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Related papers: Metal Ions based Dynamic Nuclear Polarization: MI-…

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Dynamic nuclear polarization (DNP) is an out-of-equilibrium method for generating non-thermal spin polarization which provides large signal enhancements in modern diagnostic methods based on nuclear magnetic resonance. A particular instance…

Dynamic nuclear polarization is widely used to enhance the sensitivity of nuclear magnetic resonance. It is presently the method of choice for enhancing the sensitivity of high-field solid state NMR experiments performed under cryogenic…

Chemical Physics · Physics 2022-02-02 Maria Grazia Concilio , Ilya Kuprov , Lucio Frydman

A sensitivity increase of two orders of magnitude in proton (1H) and carbon (13C) spins via dynamic nuclear polarization (DNP) has been accomplished recently using a compact benchtop DNP polarizer operating at 1 T and 77 K. However the DNP…

Dynamic nuclear polarization (DNP) has revolutionized the field of NMR spectroscopy, expanding its reach and capabilities to investigate diverse materials, biomolecules, and complex dynamic processes. Bringing high-efficiency DNP to the…

Mesoscale and Nanoscale Physics · Physics 2024-02-27 Sahand Tabatabaei , Pritam Priyadarsi , Namanish Singh , Pardis Sahafi , Daniel Tay , Andrew Jordan , Raffi Budakian

Hyper-polarization of nuclear spins is crucial for advancing nuclear magnetic resonance (NMR) and quantum information technologies, as nuclear spins typically exhibit extremely low polarization at room temperature due to their small…

Quantum Physics · Physics 2025-05-20 Haiyang Li , Hao Liao , Ping Wang

Dynamic nuclear polarization experiments use microwave irradiation to transfer the larger electron polarization to nuclear spins of interest, and thus enhance the NMR transitions above thermal equilibrium. How the polarization transfer from…

Chemical Physics · Physics 2026-01-12 Gian-Marco Camenisch , Nino Wili , Gunnar Jeschke , Matthias Ernst

Dynamic nuclear polarization transfers spin polarization from electrons to nuclei. We have achieved this by a new method, simultaneously exciting transitions of electronic and nuclear spins. The efficiency of this technique improves with…

Quantum Physics · Physics 2008-09-11 G. W. Morley , K. Porfyrakis , A. Ardavan , J. van Tol

Dynamic nuclear polarization (DNP) is an NMR hyperpolarization technique that mediates polarization transfer from highly polarized unpaired electrons to NMR-active nuclei via microwave (mw) irradiation. The ability to generate arbitrarily…

Low thermal polarization of nuclear spins is a primary sensitivity limitation for nuclear magnetic resonance. Here we demonstrate optically pumped (microwave-free) nuclear spin polarization of $^{13}\mathrm{C}$ and $^{15}\mathrm{N}$ in…

Mesoscale and Nanoscale Physics · Physics 2017-08-09 Ben L. Green , Ben G. Breeze , Gregory J. Rees , John V. Hanna , Jyh-Pin Chou , Viktor Ivády , Adam Gali , Mark E. Newton

A DFT-based method is presented which allows the computation of all-electron NMR shifts of metallic compounds with periodic boundary conditions. NMR shifts in metals measure two competing physical phenomena. Electrons interact with the…

Materials Science · Physics 2009-11-13 Mayeul d'Avezac , Nicola Marzari , Francesco Mauri

Dynamic nuclear polarization (DNP) is a method of enhancing NMR signals via the transfer of polarization from electron spins to nuclear spins using on-resonance microwave (MW) irradiation. In most cases, monochromatic continuous-wave (MCW)…

Chemical Physics · Physics 2022-11-17 Daphna Shimon , Kelly A. Cantwell , Linta Joseph , Chandrasekhar Ramanathan

Dynamic nuclear polarization (DNP) is capable of boosting signals in nuclear magnetic resonance by orders of magnitude by creating out-of-equilibrium nuclear spin polarization. The diffusion of nuclear spin polarization in the vicinity of…

Other Condensed Matter · Physics 2023-07-12 Alessandro Chessari , Samuel F. Cousin , Sami Jannin , Quentin Stern

The magnetic interactions between the spin of an unpaired electron and the surrounding nuclear spins can be exploited to gain structural information, to reduce nuclear relaxation times as well as to create nuclear hyperpolarization via…

Dynamic nuclear polarisation, which transfers the spin polarisation of electrons to nuclei, is routinely applied to enhance the sensitivity of nuclear magnetic resonance; it is also critical in spintronics, particularly when spin…

Color-center-hosting semiconductors are emerging as promising source materials for low-field dynamic nuclear polarization (DNP) at or near room temperature, but hyperfine broadening, susceptibility to magnetic field heterogeneity, and…

Quantum Physics · Physics 2022-06-01 J. Henshaw , D. Pagliero , P. R. Zangara , B. Franzoni , A. Ajoy , R. Acosta , J. A. Reimer , A. Pines , C. A. Meriles

Polar metals are an underexplored material class combining two properties that are typically incompatible, namely a polar crystal structure and reasonable electrical conductivity. These intriguing materials offer a unique combination of…

Dynamic nuclear polarization (DNP) enhances nuclear magnetic resonance (NMR) signals by transferring electron spin polarization to nuclei. As DNP requires microwave magnetic fields B1 strong enough to saturate electron spins, microwave…

Magnons offer a promising path toward energy-efficient information transmission and the development of next-generation classical and quantum computing technologies. However, methods to efficiently excite, manipulate, and detect magnons…

Nickel (Ni) is a magnetic transition metal with two allotropic phases, stable face-centered cubic (FCC) and metastable hexagonal close-packed (HCP), widely used in structural applications. Magnetism affects many mechanical and defect…

The nitrogen-vacancy (NV) centre in diamond has emerged as a candidate to non-invasively hyperpolarise nuclear spins in molecular systems to improve the sensitivity of nuclear magnetic resonance (NMR) experiments. Several promising proof of…

Mesoscale and Nanoscale Physics · Physics 2021-05-26 A. J. Healey , L. T. Hall , G. A. L. White , T. Teraji , M. -A. Sani , F. Separovic , J. -P. Tetienne , L. C. L. Hollenberg