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The optical spectra of CeO2 have been systematically investigated using three first-principles computational approaches for comparison, namely, the Heyd-Scuseria-Ernzerhof (HSE) screened hybrid functional, HSE+\emph{U}, and…

Strongly Correlated Electrons · Physics 2010-01-19 Hongliang Shi , Ping Zhang , Shu-Shen Li

Double hybrid density functional theory arguably sits on the seamline between wavefunction methods and DFT: it represents a special case of Rung 5 on the "Jacobs Ladder" of John P. Perdew. For large and chemically diverse benchmarks such as…

Chemical Physics · Physics 2020-10-16 Jan M. L. Martin , Golokesh Santra

The accuracy of one-shot $G_0W_0$ and Bethe-Salpeter equation (BSE) calculations depends strongly on the underlying starting-point eigensystem, which is commonly obtained from a mean-field density-functional approximation. Range-separated…

Chemical Physics · Physics 2026-05-22 Aditi Singh , Subrata Jana , Szymon Śmiga

This work presents a new class of hybrid density functional theory (DFT) approximations, incorporating nonlocal exact exchange in predefined states such as core atomic orbitals (AOs). These projected hybrid density functionals are a…

Chemical Physics · Physics 2023-05-16 Benjamin G. Janesko

Transition metal (TM) oxides play an increasingly important role in technology today including applications such as catalysis, solar energy harvesting, and energy storage. In many of these applications, the details of their electronic…

Materials Science · Physics 2015-09-30 Dong-Hwa Seo , Alexander Urban , Gerbrand Ceder

Intelligent reflective surfaces (IRSs) are invoked for improving both spectral efficiency (SE) and energy efficiency (EE). Specifically, an IRS-aided multiple-input multiple-output network is considered, where the performance of randomly…

Information Theory · Computer Science 2021-02-25 Tianwei Hou , Yuanwei Liu , Zhengyu Song , Xin Sun , Yue Chen , Lajos Hanzo

Density functional theory (DFT) offers an exceptional balance between accuracy and efficiency, but practical density functional approximations face an unavoidable trade-off among simplicity, accuracy, and transferability. A systematic…

Chemical Physics · Physics 2026-03-25 Jiashu Liang , Martin Head-Gordon

Orbital-free density functional theory (OF-DFT) constitutes a computationally highly effective tool for modeling electronic structures of systems ranging from room-temperature materials to warm dense matter. Its accuracy critically depends…

We use shear-mode Raman imaging to track ferroelectric switching in multilayer 3$R$-MoS$_2$. Within a single flake, mechanically segmented regions respond independently and follow distinct pathways. Partially polarized end states indicate…

Materials Science · Physics 2026-05-21 Yulu Liu , Kenji Watanabe , Takashi Taniguchi , Xiaoxiang Xi

Hybrid reconfigurable intelligent surfaces (HRIS) enhance wireless systems by combining passive reflection with active signal amplification. However, jointly optimizing the transmit beamforming with the HRIS reflection and amplification…

Signal Processing · Electrical Eng. & Systems 2026-04-13 Phuong Nam Tran , Nhan Thanh Nguyen , Markku Juntti

We introduce a novel ridge detection algorithm for time-frequency (TF) analysis, particularly tailored for intricate nonstationary time series encompassing multiple non-sinusoidal oscillatory components. The algorithm is rooted in the…

Numerical Analysis · Mathematics 2024-08-20 Yan-Wei Su , Gi-Ren Liu , Yuan-Chung Sheu , Hau-Tieng Wu

Exchange hole is the principle constituent in density functional theory, which can be used to accurately design exchange energy functional and range separated hybrid functionals coupled with some appropriate correlation. Recently, density…

Materials Science · Physics 2017-09-14 Bikash Patra , Subrata Jana , Prasanjit Samal

Recent advances in X-ray free-electron laser diagnostics have enabled direct probing of the electronic structure under extreme pressures and temperatures, such as those encountered in stellar interiors and inertial confinement fusion…

Using an end-to-end differentiable implementation of the Kohn-Sham self-consistent field equations, we obtain an accurate neural network-based exchange and correlation (XC) functional of the electronic density. The functional is optimized…

Chemical Physics · Physics 2021-06-09 Sebastian Dick , Marivi Fernandez-Serra

This paper introduces Spectral Incoherent Diffractive Imaging (SIDI) as a novel method for achieving dark-field imaging of nanostructures with heterogeneous oxidation states. With SIDI, shifts in photoemission profiles can be spatially…

Optics · Physics 2023-12-25 Tamme Wollweber , Kartik Ayyer

We demonstrate the accuracy of the hybrid functional HSE06 for computing band offsets of semiconductor alloy heterostructures. The highlight of this study is the computation of conduction band offsets with a reliability that has eluded…

Materials Science · Physics 2015-05-19 Amita Wadehra , Jeremy W. Nicklas , John W. Wilkins

We construct range-separated double-hybrid schemes which combine coupled-cluster or random-phase approximations with a density functional based on a two-parameter Coulomb-attenuating-method-like decomposition of the electron-electron…

Chemical Physics · Physics 2020-01-29 Cairedine Kalai , Bastien Mussard , Julien Toulouse

We investigate the electronic properties of the LaAlO3/SrTiO3 interface using density functional theory. In contrast to previous studies, which relied on (semi-)local functionals and the GGA+U method, we here use a recently developed hybrid…

Strongly Correlated Electrons · Physics 2013-07-18 F. Cossu , U. Schwingenschlögl , V. Eyert

Kohn-Sham (KS) density functional theory (DFT) is a very efficient method for calculating various properties of solids as, for instance, the total energy, the electron density, or the electronic band structure. The KS-DFT method leads to…

Materials Science · Physics 2019-09-20 Fabien Tran , Jan Doumont , Leila Kalantari , Ahmad W. Huran , Miguel A. L. Marques , Peter Blaha

The low energy band structure near the band gap determines the electrical performance of thermoelectric materials. Here, by using the hybrid-density functional theory (hybrid-DFT) calculations, we calculate the low energy band structure of…

Materials Science · Physics 2017-04-19 Sudong Park , Byungki Ryu