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A broad effort is underway to improve the sensitivity of nuclear magnetic resonance through the use of dynamic nuclear polarization. Nitrogen-vacancy (NV) centers in diamond offer an appealing platform because these paramagnetic defects can…

Nuclear hyperpolarization is a known method to enhance the signal in nuclear magnetic resonance (NMR) by orders of magnitude. The present work addresses the $^{13}$C hyperpolarization in diamond micro- and nanoparticles, using the…

The integration of NMR and high pressure technique brings unique opportunities to study electronic, structural and dynamical properties under extreme conditions. Despite a great degree of success has been achieved using coil-based schemes,…

Quantum Physics · Physics 2022-03-22 Yan-Xing Shang , Fang Hong , Jian-Hong Dai , Ya-Nan Lu , Hui Yu , Yong-Hong Yu , Xiao-Hui Yu , Xin-Yu Pan , Gang-Qin Liu

Atomistic modeling is a widely employed theoretical method of computational materials science. It has found particular utility in the study of magnetic materials. Initially, magnetic empirical interatomic potentials or spin-polarized…

Atomic Physics · Physics 2024-07-02 Tatiana S. Kostiuchenko , Alexander V. Shapeev , Ivan S. Novikov

Using a theory of polarizable fluids, we extend a variational treatment of an excess electron to the many-electron case corresponding to finite metal concentrations in metal-ammonia solutions (MAS). We evaluate dielectric, optical, and…

Statistical Mechanics · Physics 2009-11-13 Gennady N. Chuev , Pascal Quemerais , Jason Crain

We report polarization of a dense nuclear-spin ensemble in diamond and its dependence on magnetic field and temperature. The polarization method is based on the transfer of electron spin polarization of negatively charged nitrogen vacancy…

Quantum Physics · Physics 2013-04-01 Ran Fischer , Andrey Jarmola , Pauli Kehayias , Dmitry Budker

The ability to optically initialize the electronic spin of the nitrogen-vacancy (NV) center in diamond has long been considered a valuable resource to enhance the polarization of neighboring nuclei, but efficient polarization transfer to…

Mesoscale and Nanoscale Physics · Physics 2018-08-01 F. Shagieva , S. Zaiser , P. Neumann , D. B. R. Dasari , R. Stöhr , A. Denisenko , R. Reuter , C. A. Meriles , J. Wrachtrup

Nuclear electric resonance (NER) is based on nuclear magnetic resonance mediated by spatial oscillations of electron spin domains excited by a radio frequency (RF) electric field, and it allows us to investigate the spatial distribution of…

Mesoscale and Nanoscale Physics · Physics 2012-10-25 S. Watanabe , G. Igarashi , N. Kumada , Y. Hirayama

For applications of solid state quantum computing and quantum simulations, high fidelity initialisation of thermally mixed electronic and nuclear spin qubits is essential. Whereas electronic spins can readily be initialised optically to…

Quantum Physics · Physics 2024-04-12 O. T. Whaites , T. S. Monteiro

We reveal an interplay between temperature and radical concentration necessary to establish thermal mixing (TM) as an efficient dynamic nuclear polarization (DNP) mechanism. We conducted DNP experiments by hyperpolarizing widely used DNP…

Quantum Physics · Physics 2024-04-12 Ludovica M. Epasto , Thibaud Maimbourg , Alberto Rosso , Dennis Kurzbach

We present dynamic nuclear polarization (DNP) in the simplest pseudospin quantum Hall ferromagnet (QHF) of an InSb two-dimensional electron gas with a large g factor using tilted magnetic fields. The DNP-induced amplitude change of a…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 H. W. Liu , K. F. Yang , T. D. Mishima , M. B. Santos , Y. Hirayama

Motivated by possible spintronics applications in antiferromagnets, it was recently observed that symmetry admits magnets that combine attractive features of both ferromagnets and antiferromagnets. These systems, dubbed altermagnets, have…

We report record high Si-29 spin polarization obtained using dynamic nuclear polarization in microcrystalline silicon powder. Unpaired electrons in this silicon powder are due to dangling bonds in the amorphous region of this intrinsically…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 A. E. Dementyev , D. G. Cory , C. Ramanathan

In heavy atoms and ions, nuclear structure effects are significantly enhanced due to the overlap of the electron wave functions with the nucleus. This overlap rapidly increases with the nuclear charge $Z$. We study the energy level shifts…

Atomic Physics · Physics 2021-03-17 V. V. Flambaum , I. B. Samsonov , H. B. Tran Tan , A. V. Viatkina

Nuclear spins and paramagnetic centers in a solid randomly group to form clusters featuring nearly-degenerate, hybrid states whose dynamics are central to processes involving nuclear spin-lattice relaxation and diffusion. Their…

The use of nitrogen-vacancy centers in diamond as a non-invasive platform for hyperpolarizing nuclear spins in molecular samples is a promising area of research with the potential to enhance the sensitivity of nuclear magnetic resonance…

Quantum Physics · Physics 2024-08-08 H. Espinós , C. Munuera-Javaloy , I. Panadero , P. Acedo , R. Puebla , J. Casanova , E. Torrontegui

The use of nuclear spins as physical sensing systems is disadvantaged by their low signal responsivity, particularly when compared to sensing techniques based on electron spins. This primarily results from the small nuclear gyromagnetic…

We employ electron paramagnetic resonance (EPR) of the spin probe Mn2+ to study the paraelectric ferroelectric transition in DMAMnF and Mn2 doped DMZnF, which are considered to be model metal organic frameworks (MOF) with a Pb free…

Materials Science · Physics 2022-02-25 Nandita Abhyankar , Sylvain Bertaina , Maylis Orio , Naresh Dalal

We use dynamic nuclear polarization (DNP) enhanced nuclear magnetic resonance (NMR) at liquid helium temperatures to directly detect hydrogen attached to the surface of silicon microparticles. The proton NMR spectrum from a dry sample of…

Materials Science · Physics 2017-06-08 Mallory L. Guy , Kipp J. van Schooten , Lihuang Zhu , Chandrasekhar Ramanathan

The hyperpolarization of nuclear spins can enable powerful imaging and sensing techniques provided the hyperpolarization is sufficiently long-lived. Recent experiments on nanodiamond $^{13}$C nuclear spins demonstrate that relaxation times…

Mesoscale and Nanoscale Physics · Physics 2024-02-20 Gargee Sharma , Torsten Gaebel , Ewa Rej , David J. Reilly , Sophia E. Economou , Edwin Barnes
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