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Multiscale plasmonic systems e.g. extended metallic nanostructures with sub-nanometer inter-distances) play a key role in the development of next-generation nano-photonic devices. An accurate modeling of the optical interactions in these…

Mesoscale and Nanoscale Physics · Physics 2016-05-11 Cristian Ciracì , Fabio Della Sala

Quantum thermometry provides a key capability for nanoscale devices and quantum technologies, but most existing strategies rely on probes initialized near equilibrium. This equilibrium paradigm imposes intrinsic limitations: sensitivity is…

Quantum Physics · Physics 2026-01-09 Pritam Chattopadhyay , Jonas F. G. Santos , Avijit Misra

Machine learned chemical potentials have shown great promise as alternatives to conventional computational chemistry methods to represent the potential energy of a given atomic or molecular system as a function of its geometry. However,…

Chemical Physics · Physics 2023-11-15 Christian Devereux , Yoona Yang , Carles Martí , Judit Zádor , Michael S. Eldred , Habib N. Najm

The dynamics of water in electrolyte solutions exhibits a striking, ion-specific anomaly: the diffusion coefficient of water is enhanced relative to the neat liquid in chaotropic CsI solutions, yet suppressed in kosmotropic NaCl solutions.…

Chemical Physics · Physics 2026-04-17 Massimo Ciacchi , Ilnur Saitov , Nico Di Fonte , Isabella Daidone , Carlo Pierleoni

Obtaining the atomistic structure and dynamics of disordered condensed phase systems from first principles remains one of the forefront challenges of chemical theory. Here we exploit recent advances in periodic electronic structure to show…

We report a new Quantum Mechanical/Molecular Dynamics (QM/MD) simulation loop to model the coupling between the electron and atom dynamics in solid/liquid interfacial systems. The method can describe simultaneously both the quantum…

Materials Science · Physics 2021-02-03 Joshua D Elliott , Alessandro Troisi , Paola Carbone

Quantum phase estimation (QPE) serves as a building block of many different quantum algorithms and finds important applications in computational chemistry problems. Despite the rapid development of quantum hardware, experimental…

Quantum Physics · Physics 2024-03-01 Kentaro Yamamoto , Samuel Duffield , Yuta Kikuchi , David Muñoz Ramo

Computational fluid dynamics lies at the heart of many issues in science and engineering, but solving the associated partial differential equations remains computationally demanding. With the rise of quantum computing, new approaches have…

A comprehensive microscopic understanding of ambient liquid water is a major challenge for $ab$ $initio$ simulations as it simultaneously requires an accurate quantum mechanical description of the underlying potential energy surface (PES)…

Chemical Physics · Physics 2019-10-28 Hsin-Yu Ko , Linfeng Zhang , Biswajit Santra , Han Wang , Weinan E , Robert A. DiStasio , Roberto Car

The ground state of second-quantized quantum chemistry Hamiltonians is key to determining molecular properties. Neural quantum states (NQS) offer flexible and expressive wavefunction ansatze for this task but face two main challenges:…

Chemical Physics · Physics 2025-06-18 An-Jun Liu , Bryan K. Clark

Accurate prediction of excited states in battery electrolytes is central to understanding photostability, oxidative stability, and degradation. We employ hybrid quantum-classical algorithms -- the Variational Quantum Eigensolver (VQE) for…

Materials Science · Physics 2025-09-18 Sk Mujaffar Hossain , Seung-Cheol Lee , Satadeep Bhattacharjee

We study finite-layer alternations of the \emph{Constraint--Enhanced Quantum Approximate Optimization Algorithm} (CE--QAOA), a constraint-aware ansatz that operates natively on block one-hot manifolds. Our focus is on feasibility and…

Quantum Physics · Physics 2026-04-21 Chinonso Onah , Kristel Michielsen

We study non-normalizable quasi-equilibrium states (NNQE) arising from anomalous diffusion. Initially, particles in contact with a thermal bath are released from an asymptotically flat potential well, with dynamics that is described by…

Statistical Mechanics · Physics 2023-08-24 Lucianno Defaveri , Maike A. F. dos Santos , David A. Kessler , Eli Barkai , Celia Anteneodo

In this work, we study degradation of clofibric acid (CFA) in aqueous solution using either ionizing radiation from a $^{60}$Co source or a non-thermal plasma produced by discharges in the air above the solution. The results obtained with…

We conducted a thorough evaluation of various state-of-the-art strategies to prepare the ground state wavefunction of a system on a quantum computer, specifically within the framework of variational quantum eigensolver (VQE). Despite the…

Quantum Physics · Physics 2024-03-05 M. R. Nirmal , Sharma S. R. K. C. Yamijala , Kalpak Ghosh , Sumit Kumar , Manoj Nambiar

The development of high-performance electron sources requires theoretical frameworks that accurately link the microscopic electronic properties of cathode materials to their macroscopic photoemission observables. Here, we present a…

Materials Science · Physics 2026-02-16 Richard Schier , Chen Wang , Jonas Dube , Julius Kühn , Alice Galdi , Thorsten Kamps , Caterina Cocchi

We introduce and employ two QM:QM schemes (a quantum mechanical method embedded into another quantum mechanical method) and report their performance for the X23 set of molecular crystals. We furthermore present the theory to calculate the…

Chemical Physics · Physics 2018-10-17 Oleksandr A. Loboda , Grygoriy A. Dolgonos , A. Daniel Boese

The decoherence of a two-state system coupled with a sub-Ohmic bath is investigated theoretically by means of the perturbation approach based on a unitary transformation. It is shown that the decoherence depends strongly and sensitively on…

Quantum Physics · Physics 2017-07-10 Zhiguo Lü , Hang Zheng

We explore a novel simulation route for Plasma Wakefield Acceleration (PWFA) by using the computational method known as the Lattice Boltzmann Method (LBM). LBM is based on a discretization of the continuum kinetic theory while assuring the…

We employ classical and ring polymer molecular dynamics simulations to study the effect of nuclear quantum fluctuations on the structure and the water exchange dynamics of aqueous solutions of lithium and fluoride ions. While we obtain…

Chemical Physics · Physics 2015-06-23 David M. Wilkins , David E. Manolopoulos , Liem X. Dang
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