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We report on the growth of stoichiometric Sr$_2$IrO$_4$ single crystals, which allow us to unveil their intrinsic magnetic properties. The effect of different growth conditions has been investigated for crystals grown by the flux method. We…

Strongly Correlated Electrons · Physics 2016-04-27 N. H. Sung , H. Gretarsson , D. Proepper , J. Porras , M. Le Tacon , A. V. Boris , B. Keimer , B. J. Kim

Mm-sized LiMn$_{1-x}$Fe$_x$PO$_4$ single crystals with $0\leq x \leq 1$ were grown by means of the traveling floating-zone technique at elevated Argon pressure of 30~bar. For the various doping levels, the growth process was optimized with…

Strongly Correlated Electrons · Physics 2017-02-07 Christoph Neef , Hubert Wadepohl , Hans-Peter Meyer , Rüdiger Klingeler

High-quality single crystals are essentially needed for the investigation of the novel bulk properties of unconventional superconductors. The availability of such crystals grown by the floating-zone method has helped to unveil the…

Superconductivity · Physics 2019-01-08 J. S. Bobowski , N. Kikugawa , T. Miyoshi , H. Suwa , S. Yonezawa , D. A. Sokolov , A. P. Mackenzie , Y. Maeno

The optical floating zone crystal growth technique is a well-established method for obtaining large, high-purity single crystals. While the floating zone method has been constantly evolving for over six decades, the development of…

We report the growth of mm-sized Pmnb-Li2FeSiO4 single crystals by means of the optical floating-zone method at high argon pressure and describe the conditions required for a stable growth process. The crystal structure is determined and…

We report a study on the crystal growth of the hexagonal manganites $R$MnO$_3$ ($R$ = Y, Lu, Ho, Er, and Tm) by using an optical floating-zone method. It was found that high-quality single crystals of $R$ = Y, Lu, and Ho could be easily…

Strongly Correlated Electrons · Physics 2015-06-17 C. Fan , Z. Y. Zhao , J. D. Song , J. C. Wu , F. B. Zhang , X. F. Sun

We report the optimized conditions for growing the high quality single crystals of candidate quantum spin-ice Pr2Hf2O7 using the optical floating-zone method. Large single crystals of Pr2Hf2O7 have been grown under different growth…

Strongly Correlated Electrons · Physics 2019-01-02 V. K. Anand , A. T. M. N. Islam , A. Samartzis , J. Xu , N. Casati , B. Lake

The Fe^{4+}-containing cubic perovskite phase SrFeO_3-x is of interest both for its high-temperature, oxygen-conducting properties as a solid oxide fuel cell component, and at low temperatures, where it exhibits a plethora of helical…

Materials Science · Physics 2012-10-23 D. C. Peets , Jung-hwa Kim , M. Reehuis , P. Dosanjh , B. Keimer

Single crystals of iridates are usually grown by a flux method well above the boiling point of the SrCl2 solvent. This leads to non-equilibrium growth conditions and dramatically shortens the lifetime of expensive Pt crucibles. Here, we…

We report a systematic study on the crystal growth of the rare-earth titanates $R_2$Ti$_2$O$_7$ ($R$ = Gd, Tb, Dy, Ho, Y, Er, Yb and Lu) and Y-doped Tb$_{2-x}$Y$_x$Ti$_2$O$_7$ ($x$ = 0.2 and 1) using an optical floating-zone method.…

Strongly Correlated Electrons · Physics 2013-11-13 Q. J. Li , L. M. Xu , C. Fan , F. B. Zhang , Y. Y. Lv , B. Ni , Z. Y. Zhao , X. F. Sun

Sr$_{2}$IrO$_{4}$ with strong spin-orbit coupling (SOC) and Hubbard repulsion (U) hosts Mott insulating states. The similar crystal structure, magnetic and electronic properties, particularly the $d$-wave gap observed in Sr$_{2}$IrO$_{4}$…

Strongly Correlated Electrons · Physics 2023-12-04 Haozhe Wang , Madalynn Marshall , Zhen Wang , Kemp W. Plumb , Martha Greenblatt , Yimei Zhu , David Walker , Weiwei Xie

Iridium-based 5d transition-metal oxides are attractive candidates for the study of correlated electronic states due to the interplay of enhanced crystal-field, Coulomb and spin-orbit interaction energies. At ambient pressure, these…

Strongly Correlated Electrons · Physics 2014-06-05 D. A. Zocco , J. J. Hamlin , B. D. White , B. J. Kim , J. R. Jeffries , S. T. Weir , Y. K. Vohra , J. W. Allen , M. B. Maple

Motivated by an experimental finding that the successive phase transitions in $\alpha$-Sr$_2$CrO$_4$ observed at ambient pressure ceases to exist under high pressures, we carry out the density-functional-theory-based electronic structure…

Strongly Correlated Electrons · Physics 2020-04-22 Ryo Takahashi , Tomoki Yamaguchi , Koudai Sugimoto , Touru Yamauchi , Hiroya Sakurai , Yukinori Ohta

The wealth of structural phases seen in the rare-earth disilicate compounds promises an equally rich range of interesting magnetic properties. We report on the crystal growth by the optical floating zone method of members of the rare-earth…

Single crystals of PrNiO3 were grown under an oxygen pressure of 295 bar using a unique high-pressure optical-image floating zone furnace. The crystals, with volume in excess of 1 mm3, were characterized structurally using single crystal…

The floating zone technique is a well-established single crystal growth method in materials research, able to produce volumetrically large specimens with extremely high purities. However, traditional furnace designs have relied on heating…

Materials Science · Physics 2019-04-25 Julian L. Schmehr , Michael Aling , Eli Zoghlin , Stephen D. Wilson

Single crystal growth of {\alpha}-Na$_x$MnO$_2$ (x = 0.90) is reported via the floating zone technique. The conditions required for stable growth and intergrowth-free crystals are described along with the results of trials under alternate…

Centimeter-sized single crystals of Sr$_{1.5}$La$_{0.5}$RhO$_{4}$ were grown by the floating zone method at oxygen pressures of 20~bar. The quality of our single crystals was confirmed by X-ray Laue, powder and single crystal X-ray…

Strongly Correlated Electrons · Physics 2017-09-06 Z. W. Li , H. Guo , Z. Hu , T. S. Chan , K. Nemkovski , A. C. Komarek

A series of polycrystalline samples of Sr2-xIrO4 have been synthesized by a solid-state reaction method. The crystal structure of this doped system can be explained on the basis of the extended nature of 5d electrons and strontium vacancies…

Strongly Correlated Electrons · Physics 2016-11-09 Jimei Kong , S. L. Liu , Jie Cheng , Haiyun Wang , Xing ao Li , Z. H. Wang

We perform a time-resolved optical study of Sr$_2$IrO$_4$ to understand the influence of magnetic ordering on the low energy electronic structure of a strongly spin-orbit coupled $J_{eff}$=1/2 Mott insulator. By studying the recovery…

Strongly Correlated Electrons · Physics 2012-03-21 D. Hsieh , F. Mahmood , D. H. Torchinsky , G. Cao , N. Gedik
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