ciesler , Han Wang , Shengbai Zhang , Damien West

Tracing ultrafast processes induced by interaction of light with matter is often very challenging. In molecular systems, the initially created electronic coherence becomes damped by the slow nuclear rearrangement on a femtosecond timescale…

Chemical Physics · Physics 2021-09-20 Nikolay V. Golubev , Jiří Vaníček , Alexander I. Kuleff

Strong field photoemission and electron recollision provide a viable route to extract electronic and nuclear dynamics from molecular targets with attosecond temporal resolution. However, since an {\em ab-initio} treatment of even the…

Atomic Physics · Physics 2016-11-02 N. Suárez , A. Chacón , M. F. Ciappina , B. Wolter , J. Biegert , M. Lewenstein

We have developed a theory of three-pulse coherent control of photochemical processes. It is based on adiabatic passage and quantum coherence and interference attributed to the lower-lying dissociation continuum and excited upper discrete…

Quantum Physics · Physics 2009-11-10 A. K. Popov , V. V. Kimberg , Thomas F. George

Laser-induced electron diffraction is an evolving tabletop method, which aims to image ultrafast structural changes in gas-phase polyatomic molecules with sub-{\AA}ngstr\"om spatial and femtosecond temporal resolution. Here, we provide the…

Time-resolved ultrafast x-ray scattering is an emerging approach to probe the temporally evolving electronic charge distribution in real-space and in real-time. In this contribution, time-resolved ultrafast x-ray scattering from an…

Atomic Physics · Physics 2015-06-18 Gopal Dixit , Robin Santra

The route towards manipulation of the optoelectronic properties of matter beyond the current limits of electronics starts from a comprehensive study of the ultrafast dynamics triggered by interaction with light. Among them, a fundamental…

A new perspective on how to manipulate molecules by means of very strong laser pulses is emerging with insights from the so-called light-induced potentials, which are the adiabatic potential energy surfaces of molecules severely distorted…

Chemical Physics · Physics 2016-03-03 Bo Y. Chang , Ignacio R. Sola , Seokmin Shin

Time-resolved femtosecond x-ray diffraction patterns from laser-excited molecular iodine are used to create a movie of intramolecular motion with time and space resolution of $30~$fs and $0.3$ \AA . The high spatial fidelity is due to…