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We prove classical simulation hardness, under the generalized $\mathsf{P}\neq\mathsf{NP}$ conjecture, for quantum circuit families with applications in near-term chemical ground state estimation. The proof exploits a connection to particle…

Quantum Physics · Physics 2026-02-06 Oskar Leimkuhler , K. Birgitta Whaley

We provide three improvements to the product formula implementation of the ground state energy estimation algorithm via Trotter-Suzuki decomposition. These consist of smaller circuit templates for each Hamiltonian term, parallelization of…

Quantum Physics · Physics 2025-06-26 Andre Kornell , Peter Selinger

Determining ground state energies of quantum systems by hybrid classical/quantum methods has emerged as a promising candidate application for near-term quantum computational resources. Short of large-scale fault-tolerant quantum computers,…

Quantum Physics · Physics 2016-10-25 Nicholas C. Rubin

Recent work has dramatically reduced the gate complexity required to quantum simulate chemistry by using linear combinations of unitaries based methods to exploit structure in the plane wave basis Coulomb operator. Here, we show that one…

Quantum Physics · Physics 2019-12-04 Dominic W. Berry , Craig Gidney , Mario Motta , Jarrod R. McClean , Ryan Babbush

We introduce novel algorithms for the quantum simulation of molecular systems which are asymptotically more efficient than those based on the Trotter-Suzuki decomposition. We present the first application of a recently developed technique…

Quantum signal processing (QSP) is a powerful quantum algorithm to exactly implement matrix polynomials on quantum computers. Asymptotic analysis of quantum algorithms based on QSP has shown that asymptotically optimal results can in…

Quantum Physics · Physics 2021-07-13 Yulong Dong , Xiang Meng , K. Birgitta Whaley , Lin Lin

With a view toward addressing the explosive growth in the computational demands of nuclear structure and reactions modeling, we develop a novel quantum algorithm for neutron-nucleus simulations with general potentials, which provides…

Quantum Physics · Physics 2026-03-17 Soorya Rethinasamy , Ethan Guo , Alexander Wei , Mark M. Wilde , Kristina D. Launey

As a cornerstone of automated reasoning, equational reasoning finds equivalences between symbolic expressions and fuels advances across scientific disciplines. Yet, its potential remains limited by the exponential growth of equivalent…

Quantum Physics · Physics 2026-05-19 Davide Rattacaso , Daniel Jaschke , Marco Ballarin , Ilaria Siloi , Simone Montangero

Fast-forwarding refers to the ability to simulate a system of time $t$ using significantly fewer than $t$ queries or circuit depth. While various Hamiltonian systems are known to circumvent the no fast-forwarding theorem, analogous results…

Quantum Physics · Physics 2026-05-25 Zhong-Xia Shang , Dong An , Changpeng Shao

We give a detailed account of an $\it{ab}$ $\it{initio}$ spectral approach for the calculation of energy spectra of two active electron atoms in a system of hyperspherical coordinates. In this system of coordinates, the Hamiltonian has the…

In this paper, we develop a framework to construct energy-preserving methods for multi-components Hamiltonian systems, combining the exponential integrator and the partitioned averaged vector field method. This leads to numerical schemes…

Numerical Analysis · Mathematics 2021-11-08 X. Gu , C. Jiang , Y. Wang , W. Cai

Block-encodings have become one of the most common oracle assumptions in the circuit model. I present an algorithm that uses von Neumann's measurement procedure to measure a phase, using time evolution on a block-encoded Hamiltonian as a…

Quantum Physics · Physics 2025-09-05 S. E. Skelton

Quantum computers promise to revolutionise electronic simulations by overcoming the exponential scaling of many-electron problems. While electronic wave functions can be represented using a product of fermionic unitary operators, shallow…

Quantum Physics · Physics 2022-07-04 Hugh G. A. Burton , Daniel Marti-Dafcik , David P. Tew , David J. Wales

Hamiltonian simulation, i.e., simulating the real time evolution of a target quantum system, is a natural application of quantum computing. Trotter-Suzuki splitting methods can generate corresponding quantum circuits; however, a faithful…

Quantum Physics · Physics 2024-03-21 Ayse Kotil , Rahul Banerjee , Qunsheng Huang , Christian B. Mendl

As physical implementations of quantum architectures emerge, it is increasingly important to consider the cost of algorithms for practical connectivities between qubits. We show that by using an arrangement of gates that we term the…

We describe an algorithm that computes the ground state energy and correlation functions for 2-local Hamiltonians in which interactions between qubits are weak compared to single-qubit terms. The running time of the algorithm is polynomial…

Quantum Physics · Physics 2009-11-13 Sergey Bravyi , David DiVincenzo , Daniel Loss

The quantum computation of electronic energies can break the curse of dimensionality that plagues many-particle quantum mechanics. It is for this reason that a universal quantum computer has the potential to fundamentally change…

Hamiltonian simulation is one of the most promising candidates for the demonstration of quantum advantage within the next ten years, and several studies have proposed end-to-end resource estimates for executing such algorithms on…

Quantum Physics · Physics 2025-06-11 Tyler LeBlond , Ryan S. Bennink

Hamiltonian quantum simulation of bosons on digital quantum computers requires truncating the Hilbert space to finite dimensions. The method of truncation and the choice of basis states can significantly impact the complexity of the quantum…

Quantum Physics · Physics 2025-10-10 Masanori Hanada , Shunji Matsuura , Emanuele Mendicelli , Enrico Rinaldi

Quantum algorithms for estimating the ground state energy of a quantum system often operate by preparing a classically accessible quantum state and then applying quantum phase estimation. Whether this approach yields quantum advantage…

Quantum Physics · Physics 2026-02-25 Daochen Wang
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