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The phenomenon of high temperature superconductivity, approaching room temperature, has been realized in a number of hydrogen-dominant alloy systems under high pressure conditions1-12. A significant discovery in reaching room temperature…

A diamond anvil cell (DAC) which can generate extremely high pressure of multi-megabar is promising tool to develop a further physics such a high-transition temperature superconductivity. However, electrical transport measurements, which is…

Sulfur has recently been found to be a superconductor at high pressure. At ~93 GPa Tc is 10.1 K, and the sulfur is in a base-centered orthorhombic (b.c.o) structure. At ~160 GPa Tc is 17 K and sulfur is in a rhobohedral (b-Po) structure.…

Superconductivity · Physics 2016-08-31 Eric Lewin Altschuler , Martin Lades

Experimental discovery that compressed sulphur hydride exhibits superconducting transition temperature Tc=203 K (Drozdov et al 2015 Nature 525 73) sparked intensive studies of superconducting hydrides. However, this discovery was not a…

Superconductivity · Physics 2022-11-14 E. F. Talantsev

Recent discovery of high-temperature superconductivity (Tc = 190 K) in sulfur hydrides at megabar pressures breaks the traditional belief on the Tc limit of 40 K for conventional superconductors, and open up the doors in searching new…

This article reports the experimentally clarified crystal structure of a recently discovered sulfur hydride in high temperature superconducting phase which has the highest critical temperature Tc over 200 K which has been ever reported. For…

We use Density Functional Theory (DFT) and structure searching methods to show that the ground state of elemental sulfur is a Barium-IVa type incommensurate host-guest (HG) phase between $386$-$679$ GPa, becoming the first group-VI element…

Materials Science · Physics 2021-07-12 Jack Whaley-Baldwin , Michael Hutcheon , Chris J. Pickard

Superconductivity in highly-pressurized hydrides became primary direction for the exploration of fundamental upper limit for the superconducting transition temperature, Tc, after Drozdov et al (Nature 2015, 525, 73) discovered…

Superconductivity · Physics 2023-08-28 E. F. Talantsev

While great scientific efforts focus on the synthesis and studies of near-room-temperature (NRT) superconductors exhibited record superconducting transition temperatures (for instance, laser annealed H3S, LaH10 and YHn (n = 4,6,7,9) with Tc…

Superconductivity · Physics 2020-04-21 E. F. Talantsev

We calculate superconducting transition temperatures ($T_{\rm c}$) in sulfur hydrides H$_{2}$S and H$_{3}$S from first principles using the density functional theory for superconductors. At pressures of $\lesssim$150 GPa, the high values of…

Superconductivity · Physics 2015-07-08 Ryosuke Akashi , Mitsuaki Kawamura , Shinji Tsuneyuki , Yusuke Nomura , Ryotaro Arita

Hydrogen sulfide (H2S) is a prototype molecular system and a sister molecule of water. The phase diagram of solid H2S at high pressures remains largely unexplored arising from the challenges in dealing with the looser S-H bond and larger…

Superconductivity · Physics 2015-03-26 Yinwei Li , Jian Hao , Yanling Li , Yanming Ma

Due to its low atomic mass hydrogen is the most promising element to search for high-temperature phononic superconductors. However, metallic phases of hydrogen are only expected at extreme pressures (400 GPa or higher). The measurement of a…

Superconductivity · Physics 2016-03-23 José A. Flores-Livas , Antonio Sanna , E. K. U. Gross

We report experimental discovery of tantalum polyhydride superconductor. It was synthesized at high pressure and high temperature conditions using diamond anvil cell combined with in-situ high pressure laser heating techniques. The…

The exploration of superconductors in metastable phases by manipulating crystal structures through high-pressure techniques has attracted significant interest in materials science to achieve a high critical temperature ($T_c$). In this…

Layered metal-rich subsulfides have become a promising area for exploring intriguing properties such as superconductivity, nontrivial topology, and charge density waves; however, despite their extraordinary potential, they have remained…

Superconductivity · Physics 2023-08-02 A. Kataria , R. P. Singh

The maximum critical temperature for superconductivity in pressurized hydrides appears at the top of superconducting domes in Tc versus pressure curves at a particular pressure, which is not predicted by standard superconductivity theories.…

Satterthwaite and Toepke (1970 Phys. Rev. Lett. 25 741) predicted high-temperature superconductivity in hydrogen-rich metallic alloys, based on an idea that these compounds should exhibit high Debye frequency of the proton lattice, which…

Superconductivity · Physics 2021-09-21 E. F. Talantsev

Observation of high-temperature superconductivity in sulfur hydrides at megabar pressures has generated an irresistible wave on searching for new superconductors in other compressed hydrogen-rich compounds. An immediate effort is towards…

Superconductivity · Physics 2016-02-10 Xin Zhong , Hui Wang , Jurong Zhang , Hanyu Liu , Shoutao Zhang , Hai-Feng Song , Guochun Yang , Lijun Zhang , Yanming Ma

The recent report of superconductivity under high pressure at the record transition temperature of Tc=203K in sulfur hydride has been identified as conventional in view of the observation of an isotope effect upon deuteration. Here it is…

Superconductivity · Physics 2016-05-24 Annette Bussmann-Holder , Jurgen Kohler , M. -H. Whangbo , Antonio Bianconi , Arndt Simon

AgSbTe2 is a well-known thermoelectric material with a high Seebeck coefficient and intrinsically low thermal conductivity, but its behavior under pressure remains largely unexplored. Here we report a systematic investigation of the…

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