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Polyphenols are natural molecules of crucial importance in many applications, of which tannic acid (TA) is one of the most abundant and established. Most high-value applications require precise control of TA interactions with the system of…

We report self-consistent ab-initio electronic, structural, elastic, and optical properties of cubic SrTiO$_{3}$ perovskite. Our non-relativistic calculations employed a generalized gradient approximation (GGA) potential and the linear…

Materials Science · Physics 2012-04-03 C. E. Ekuma , M. Jarrell , J. Moreno , D. Bagayoko

Amorphous films of tantalum oxide (Ta2O5) are widely applied to build highly reflective mirrors used in interferometric gravitational wave detectors, such as the Laser Interferometer Gravitational Wave Observatory (LIGO). Despite a large…

Materials Science · Physics 2021-11-29 Alberto Martinelli , Mauro Giovannini , Martina Neri , Gianluca Gemme

The structural, electronic, and dielectric (optical) properties of graphene-like 2D MgO monolayer have been explored through first-principles calculations under bi-axial tensile and compressive mechanical strain within a range of -10% to…

Materials Science · Physics 2024-05-31 Kamal Kumar , Anjali Kumari , Soni Mishra , Ramesh Sharma , Abhishek Kumar Mishra

The electronic structure of the zincblende $\beta$-HgS is not well understood. Previous first-principles calculations using fully-relativistic density functional theory and many-body perturbation theory in the fully-relativistic $GW$…

Materials Science · Physics 2022-03-31 Bradford A. Barker , Steven G. Louie

The structural, dielectric and ferroelectric properties of lead-free (Na0.5-xKxBi0.5-xLax)TiO3 powders synthesized by sol-gel self-combustion method were investigated. Rietveld refinement of Synchrotron x-ray diffraction data confirms pure…

A new iron-oxychalcogenide (CaO)(FeSe) was obtained which crystallizes in the orthorhombic space group Pnma (No. 62) with a = 5.9180(12) {\AA}, b = 3.8802(8) {\AA}, c = 13.193(3) {\AA}. The unique structure of (CaO)(FeSe) is built up of a…

First-principles DFT levels of calculations have been carried out in order to study the structural stability and electronic properties of hydrogen passivated graphene (H-graphene) clusters. Two different shaped clusters, rectangular and…

Materials Science · Physics 2014-05-02 Deepak B Karki , Narayan P Adhikari

Band structures of electrons in a periodic potential are well-known to host topologies that impact their behaviors at edges and interfaces. The concept however is more general than the single-electron setting. In this work, we consider…

Mesoscale and Nanoscale Physics · Physics 2024-10-16 Luis Brey , H. A. Fertig

Isolated oxygen impurities and fully oxidized structures of four stable two-dimensional (2D) SiS structures are investigated by {\em ab initio} density functional calculations. Binding energies of oxygen impurities for all the four 2D SiS…

Materials Science · Physics 2019-04-23 Zhengnan Li , Shuai Dong , Jie Guan

Transition metal monochalcogenides comprise a class of two-dimensional materials with electronic band gaps that are highly sensitive to material thickness and chemical composition. Here, we explore the tunability of the electronic…

quasi-one-dimensional (1D) titania nanostructures - single-walled nanotubes formed by rolling [101] planes of TiO$_2$ (anatase phase) are modeled and their electronic properties and bond orders indices are studied using the tight-binding…

Materials Science · Physics 2009-11-07 V. V. Ivanovskaya , A. N. Enyashin , N. I. Medvedeva , A. L. Ivanovskii

The AM2Pn2 (A= Ca, Sr, Ba, Yb, Mg; M= Mn, Zn, Cd, Mg; and Pn=N, P, As, Sb, Bi) family of Zintl phases has been known as thermoelectric materials and has recently gained much attention for highly promising materials for solar absorbers in…

We report the electronic structure of monoclinic CuO as obtained from first principles calculations utilizing density functional theory plus effective Coulomb interaction (DFT + U) method. In contrast to standard DFT calculations taking…

Strongly Correlated Electrons · Physics 2014-02-19 C. E. Ekuma , V. I. Anisimov , J. Moreno , M. Jarrell

We propose a new structural model for the Si(111)-(5x2)-Au reconstruction. The model incorporates a new experimental value of 0.6 monolayer for the coverage of gold atoms, equivalent to six gold atoms per 5x2 cell. Five main theoretical…

Materials Science · Physics 2015-05-14 Steven C. Erwin , Ingo Barke , F. J. Himpsel

We present a comparative study of the valence band electronic structure of Pd based ternary chalcogenide superconductors Nb2Pd0.95S5, Ta2Pd0.97S6 and Ta2Pd0.97Te6 using experimental photoemission spectroscopy and density functional based…

Superconductivity · Physics 2023-10-31 H. Lohani , P. Mishra , R. Goyal , V. P. S. Awana , B. R. Sekhar

In this work using the density functional theory (DFT), we have studied the structural, electronic and magnetic properties of uranium dioxide with antiferromagnetic 1k-, 2k-, and 3k-order structures. Ordinary approximations in DFT, such as…

Materials Science · Physics 2020-08-25 Samira Sheykhi , Mahmoud Payami

LiNi0.5Mn1.5O4, which has a spinel framework structure, is a promising candidate for the cathode material of next-generation lithium-ion batteries with high energy density. We investigate the structural transition in LixNi0.5Mn1.5O4 (0 <= x…

Materials Science · Physics 2013-02-05 Ippei Kishida , Kengo Orita , Atsutomo Nakamura , Yoshiyuki Yokogawa

A novel stable crystallographic structure is discovered in a variety of ABO3, ABF3 and A2O3 compounds (including materials of geological relevance, prototypes of multiferroics, exhibiting strong spin-orbit effects, etc...), via the use of…

Materials Science · Physics 2015-01-20 Changsong Xu , Bin Xu , Yurong Yang , Huafeng Dong , A. R. Oganov , Shanying Wang , Wenhui Duan , Binglin Gu , L. Bellaiche

Thin Ge layers deposited on Si(105) form a stable single-domain film structure with large terraces and rebonded-step surface termination, thus realizing an extended and ordered Ge/Si planar hetero-junction. At the coverage of four Ge…

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